氮化鋁雖具有許多優越的性質，實際應用卻未如預期快速成長，其中之主要的原因為許多應用上的問題尚未完全解決。這些應用上的問題，其中關鍵的問題就是水解與潮解的問題；因氮化鋁與碳化矽晶格結構、密度及原子尺寸非常相近，兩者在一定條件下可形成完全固溶體，本論文欲利用其固溶方式改善氮化鋁在抵抗水解及溼氣能力。於低氮壓下製備氮化鋁-碳化矽固溶體，鋁矽比決定固溶體之性質，氮氣壓力則無實質影響；片狀鋁粉則因外表物理因素不適合生產固溶體。使用燃燒合成法製備的氮化鋁-碳化矽固溶體，經抗濕、抗水解測試後，發現氮化鋁-碳化矽固溶體擁有較佳的抵抗濕氣及抵抗水解的能力，並明顯降低水解形成氫氧化鋁的速率，其於高溫中(110℃)抵抗水解的能力更勝於以磷酸表面改質之氮化鋁粉體。而氮化鋁-碳化矽固溶體隨著組成接近氮化鋁，其性質也接近氮化鋁，但僅需固溶微量碳化矽(5 mol%)便可大幅減緩水解後生成氫氧化鋁之速率。雖目前以燃燒合成法之氮化鋁-碳化矽固溶體含有未反應物雜質，但其與環氧樹脂製成複合材料熱傳導值仍有使用純氮化鋁複合材料之一半以上。

Aluminum nitride (AlN) has many superior properties, but in practical application has not been growth rapidly as expected, one of the main reasons is the application problems has not resolved. The key point of the application problems is that AlN is easy to react with water for hydrolysis and deliquescence. The lattice structure, density and atomic size of AlN and silicon carbide (SiC) are very similar that they can form solid solutions in under certain conditions. This thesis wants to improve the hydrolyzed resistance and moisture resistance of AlN by solid solutions of AlN-SiC. Combustion synthesis AlN-SiC solid solutions at low nitrogen pressure region: properties decide by the ratio of Al and Si, the nitrogen pressure has poor correlation with properties. The flaky aluminum is unsuitable to synthesis solid solutions Due to the physical factors of shape. The experiment results show that AlN-SiC solid solutions synthesis by combustion synthesis has better hydrolyzed resistance and moisture resistance, reduce the forming rate of aluminium hydroxide (Al(OH)3) obviously. At high temperature (110℃) surrounding, the hydrolyzed resistance of AlN-SiC solid solutions even better than the phosphoric acid (H3PO4) surface treatment of AlN. The composition of AlN increase, the property of AlN-SiC solid solutions trend to AlN, but only solid solution trace amounts of SiC (5 mol%) can extend the time of forming Al(OH)3 obviously. Although combustion synthesis of AlN-SiC solid solutions has unreacted agent, the composites with epoxy has high thermal conductivity above half of AlN’s composites.

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