簡易檢索 / 詳目顯示

研究生: 謝信瑞
Hsieh, Hsin-Jui
論文名稱: 光電化學法與堆疊式閘極薄膜製作氮化鋁鎵/氮化鎵互補式金氧半高電子遷移率場效電晶體
Investigation of AlGaN/GaN Complementary MOS-HEMTs with Photoelectrochemical Method and Gate Dielectric Stack
指導教授: 李清庭
Lee, Ching-Ting
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 微電子工程研究所
Institute of Microelectronics Engineering
論文出版年: 2021
畢業學年度: 109
語文別: 中文
論文頁數: 91
中文關鍵詞: 氮化鋁鎵/氮化鎵 、光電化學法 、鈮酸鋰 、電子捕捉層堆疊式閘極氧化層 、互補式金氧半高電子遷移率場效電晶體 、閘極掘入
外文關鍵詞: AlGaN/GaN MOS-HEMTs, photoelectrochemical method, LiNbO3, ferroelectric charge trap gate stacked oxide structure, CMOS-HEMTs
相關次數: 點閱:164  下載:0 
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 由三五族半導體氮化鋁鎵/氮化鎵之異質結構所產生的極化特性,於兩者間導帶不連續處形成一量子井,使高濃度的電子被侷限於量子井內且少了雜質散射等影響,因此能在二維平面下進行高速移動,故稱其為二維電子氣(two dimensional electron gas, 2DEG)通道。此通道不僅擁有高電子遷移率,更因氮化鎵材料本身具有寬能隙、高崩潰電場、良好的熱穩定,使氮化鋁鎵/氮化鎵之異質結構半導體元件能在高溫、高頻下還能擁有良好的操作表現。本論文中引用氮化鋁鎵/氮化鎵異質結構所製作的空乏型(depletion mode)及增強型(enhancement mode)之金氧半高電子遷移率場效電晶體(MOS-HEMTs)結合,並將電路設計成共源極反相器電路,以形成空乏型元件與增強型元件串聯之互補式金氧半高電子遷移率場效電晶體元件(CMOS-HEMTs),完成反相器作動之目的。
    空乏型元件採用光電化學氧化法形成閘極氧化層,並使用光電化學蝕刻法進行不同蝕刻深度以調變空乏型元件操作電流。此法有別於傳統互補式電晶體利用閘極寬長比調變電流比例,容易因為兩者元件面積尺寸不一而增加整合於積體電路中的難易度,故透過蝕刻氮化鋁鎵薄膜厚度調變電流即可避免此問題,亦不影響該反相器作動的能力。
    為了完成增強型元件操作之目的,使臨界電壓(threshold voltage, Vth)往正偏移,必須減少氮化鋁鎵薄膜厚度,降低二維電子氣通道內載子濃度,並同時提升閘極控制通道的能力。首先採用脈衝雷射沉積法(pulsed laser deposition technique)製作鈮酸鋰(lithium niobate, LiNbO3)鐵電薄膜作為堆疊式閘極氧化層最上層,利用其自發極化特性,並結合中間的電子捕捉層二氧化鉿(hafnium oxide, HfO2)薄膜捕捉電子與最下層的電子穿隧層三氧化二鋁(aluminum oxide, Al2O3)使電子穿隧並困於二氧化鉿中後不易跳回通道,達到更進一步空乏二維電子氣通道之目的,同時搭配光電化學(photoelectronchemical, PEC)濕式蝕刻法完成閘極掘入結構製作,使閘極更接近通道並提升閘極對通道的控制能力,完成增強型高速電子遷移率電晶體製作。
    在負載端空乏型元件之氮化鋁鎵薄膜在經過蝕刻後所剩深度分別為12 nm、10 nm及8 nm下,空乏型元件與增強型元件的電流比例分別為5、8及22倍,並經過負載線特性分析、時域輸出波型及輸出輸入轉移曲線等反相器各項特性趨勢中,可以得知互補式場效電晶體元件在22倍的操作電流比例下將擁有較好的反相器輸出特性,操作在VDD為5 V、VIN為5 V的條件下,輸出擺幅(output swing):4.90 V、雜訊邊際(noise margin):NMH= 1.99 V、NML= 1.73 V,而當VOUT=2.5 V時,其VIN值已約落於2.5 V(VDD/2)的位置,達到無偏斜反相器的輸出特性。

    In this research, the complementary metal-oxide-semiconductor high-electron-mobility transistors (CMOS-HEMTs) were integrated with the AlGaN/GaN Enhancement-mode (E-mode) and Depletion-mode (D-mode) transistors. Owing to the heterostructure of energy band, AlGaN/GaN HEMTs were born to have a great advantage of polarization-induced two dimensional electron gas (2DEG) channel to form a high-speed device.
    Although the AlGaN/GaN HEMTs with the polarization induced two dimensional electron gas (2DEG) channel were generally fabricated as the D-mode transistors, Al-GaN/GaN enhancement-mode MOSHEMTs (E-mode MOSHEMTs) were still demanded to practical integrated circuits to simplify circuit design, improve safety capability, and reduce power consumption. Therefore, to fabricate the E-mode transistors, a gate-recessed structure and LiNbO3 ferroelectric charge trap gate stacked oxide layers were utilized in AlGaN/GaN E-mode MOSHEMTs.
    Besides, to form the unskewed inverter, the current ratio () of E/D-mode transistors was adjusted with various etching depths in the AlGaN layer of the load type D-mode transistors. Compared to the typical tuning method, this PEC etching method is benefi-cial for scaling down the CMOS-HEMTs due to the matching size between the E-mode and D-mode MOSHEMTs. Finally, as the input signal was 5 V, the output swing of the resulting CMOS-HEMTs with the E/D-mode transistor current ratio () of 22 was 4.90 V. The noise margin high and low were about 1.99 V and 1.73 V, respectively. As to the voltage transfer curve (VTC), the corresponded VIN was about 2.5 V which be closer to VDD/2 (= 2.5 V) as the VOUT was 2.49 V, which revealed that the resulting CMOS-HEMTs with the  was 22 could be operated as an unskewed inverter.

    摘要I AbstractIV 致謝XI 目錄XIII 表目錄XVII 圖目錄XVIII 第一章 序論 1 1.1 氮化鋁鎵/氮化鎵高電子遷移率場效電晶體 1 1.2 研究動機 2 1.3 論文架構 4 參考文獻 7 第二章 原理與文獻回顧 10 2.1 氮化鋁鎵/氮化鎵之異質結構 10 2.1.1 氮化鋁鎵/氮化鎵之異質結構成長 10 2.1.2 二維電子氣之特性 11 2.2 氮化鋁鎵材料之蝕刻原理 11 2.2.1 光電化學濕式蝕刻/氧化法 11 2.3 鈮酸鋰鐵電材料原理 14 2.3.1 介電材料之極化機制 14 2.4 鈮酸鋰薄膜基本性質 15 2.4.1 晶體結構及性質 15 2.4.2 基板效應 16 2.5 堆疊式閘極氧化層 17 2.5.1 堆疊式閘極氧化層結構發展與原理 17 2.5.2 Fowler-Nordheim穿隧機制 18 2.6 互補式金氧半高電子遷移率場效電晶體 18 2.6.1 共源極反相器電路 18 2.6.2 負載式空乏型電晶體元件 19 2.6.3 使用光電化學蝕刻法製作負載式空乏型電晶體 20 參考文獻 27 第三章 元件製程及量測儀器 31 3.1 試片結構 31 3.2 金氧半高電子遷移率場效電晶體製作流程 31 3.2.1 高台隔離製作 32 3.2.2 表面硫化處理 33 3.2.3 歐姆接觸電極 34 3.2.4 空乏型電晶體閘極氧化層生長 35 3.2.5 增強型電晶體閘極掘入 36 3.2.6 堆疊式增強型電晶體閘極氧化層生長 37 3.2.7 閘極金屬製作 38 3.3 製程及量測儀器 38 3.3.1 電子束蒸鍍系統 38 3.3.2 原子層沉積系統 39 3.3.3 脈衝雷射沉積系統 39 3.3.4 直流電流-電壓量測系統 40 3.3.5 交流輸出-輸入量測系統 40 參考文獻 51 第四章 實驗結果與討論 54 4.1 增強型高電子遷移率場效電晶體 54 4.1.1 鐵電材料鈮酸鋰薄膜 54 4.1.2 堆疊式閘極氧化層增強型元件界面態密度電容-電壓量測 56 4.1.3 堆疊式閘極氧化層增強型高電子遷移率場效電晶體 57 4.1.4 堆疊式閘極氧化層增強型元件之電特性 58 4.2 乏型高電子遷移率場效電晶體 59 4.2.1 負載式空乏型電晶體 60 4.2.2 不同掘入深度之元件特性量測 61 4.3 互補式高電子遷移率場效電晶體 61 4.3.1 使用光電化學蝕刻法調變空乏型元件電流比例 62 4.3.2 空乏型與增強型元件操作電流比例與反相器輸出特性 63 4.3.3 空乏型與增強型元件電流比例與反相器交流特性量測 65 4.3.4 輸出擺幅與無偏斜轉移曲線反相器之特性 66 4.3.5 最佳輸出擺幅與無偏斜轉移曲線互補式電晶體反相器電路特性 68 參考文獻 88 第五章 結論 90 表目錄 表1.1 材料性質比較 5 表2.1 鈮酸鋰之相關物理參數表 21 表3.1 各種常見金屬之功函數 41 表4.1 增強型高速電子遷移率場效電晶體製程參數 70 表4.2 反相器輸出特性於不同電流比例下數據整理 70 圖目錄 圖1.1寬能隙材料的應用與發展趨勢 6 圖1.2 氮化鋁鎵/氮化鎵高速電晶體的異質結構與能帶示意圖 6 圖2.1 氮化鋁鎵/氮化鎵異質結構極化方向及二維電子氣位置示意圖 21 圖2.2 氮化鋁鎵結構成長截止面對於極化方向之示意圖 22 圖2.3 光電化學法機制之能帶示意圖 22 圖2.4 原子極化、離子極化、電偶極極化及空間電荷極化示意圖 23 圖2.5 鈮酸鋰晶體菱形晶胞示意圖 24 圖2.6 鈮酸鋰晶胞中鋰原子與鈮原子在c軸上相對位置變化與自發極化方向的關係圖 24 圖2.7 鈮酸鋰薄膜成長於氮化鋁鎵上受基板效應影響之電偶極分布及極化方向示意圖 25 圖2.8 F-N tunneling 穿隧機制示意圖 25 圖2.9 共源極反相器電路 26 圖2.10 以寬長比調變電流比之反相器特性 26 圖3.1 試片磊晶結構圖 42 圖3.2 互補式金氧半高電子遷移率場效電晶體光罩圖形 42 圖3.3 互補式金氧半高電子遷移率場效電晶體製作 47 圖3.4 互補式金氧半高電子遷移率場效電晶體元件結構剖面圖 47 圖3.5 光電化學濕式蝕刻/氧化系統示意圖 48 圖3.6 金半接面之電流-電壓特性 48 圖3.7 電子束蒸鍍系統示意圖 49 圖3.8 脈衝雷射沉積系統示意圖 49 圖3.9 AC特性量測系統示意圖 50 圖4.1 鈮酸鋰薄膜於腔體溫度600°C生長後經600°C的氧氣環境下進行退火30分鐘之X光繞射圖 71 圖4.2 鈮酸鋰薄膜之PFM極化特性分析 72 圖4.3 閘極氧化層COX電容電壓量測特性圖 73 圖4.4 高低頻電容電壓量測特性圖 73 圖4.5 堆疊式增強型元件未施加初始化電壓之汲源極電流-汲源極電壓輸出特性曲線圖 74 圖4.6 堆疊式增強型元件未施加初始化電壓之汲源極電流-閘源極電壓輸出特性曲線圖 74 圖4.7 堆疊式增強型元件施加初始化電壓(12 V)之汲源極電流-汲源極電壓輸出特性曲線圖 75 圖4.8 堆疊式增強型元件施加初始化電壓(12 V)之汲源極電流-閘源極電壓輸出特性曲線圖 75 圖4.9 堆疊式閘極氧化層增強型元件之閘極漏電流-閘源極電壓圖 76 圖4.10 堆疊式閘極氧化層增強型元件之汲極崩潰電壓特性曲線圖 76 圖4.11 氮化鋁鎵厚度為10 nm空乏型元件之汲源極電流-汲源極電壓輸出特性曲線圖 77 圖4.12 氮化鋁鎵厚度為10 nm空乏型元件之汲源極電流-閘源極電壓輸出特性曲線圖 77 圖4.13 氮化鋁鎵厚度為10 nm空乏型負載於閘源極電壓為0 V之汲源極電流-汲源極電壓輸出特性曲線 78 圖4.14 氮化鋁鎵厚度為8 nm、10 nm、12 nm空乏型負載於閘源極電壓為0 V之汲源極電流-汲源極電壓輸出特性曲線 78 圖4.15 反相器電路充放電元件工作形態 79 圖4.16 反相器輸出特性曲線與電流比例關係 79 圖4.17 飽和區操作電流比例5倍的輸出特性曲線 (a)增強型 (b)空乏型 80 圖4.18 飽和區操作電流比例8倍的輸出特性曲線 (a)增強型 (b)空乏型 81 圖4.19 飽和區電流比例22倍的輸出特性曲線 (a)增強型 (b)空乏型 82 圖4.20 電流比例5倍的互補式場效電晶體負載線特性曲線 (a)原輸出特性曲線10V操作 (b)設定偏壓值5V操作 83 圖4.21 電流比例8倍的互補式場效電晶體負載線特性曲線 (a)原輸出特性曲線10V操作 (b)設定偏壓值5V操作 83 圖4.22 電流比例22倍的互補式場效電晶體負載線特性曲線 (a)原輸出特性曲線10V操作 (b)設定偏壓值5V操作 83 圖4.23 電流比例5至22倍的互補式場效電晶體負載線特性趨勢 84 圖4.24 時域之輸入、輸出波型 (a) 5倍 (b) 8倍 (c) 22倍 85 圖4.25 輸出對於輸入波型轉移曲線 (a) 5倍 (b) 8倍 (c) 22倍 86 圖4.26 輸出對於輸入波型轉移曲線於電流比例5倍至22倍之趨勢 87

    第一章
    [1] F. Roccaforte, P. Fiorenza, G. Greco, R. L. Nigro, F. Giannazzo, F. Iu-colano, and M. Saggio, “Emerging trends in wide band gap semicon-ductors (SiC and GaN) technology for power devices,” Microelectron Eng., vol. 187-188, pp. 66-77, 2018.
    [2] R. J. Trew, “SiC and GaN transistors—is there one winner for micro-wave power applications?,” Proc. IEEE Inst. Electr. Electron. Eng., vol. 90, pp. 1032-1047, 2002.
    [3] T. P. Chow and R. Tyagi, “Wide bandgap compound semiconductors for superior high-voltage unipolar power devices,” IEEE Trans. Electron Devices, vol. 41, pp. 1481-1483, 1994.
    [4] D. Jin and J. A. del Alamo, “Methodology for the study of dynamic on-resistance in high-voltage GaN field-effect transistors,” IEEE Trans. Electron Devices, vol. 60, pp. 3190-3196, 2013.
    [5] S. Zhou, M. Liu, H. Xu, Y. Liu, Y. Gao, X. Ding, S. Lan, Y. Fan, C. Gui, and S. Liu, “High-efficiency GaN-based LED with patterned SiO2 cur-rent blocking layer deposited on patterned ITO,” Opt. Laser Technol., vol. 109, pp. 627-632, 2019.
    [6] W. Wang, W. Xie, Z. Deng, H. Yang, M. Liao, J. Li, X. Luo, S. Sun, and D. Zhao, “Performance improvement of GaN based laser diode using Pd/Ni/Au metallization ohmic contact,” Coatings, vol. 9, pp. 291-1-291-15, 2019.
    [7] J. Sun, “Realization of terahertz self-mixing detectors based on Al-GaN/GaN HEMT in field-effect self-mixing terahertz detectors,” Springer, Berlin, Heidelberg, 2016.
    [8] L. F. Eastman, V. Tilak, J. Smart, B. M. Green, E. M. Chumbes, R. Di-mitrov, H. Kim, O. S. Ambacher, N. Weimann, T. Prunty, M. Murphy, W. J. Schaff and J. R. Shealy, “Undoped AlGaN/GaN HEMTs for mi-crowave power application,” IEEE Trans. Electron Devices., vol. 48, pp. 479-485, 2001.
    [9] F. Sacconi, A. D. Carlo, P. Lugli and H. Morkoc, “Spontaneous and pi-ezoelectric polarization effects on the output characteristics of Al-GaN/GaN heterojunction modulation doped FETs,” IEEE Trans. Elec-tron Devices., vol.48, pp. 450-457, 2001.
    [10] I. P. Smorchkova, C. R. Elsass, J. P. Ibbetson, R. Vetury, B. Heying, P. Fini, E. Haus, S. P. DenBaars, J. S. Speck and U. K. Mishra, “Polariza-tion-induced charge and electron mobility in AlGaN/GaN heterostruc-tures grown by plasma-assisted molecular-beam expitaxy,” J. Appl.Phys., vol. 86, pp. 4520-4526, 1999.
    [11] O. Ambacher, B. Foutz, J. Smart, J. R. Shealy, N. G. Weimann, K. Chu, M. Murphy, A. J. Sierakowski, W. J. Schaff and L. F. Eastman, “Two dimensional electron gases induced by spontaneous and piezoelectric polarization in undoped AlGaN/GaN heterostructures,” J. Appl. Phys., vol. 87, pp. 334-344, 2000.
    [12] H. Morkoc, A. D. Carlo and R. Cingolani, “GaN-based modulation doped FETs and UV detectors,” Solid-State Electron., vol. 46, pp. 157-202, 2002.
    [13] R. Dimitrov, M. Murphy, J. Smart, W. Schaff, J. R. Shealy and L. F. Eastman, “Two-dimensional electron gases in Ga-face and N-face Al-GaN/GaN heterostructures grown by plasma-induced molecular beam epitaxy and Metalorganic chemical vapor deposition on sapphire,” J. Appl. Phys., vol. 87, pp. 3375-3380, 2000.
    [14] O. Ambacher, J. Smart, J. R. Shealy, N. G. Weimann, K. Chu, M. Mur-phy, W. J. Schaff and L. F. Eastman, “Two-dimensional electron gases induced by spontaneous and piezoelectric polarization charges in N- and Ga-face AlGaN/GaN heterostructures,” J. Appl. Phys., vol. 85, pp. 3222-3233, 1999.
    [15] M. Miyoshi, M. Sakai, S. Arulkumaran, H. Ishikawa, T. Egawa, M. Tanaka, and O. Oda, “Characterization of different-Al-Content Al-GaN/GaN heterostructures and high-electron-mobility transistors grown on 100-mm-diameter sapphire substrates by metalorganic vapor phase epitaxy,” Jpn. J. Appl. Phys., vol. 43, pp. 7939-7943, 2004.

    第二章
    [1] A. Laposa, J. Jakovenko, and M. Husak, “Temperature dependence of the pyroelectric behaviour in GaN/AlGaN,” The Eighth International Conference on Advanced Semiconductor Devices and Microsystems, Smolenice, pp. 93-96, 2010.
    [2] O. Ambacher, B. Foutz, J. Smart, J. R. Shealy, N. G. Weimann, K. Chu, M. Murphy, A. J. Sierakowski, W. J. Schaff, L. F. Eastman, R. Dimitrov, A. Mitchell, and M. Stutzmann, “Two dimensional electron gas induced by spontaneous and piezoelectric polarization in undoped and doped AlGaN/GaN heterostructures,” J. Appl. Phys., vol. 87, pp. 334-344, 2000.
    [3] I. P. Smorchkova, C. R. Elsass, J. P. Ibbetson, R. Vetury, B. Heying, P. Fini, E. Haus, S. P. DenBaar, J. S. Speck, and U. K. Mishra, “Polariza-tion-induced charge and electron mobility in AlGaN/GaN heterostruc-tures grown by plasma-assisted molecular-beam epitaxy,” J. Appl. Phys., vol. 86, pp. 4520-4526, 1999.
    [4] H. X. Guang, Z. D. Gang, and J. D. Sheng, “Formation of two-dimensional electron gas at AlGaN/GaN heterostructure and the derivation of its sheet density expression,” Chin. Phys. B, vol. 24, 067301, 2015.
    [5] M. A. Khan, M. S. Shur, J. N. Kuzunia, Q. Chen, J. Burm and W. Schaff, “Temperature activated conductance in GaN/AlGaN heterostructure field effect transistors operating at temperatures up to 300oC,” Appl. Phys. Lett., vol. 66, pp. 1083-1085, 1995.
    [6] J. A. Grenko, C. L. Reynolds, R. Schlesser, K. Bachmann, Z. Rietmeier, Robert F. Davis, and Z. Sitar, “Selective etching of GaN from Al-GaN/GaN and AlN/GaN structures,” Mrs. Internet J. Nitride Semicond. Res., vol. 9, pp. 1-8, 2004.
    [7] L. H. Huang, S. H. Yeh, C. T. Lee, H. Tang, J. Bardwell, and J. B. Webb, “AlGaN/GaN metal–oxide–semiconductor high-electron mobility tran-sistors using oxide insulator grown by photoelectrochemical oxidation method,” IEEE Electron Device Lett., vol. 29, pp. 284-286, 2008.
    [8] E. H. Chen, D. T. Mclnturff, T. P. Chin, M. R. Melloch, and J. M. Woodall, “Use of annealed low-temperature grown GaAs as a selective photoetch-stop layer,” Appl. Phys. Lett., vol. 68, pp. 1678-1680, 1996.
    [9] L. H. Huang and C. T. Lee, “Investigation and analysis of AlGaN MOS devices with an oxidized layer grown using the photoelectrochemical oxidation method,” J. Electrochem. Soc., vol. 154, pp. 862-866, 2007.
    [10] W. D. Kingery, H. K. Bowen and D. R. Uhlmann, “Introduction to Ce-ramics,” 1976.
    [11] M Veithen and Ph. Ghosez, “First-principles study of the dielectric and dynamical properties of lithium niobate,” Phys. Rev. B, vol. 65, pp. 214302-1-214302-12, 2002.
    [12] L. Z. Hao, J. Zhu and Y. Liu, S. Wang, H. Zeng, X. Liao, Y. Liu, H. Lei, Y. Zhang, W. Zhang and Yanrong, “Integration and electrical properties of epitaxial LiNbO3 ferroelectric film on n-type GaN semiconductor,” Thin Solid Films, vol. 520, pp. 3035-3038, 2012.
    [13] P. J. Hansen, Y. Terao, Y. Wu, R. A. York, U. K. Mishra, and J. S. Speck, “LiNbO3 thin film growth on (0001)-GaN,” J. Vac. Sci. Technol. B., vol. 23, pp. 162-167, 2005.
    [14] L. Z. Hao, J. Zhu and Y. R. Li, “Integration between LiNbO3 ferroelec-tric film and AlGaN/GaN system,” Mater. Sci. Forum., vol. 687, pp. 303-308, 2011.
    [15] K. Nassau, H. J. Levinstein and G.M. Loiacono, “Ferroelectric lithium niobate. 2. preparation of single domain crystals,” J. Phys. Chem. Sol-ids., vol. 27, pp. 989-996, 1966.
    [16] S. C. Abrahams, J. M. Reddy and J. L. Bernstein, “Ferroelectric lithium niobate. 3. single crystal X-ray diffraction study at 24°C,” J. Phys. Chem. Solids., vol. 27, pp. 997-1012, 1966.
    [17] D. L. Staebler and J. J. Amodei, “Thermally fixed holograms in LiNbO3,” Ferroelectrics, vol. 3, pp. 107-113, 1972.
    [18] M. G. Clark, F. J. DiSalvo, A. M. Glass and G. E. Peterson, ” Electronic structure and optical index damage of iron‐doped lithium niobate,” J. Phys. Chem. Solids., vol. 59, 12, pp. 6209-6219, 1973.
    [19] S. Tan, T. Gilbert, C. Y. Hung, and T. E. Schlesinger, “Sputter deposited c-oriented LiNbO3 thin films on SiO2,” J. Appl. Phys., vol.79, 1996.
    [20] G. Namkoong,K. K. Lee, S. M. Madison, W. Henderson, S. E. Ralph and W. A. Doolittle, “III-nitride integration on ferroelectric materials of lithium niobate by molecular beam epitaxy,” Appl. Phys. Lett., vol. 87, pp. 171107, 2005.
    [21] X. Q. Chen, H. Yamada, Y. Terai, T. Horiuchi, K, Matsushige and P. S. Weiss, “Strong substrate effect in local poling of ultrathin ferroelectric polymer films,” J. Vac. Sci. Technol. B., vol. 353, pp. 259-263, 2005.
    [22] M. Lenzlinger and E. H. Snow, “Fowler-Nordheim tunneling into ther-mally grown SiO2,” J. Appl. Phys., vol. 40, pp. 278-283, 1969.
    [23] J. J. Lee and D.-L. Kwong, “Metal nanocrystal memory with high-κ tunneling barrier for improved data retention,” IEEE Trans. Electron Devices, vol. 52, pp. 507–511, 2005.H. C. Sánchez, F. Z. Rincón, and R. T. Torres, “Alternative determination of the intrinsic cut-off frequency applied to a degraded MOSFET,” IEEE Microw. Wirel. Compon. Lett., vol. 26, pp. 693-695, 2016.
    [24] Y. Cai, Z. Cheng, W. C. W. Tang, K. M. Lau, and K. J. Chen, “Mono-lithically integrated enhancement/depletion-mode AlGaN/GaN HEMT inverters and ring oscillators using CF4 plasma treatment,” IEEE Trans. Electron Devices, vol. 53, pp 2223-2230, 2006.
    [25] M. Kanamura, T. Ohki, T. Kikkawa, K. Imanishi, T. Imada, A.Yamada, and N. Hara, “Enhancement-mode GaN MIS-HEMTs with n-GaN/i-AlN/n-GaN triple cap layer and high-k gate dielectrics,” IEEE Electron Device Lett. , vol. 31, pp 189-191, 2010.

    第三章
    [1] P. E. Riley, “Plasma etching of aluminum metallizations for ultra-largescale integrated circuits,” J. Electrochem. Soc., vol. 140, pp. 1518-1522, 1993.
    [2] S. K. Ghandhi, “VLSI fabrication principles,” John Wiley & Sons., pp. 635, 1994.
    [3] C. T. Lee, Y. J. Lin, and C. H. Lin, “Nonalloyed ohmic mechanism of TiN interfacial layer in Ti/Al contact to (NH4)2Sx-treated n-type GaN layers,” J. Appl. Phys., vol. 92, pp. 3825-3829, 2002.
    [4] E. H. Rhoderick, “Metal-semiconductor contacts,” IEEE Proceedings I - Solid-State and Electron Devices, vol. 129, pp. 1-14, 1982.
    [5] Q. Z. Liu, L. S. Yu, F. Deng, S. S. Lau, Q. Chen, J. W. Yang, and M. A. Khan, “Study of contact formation in AlGaN/GaN heterostructures,” Appl. Phys. Lett., vol. 71, pp. 1658-1660, 1997.
    [6] M. E. Lin, Z. Ma, F. Y. Huang, Z. F. Fan, L. H. Allen, and H. Morkoç, “Low resistance ohmic contacts on wide band-gap GaN,” Appl. Phys. Lett., vol. 64, pp. 1003-1005, 1994.
    [7] C. T. Lee and H. W. Kao, “Long-term thermal stability of Ti/Al/Pt/Au Ohmic contacts to n-type GaN,” Appl. Phys. Lett., vol. 76, pp. 2364-2366, 2000.
    [8] M. Kanamura, T. Ohki, T. Kikkawa, K. Imanishi, T. Imada, A. Yamada and N. Hara, “Enhancement-mode GaN MIS-HEMTs with n-GaN/i-AlN/n-GaN triple cap layer and high-k gate dielectrics,” IEEE Electron Device Lett., vol. 31, pp 189-191, 2010.
    [9] Y. L. Chiou and C. T. Lee, “Band alignment and performance im-provement mechanisms of chlorine-treated ZnO-Gate AlGaN/GaN met-al-oxide-semiconductor high-electron mobility transistors,” IEEE Trans. Electron Devices., vol. 58, pp 3869-3876. 2011.
    [10] J. S. Moon, D. Wong, T. Hussain, M. Micovic, P. Deelan, M. Hu, M. Antcliffe, C. Ngo, P. Hashimoto, and L. McCray, “Submicron enhance-ment-mode AlGaN/GaN HEMTs,” 60th DRC. Conference Digest Device Research Conference, pp. 23-24, 2002.
    [11] A. Kumar, N. Gupta, and R. Chaujar, “TCAD RF performance investi-gation of transparent gate recessed channel MOSFET,” Microelectron. J., vol. 49, pp. 36-42, 2016.
    [12] C. T. Lee, C. L. Yang, C. Y. Tseng, J. H. Chang, R. Y. Horng “GaN-based enhancement-mode metal–oxide–semiconductor high-electron mobility transistors using LiNbO3 ferroelectric insulator on gate-recessed structure,” IEEE Trans. Electron Devices, vol. 62, pp. 2481-2487, 2015.
    [13] O. Plot, A. Malaurie, and J. Machet, “Experimental and theoretical studies of coating thickness distributions obtained from high rate elec-tron beam evaporation sources,” Thin Solid Films, vol. 293, pp. 124-132, 1997.
    [14] O. G. M. Saavedraa, M. E. S. Vergara, A. O. Rebollo, and R. O. Martınez, “Electrical and optical properties of Jager-nickel (II)-based molecular-material thin films prepared by the vacuum thermal evapora-tion technique,” J. Phys. Chem. Solids., vol. 68, pp. 1571-1582, 2007.
    [15] J. W. Son, S. S. Orlov, B. Phillips and L. Hesselink, “Pulsed laser dep-osition of single phase LiNbO3 thin film waveguides,” J. Electroceram., vol. 17, pp. 591-595, 2006.
    [16] S. Higuchi and I. Tsukada, “Pulsed-laser deposition of LiNbO3 thin films at low oxidation gas pressure with pure ozone,” Jpn. J. Appl. Phys., vol. 42, pp. L1066-L1068, 2003.
    [17] J. Gonzalo, C. N. Afonso, J. M. Ballesteros, A. Grosman and C. Ortega, “Li deficiencies in LiNbO3 films prepared by pulsed laser deposition in a buffer gas,” J. Appl. Phys., vol. 82, pp. 3129-3133, 1997.

    第四章
    [1] C. T. Lee, C. L. Yang, C. Y. Tseng, J. H. Chang, R. Y. Horng “GaN-based enhancement-mode metal–oxide–semiconductor high-electron mobility transistors using LiNbO3 ferroelectric insulator on gate-recessed structure,” IEEE Trans. Electron Devices, vol. 62, pp. 2481-2487, 2015.
    [2] T. Kamimura, D. Krishnamurthy, A, Kuramata, S. Yamakoshi, and M. Higashiwaki, “Epitaxially grown crystalline Al2O3 interlayer on β-Ga2O3 (010) and its suppressed interface state density,” J. Appl. Phys., vol. 55, pp. 1202B5-1-1202B5-7, 2016.
    [3] H. Y. Liu, C. S. Lee, F. C. Liao, W. C. Hsu, B. Y. Chou, J. H. Tsai, and H. Y. Lee, “A comparative studies on AlGaN/GaN MOS-HEMTs with stacked La2O3/Al2O3 dielectric structures,” Electrochem Soc Interface, vol. 3, pp. N115-N119, 2014.
    [4] B. Lee, C. Kirkpatrick, Y. H. Choi, X. Y. Y, A. Q. H, and V. Misra, “Normally off AlGaN/GaN MOSHFET using ALD SiO2 tunnel dielec-tric and ALD HfO2 charge storage layer for power device application,” Phys. Status Solidi C., vol. 9, pp. 868-870, 2012.
    [5] H. Y. Lee, C. H. Lin, C. C. Wei, J. C. Yang, E. Y. Chang, and C. T. Lee, “AlGaN/GaN enhancement-mode MOSHEMTs utilizing hybrid gate-recessed structure and ferroelectric charge trapping/storage stacked LiNbO3/HfO2/Al2O3 structure,” IEEE Trans Electron Devices, vol. 68, pp. 3768-3774, 2021.
    [6] L. H. Huang, and C. T. Lee, “Investigation and analysis of AlGaN MOS devices with an oxidized layer grown using the photoelectrochemical oxidation method,” J. Electrochem. Soc., vol. 154, pp. H862-H866, 2007.
    [7] S. Arulkumaran, T. Egaway, L. Selvaraj, and H. Ishikawa, “On the ef-fects of gate-recess etching in current-collapse of different cap layers grown AlGaN/GaN high-electron-mobility-transistors,” Jpn. J. Appl. Phys., vol. 45, pp. 220-223, 2006.
    [8] N. Weste, D. M. Harris, CMOS VLSI Design, 3rd, Pearson Education, 2004.
    [9] Y. Cai, Z. Cheng, W. C. W. Tang, K. M. Lau and K. J. Chen, “Mono-lithically integrated enhancement/depletion-Mode AlGaN/GaN HEMT inverters and Ring oscillators using CF4 plasma treatment,” IEEE Trans. Electron Devices, vol. 53, pp. 2223-2230, 2006.
    [10] D. A. Hodges, H. G. Jackson, R. A. Saleh, Analysis and design of digital Integrated Circuits, 3rd, McGraw-Hill Science Engineering, 2003.

    下載圖示
    2026-09-14公開
    QR CODE