通過施加溶液在矽表面上構建由 5,10,15,20-四（4-吡啶基）-21H,23H-卟啉（TPyP）分子和銀離子金屬連接體組成的層狀結構銀離子-卟啉納米膜基於逐層增長的方法。銀介導的卟啉層狀結構組裝在通過納米球光刻與有機矽烷自組裝技術製備的有機矽烷納米孔內。使用兩種類型的有機矽烷分子來形成自組裝單層。此外，有四種類型的有機矽烷分子用於功能化有機矽烷納米孔。採用原子力顯微鏡 (AFM)、掃描電子顯微鏡 (SEM) 和紫外-可見光譜測量來檢查納米膜的特性。結果很好地證明了生產有機矽烷自組裝單層的簡便策略。此外，有機矽烷納米孔薄膜可用於表面選擇性應用。最後，還介紹了一種簡單的製備方法來製備銀介導的卟啉層結構納米膜，這對於金屬有機框架在納米器件中的潛在應用的未來使用至關重要。

Layer-structured silver ion-porphyrin nanofilms consisting of 5,10,15,20-Tetra(4-pyridyl)-21H,23H-porphine (TPyP) molecules, and silver ion metal linkers were constructed on a silicon surface by applying a solution-based layer-by-layer growth approach. The silver-mediated porphyrin layered structure was assembled inside the organosilane nanoholes prepared by nanosphere lithography coupled with the organosilane self-assembly technique. Two types of organosilane molecules were utilized to form the self-assembled monolayers. Besides, there are four types of organosilane molecules that were used to functionalize the organosilane nanopores. atomic force microscopy (AFM), scanning electron microscopy (SEM) and UV-Visible spectroscopy measurements were employed to examine the nanofilm characteristics. The results provide an excellent demonstration of a facile strategy to produce organosilane self-assembled monolayers. Furthermore, the organosilane nanohole thin films can be employed for surface selectivity applications. Lastly, an easy fabrication method to prepare silver-mediated porphyrin layer-structured nanofilm was also introduced, which is crucial for the future use of metal-organic frameworks in potential applications in nanodevices.

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