| 研究生: |
楊幼如 Yang, Yu-Ju |
|---|---|
| 論文名稱: |
以奈米軟水鋁石合成銪鏑共摻鋁酸鍶螢光體初探 A Preliminary Study on the Synthesis of SrAl2O4:Eu, Dy Phosphor from Nano-Sized Boehmite Dispersion |
| 指導教授: |
申永輝
Shen, Yun-Hwei |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 資源工程學系 Department of Resources Engineering |
| 論文出版年: | 2006 |
| 畢業學年度: | 94 |
| 語文別: | 中文 |
| 論文頁數: | 85 |
| 中文關鍵詞: | 鋁酸鍶 、螢光體 、軟水鋁石 |
| 外文關鍵詞: | phosphor, boehmite, strontium aluminate |
| 相關次數: | 點閱:89 下載:2 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
近年來人們對環境污染及能源資源短缺等問題日益重視,促使許多科學家致力於研發低耗能、高光效、無污染的新型「綠色」發光材料。而鋁酸鍶長餘輝發光材料因其具有優異的蓄光-發光性能,為目前研究發展的重點。
目前SrAl2O4:Eu, Dy的合成以固態反應法為主,傳統固態反應法合成粉末雖然製程容易、成本低且容易量產,但得到的粉末易受原料混合不均影響而需要較高的反應溫度使反應完成。因此本研究欲改善傳統固態反應法原料混合不均及高溫燒的問題,利用漿料中之boehmite顆粒均勻地被陽離子所包圍之狀態下,形成穩定之凝膠而製備出混合均勻之前導粉末。
經實驗結果可知,以硝酸鍶為起始原料合成SrAl2O4螢光體之反應溫度較氯化鍶低,且發光性質佳,當各原料比例為Sr(NO3)2:AlOOH:Eu(NO3)3:Dy(NO3)3:H3BO3 = 0.94:2:0.02:0.04:0.2時,於還原氣氛下、1100℃持溫4小時,可以得到具有最佳餘輝性質之螢光體,較傳統使用α-Al2O3之固態反應法合成溫度低了約100~200℃。
In recent years people pay more attention to the problems of environmental pollution and energy resources shortage, so that scientists are devoted to the study of green phosphors which are safe, high-efficiency, and clean. Strontium aluminate becomes the focal point of luminescence study because of its excellent properties on storing up and radiating of light.
At present SrAl2O4:Eu,Dy phosphors are mainly prepared by the solid-state process which is more feasible than others in terms of operation and large-scale production. However, for solid-state process the raw materials are usually not mixed well and very high temperature is needed to synthesize the final powder. In order to solve those problems, a process using boehmite suspension to form a stable and well mixed gel by mixing with aqueous cations was investigated in this thesis.
The results of this study indicated that strontium nitrate is the better choice than strontium chloride to use for synthesizing SrAl2O4:Eu,Dy phosphors with better luminescent characteristics and lower forming temperature. At Sr(NO3)2 : AlOOH : Eu(NO3)3 : Dy(NO3)3 : H3BO3 = 0.94:2:0.02:0.04:0.2, we can synthesize the Sr0.94Al2O4:Eu0.02,Dy0.04 phosphors with best luminescent characteristics. The final powders was obtained after sintering at 1100℃ for 4 hours which is 200~300℃ lower than that obtained by the traditional solid-state process.
[1] Shigeo Shionoya, PHOSPHOR HANDBOOK, CRC Press LLC, New York, U.S.A, 1999.
[2] Nemoto&Co., LTd, Japanese Patent 751505, Radioluminescent Material, 1974.
[3] 工業技術研究院,電子產業用螢光材料之應用調查,pp.2-3,1992.
[4] H. Lange, U.S. Patent 3294699, Luminescent Europium Activated Strontium Aluminate, 1966.
[5] F.C. Palilla, A. K. Levine,and M. R. Tomkus, Fluorescent Properties of Alkaline Earth Aluminates of the Type MAl2O4 Activated by Divalent Europium, J. Electrochem. Soc., 115, pp.642-644, 1968.
[6] T. Matsuzawa, Y. Aoki, N. Takeuchi, and Y. Murayama, A New Long Phosphorescent Phosphor with High Brightness, SrAl2O4:Eu2+,Dy3+, J. Electrochem. Soc., 143, pp.2670–2673, 1996.
[7] 李碩重,照明設計學,全華科技股份有限公司,1993。
[8] 陳一誠,銪鏑共摻鋁酸鍶系長餘輝螢光體之溶膠/凝膠合成、雜質摻雜與其餘輝與熱發光特性之研究,國立交通大學應用化學系博士論文,2001。
[9] F. P. Glasser, and L. S. Dent Glasser, Crystal Chemistry of Some AB2O4 Compounds, J. Am. Ceram. Soc., 46, pp.377-380, 1963.
[10] Von A. R. Schulze, and H. Mller-Buschbauch, Zur Struktur von monoklinem SrAl2O4, Z. Anorg. Allg. Chem. 475, pp.205-210, 1981.
[11] Levin, E.M., Robbins, C.R. and McMurdie, H.F., Phase Diagrams for Ceramists, ed. M.K. Reser, American Ceramic Society, Colombus, OH, Fig. 294, 1964.
[12] T. Katsumata, T. Nabae, K. Sasajima, S. Kumuro, and T. Morikawa, Characteristics of Strontium Aluminate Crystals Used for Long-duration Phosphors, J. Amer. Ceram. Soc., 81, pp.413-416, 1998.
[13] F. Clabau, X. Rocquefelte, S. Jobic, P. Deniard, M. –H. Whangbo, A. Garcia, and T. Le Mercier, Mechanism of Phosphorescence Appropriate for the Long-Lasting Phosphors Eu2+-Doped SrAl2O4 with Codopants Dy3+ and B3+, Chemistry of Materials, 17, 15, pp.3904-3912, 2005.
[14] R. D. Shannon, Revised Effective Ionic Radii and Systematic Studies of Interatomic Distances in Halides and Chalcogenides, Acta Cryst., A32, pp.751-767, 1976.
[15] 溫惠玲,由Boehmite製得之氧化鋁粉末的θ→α-Al2O3相轉換,國立成功大學資源工程研究所博士論文,2000。
[16] R. Morrell, Handbook of Properties of Technical and Engineering Ceramics, Part2 Data Reviews-Selection 1:High-Alumina Ceramic, National Physical Laboratory, HMSO, London, 1987.
[17] 李志明,氧化鋁鍶摻雜釤螢光體之發光特性研究,國立台北科技大學材料及資源工程系碩士論文,2003。
[18] 楊智量,藉pH值控制混合之固相反應製備的YAG:Ce粉體分析及其螢光性質,國立成功大學資源工程研究所碩士論文,2005。
[19] G. Blasse, B. C. Grabmaier, Luminescent Materials, Springer-Verlag Telos, pp.1-37, 1994.
[20] W. Jia, H. Yuan, L. Lu, H. Liu, and W.M. Yen, Phosphorescent Dynamics in SrAl2O4:Eu2+, Dy3+ Single Crystal Fibers, J. Luminescence, 76-77, pp.424-428, 1998.
[21] D. Wang, Q. Yin, Y. Li, and M. Wang, Concentration Quenching of Eu2+ in SrO•Al2O3:Eu2+ Phosphor, J. Luminescence, 97, pp.1-6, 2002.
[22] Phosphor Research Society, Phosphor Handbook, CRC Press, Boca Raton, 1999.
[23] G. Blasse and A. Bril, Philips Res. Rep., 23, 201, 1968.
[24] 唐明道、李長寬、高志武,SrAl2O4:Eu2+的長餘輝發光特性的研究,發光學報,16,pp.51-56,1995。
[25] D. Haranath, Virendra Shanker, Harish Chander, and Pooja Sharma, Studies on the Decay Characteristics of Strontium Aluminate Phosphorn on Thermal Treatment, Materials Chemistry and Physics, 78, pp.6-10, 2002.
[26] J. Geng and Z. Wu, Preparation of SrAl2O4:Eu, Dy Phosphor and Its Properties, Chinese Journal of Luminescence, 23, pp.247-250, 2002.
[27] M. Wang, W. Dong, and G. Lu, Research on Fluorescence Spectra and Structure of Single-Phase 4SrO.7Al2O3: Eu2+ Phosphor Prepared by Solid-state Reaction method, Journal of Materials Science and Engineering, 57, pp.18-23, 1998.
[28] T. Peng, H. Liu, H. Yang, and C. Yan, Synthesis of SrAl2O4:Eu, Dy Phosphor Nanometer Powders by Sol-Gel Porcesses and Its Optical Properties, Materials Chemistry and Physics, 85, pp.68-72, 2004.
[29] P. Zhang and Y. Shen, Study on the Solid State Reaction Process and Phase Forming Law of the nanometer Luminescent Powers of SrAl2O4:Eu2+, Dy3+ with Sol-Gel Synthesis, Journal of Hebei Institute of Technology, 26, pp.88-91, 2004.
[30] X. Wang, H. Lou, Y. Tang, J. Yang, and C. Shi, Study on Sol-Gel Synthesis of Strontium Aluminates : Eu and Its Luminescent Characteristics, Journal of Zhejiang University(Science Edition), 31, pp.66-69, 2004.
[31] T. R. N. Kutty, R. Jagannathan and R. P. Rao, Luminescence of Eu2+ in Strontium Aluminates Prepared by the Hydrothermal Method, Mater. Res. Bull., 25, pp.1355-1362, 1990.
[32] C. Zhou, Z. Lu, Y. Dai, and B. Wang, Study on Combustion Synthesis of Eu2+, Dy3+ Co-doped Strontium Aluminate Long Persistence Phosphors, New Chemical Materials, 32, pp.33-36, 2004.
[33] J. Li, K. Qiu, X, Lai, and Q. Li, Synthesis of SrAl2O4:Eu2+, Dy3+ Phosphors with Long-afterglow by Rapid Combustion, Journal of the Chinese Ceramic Society, 32, pp.1560-1562, 2004.
[34] R. J. Pet, M. van den Nieuwenhof and J. P. H. M. Duisters, U.S. Patent 4795588, Method of Preparing a Luminescent Eu2+ Activated Strontium Aluminate, 1989.
[35] M. R. Royce, H. Tamaki, and Y. Murazaki, U.S. Patent 5376303, Long Decay Phosphors, 1994.
[36] D. Wang, Q. Yin, Y. Li, and M. Wang, Influence of B2O3 on Matrix Forming Process and Luminescent Properties of SrO∙Al2O3:Eu2+ Phosphor, J. Electrochem. Soc., 149, pp.H65-H67, 2002.
[37] Abanti Nag and T. R. N. Kutty, Role of B2O3 on the Phase Stability and Long Phosphorescence of SrAl2O4:Eu, Dy, Journal of Alloys and Compounds, 354, pp.221-231, 2003.
[38] Levin, E.M., Robbins, C.R. and McMurdie, H.F., Phase Diagrams for Ceramists v.VI, ed. M.K. Reser, American Ceramic Society, Colombus, OH, Fig. 6434, 1979.
[39] X. Zhang, Z. Bai, X. Guan, X. Wang, W. Wang, H. Sun, Z. Cao, J. Du, and Y. Guo, Preparation of Long Persistent Phosphorescence SrAl2O4:Eu2+, Dy3+ Phosphors by Solid State Reaction and Characterization, Rare Metal Materials and Engineering, 32, 5, pp.379-382, 2003.
[40] M. Nogami, T. Yamazaki, and Y. Abe, Fluorescence Properties of Eu3+ and Eu2+ in Al2O3–SiO2 Glass, J. Luminescence, 78, pp.63-68, 1998.
[41] 宋慶梅、黃錦斐、吳茂鈞,鋁酸鍶銪的合成與發光的研究,發光學報,12,2,pp.144,1991。
[42] 王紅梅、龐明、張繼紅、王永錢、胡小華、楊應國、袁曦明,稀土長餘輝發光材料SrAl2O4:Eu2+,Dy3+的製備及性能研究,地球科學-中國地質大學學報,29,1,pp.50-54,2004。