本研究主要針對重型柴油引擎進行穩態測試，並探討柴油引擎於不同油品及加裝有無氧化觸媒之濾煙器(DOC+DPF/DPF)之毒性污染物排放特性，其中燃料油品包含超級柴油(B2)、10%生質柴油(B10)及20%生質柴油(B20)，毒性污染物測試項目包含多環芳香烴(PAHs)、戴奧辛/呋喃(PCDD/Fs)及多氯聯苯(PCBs)。
實驗結果顯示：B2、B10與B20之總PAHs排放濃度分別為250、223及130 μg/Nm3；總PCDD/F I-TEQ排放濃度分別為9.12、3.75及1.66 pg I-TEQ/Nm3；總PCB TEQ排放濃度分別為0.965、0.598及0.212 pg WHO-TEQ/Nm3。以B2測試，比較柴油引擎加裝DOC+DPF及DPF後對排放廢氣之毒性污染物影響：加裝DOC＋DPF對排放廢氣之總PAHs、總PCDD/F I-TEQ及總PCB TEQ比值分別為0.4、3.4及3.7，於加裝DPF後則分別為0.2、1.4及9.7。
在氣相與粒狀物相分佈上，以B2測試之結果顯示，油品對有毒污染物排放廢氣之組成主要以氣相為主，分別為總PAHs之99.95%、總PCDD/Fs 之99.3%及總PCBs之94.9%；在使用DPF後，則分別為總PAHs之94.4%、總PCDD/Fs之48.1%及總PCBs之4.7%，結果不盡相同。
本實驗結果顯示使用生質柴油之柴油引擎隨著生質柴油比例之增高有降低廢氣中有機毒性污染物濃度之趨勢，當柴油引擎加裝DOC+DPF及DPF後對排放廢氣之總PAHs濃度皆有下降趨勢，但對總PCDD/F I-TEQ及總PCB TEQ濃度則有增加之趨勢。

The emission of toxic pollutants from the heavy-duty diesel engine (HDDE) on a dynamometer by varying fuels and deploying diesel particle filter (DPF) with diesel oxidation catalyst (DOC) or without (DOC+DPF/DPF) was investigated. These fuels included Super diesel (B2), 10% biodiesel in diesel (B10) and 20% biodiesel in diesel (B20). The toxic pollutants including Polycyclic Aromatic Hydrocarbons (PAHs), Polychlorinated dibenzo-p-dioxins and Polychlorinated dibenzofurans (PCDD/Fs), and Polychlorobiphenyls (PCBs) which were emitted from HDDE exhaust.
The emission of total-PAH concentration of B2, B10, B20 were 250、223 and 130 μg/Nm3, respectively. The emission of total-PCDD/Fs I-TEQ concentration of B2, B10, B20 were 9.12、3.75 and 1.66 pg I-TEQ/Nm3, respectively.. The emission of total-PCB TEQ concentration of B2, B10, B20 were 0.965、0.598 and 0.212 pg WHO-TEQ/Nm3, respectively.
Comparing the influence of deploying DOC+DPF and DPF on the toxic pollutants emitted from the diesel engine fueling with B2: after deploying DOC+DPF, the influence ratio was 0.4 for total-PAHs, 3.7 for total-PCDD/Fs I-TEQ and 3.7 for total-PCBs TEQ; after deploying DPF only, the effect ratio was 0.2 for total-PAH, 1.4 for total-PCDD/Fs I-TEQ and 9.7 for total-PCBs TEQ
In particle/gas partition, the toxic pollutant in B2 primarily consist in gaseous phase: the proportion in gaseous phase was 99.95% for total-PAHs, 99.3% for total-PCDD/Fs and 94.9% for total-PCBs. After deploying DPF, the proportion in gaseous phase was 94.1% for total-PAHs, 48.1% for total-PCDD/Fs and 4.7% for total-PCBs.
In this study, increasing the proportion of biodiesel in the fuel did reduce the toxic pollutant concentration in the exhaust of the diesel engine. However, it would reduce total-PAHs concentrations in the exhaust of the diesel engine both by deploying DOC+DPF and DPF, but increase total-PCDD/Fs I-TEQ and total-PCBs TEQ concentrations in the exhaust of the diesel engine.

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