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研究生： 劉泓甫
Liu, Hong-Fu
論文名稱： 界面電荷分離對并四苯亞能隙有機發光二極體的影響
The Influcence of the interface charge separation on sub-bandgap emission Tetracene Oraganic Light-Emitting Diodes
指導教授： 郭宗枋
Guo, Tzung-Fang
學位類別： 碩士
Master
系所名稱： 理學院 - 光電科學與工程學系
Department of Photonics
論文出版年： 2025
畢業學年度： 113
語文別： 中文
論文頁數： 126
中文關鍵詞： 亞能隙發光 、三重態-三重態湮滅上轉換 、電荷轉移 、磁電致發光效應 、界面電荷分離 、Forster 能量轉移
外文關鍵詞： sub-bandgap emission, triplet-triplet annihilation upconversion, charge transfer, magneto-electroluminescence, interface charge separation, forster energy transfer
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    • 摘要 I Extended Abstract II 致謝 VIII 目錄 IX 圖目錄 XII 第一章 研究領域與動機 1 1.1 有機半導體 1 1.2 有機發光二極體 2 1.3 亞能隙有機放光二極體 7 1.3.1 亞能隙有機放光二極體機制 16 1.3.2 Charge transfer state的形成 17 1.3.3有機二極體中分子與分子之間的能量傳遞 18 1.3.4影響亞能隙放光強弱的因素 20 1.4研究動機 23 1.5章節總結 23 第二章 有機材料激發態與磁場效應 24 2.1 有機自旋電子學的發展與應用 24 2.2 有機材料中所形成的激發態 34 2.3 建構物理模型 37 2.3.1 軌道自旋耦合效應(Spin-orbit coupling, SOC) 37 2.3.2超精細結構作用(Hyperfine interaction, HFI) 38 2.3.3 塞曼分裂(Zeeman Splitting) 39 2.4 磁場效應 40 2.4.1 極化子對模型(Polaron-pair model) 42 2.4.2 單重態裂變及三重態-三重態湮滅 43 2.5 章節總結 46 第三章 實驗製程與量測分析方法 47 3.1 製程介紹 47 3.1.1基板製備過程 48 3.1.2基板清潔 52 3.2 有機發光二極體元件製程 53 3.3 元件量測 57 3.3.1材料吸收 57 3.3.2 元件電性 57 3.3.3電致發光及光致發光光譜 58 3.3.4磁場效應架設 59 3.3.5磁場效應分析 61 第四章 亞能隙有機發光二極體中的界面電荷分離 63 4.1 亞能隙發光元件機制 63 4.1.1 擁有TTA機制的材料 64 4.1.2 來自界面電荷分離的影響 67 4.1.3 章節小結 70 4.2 與界面電荷分離競爭單重激發態(S1) 71 4.2.1 釐清混蒸元件機制 75 4.2.2增強FRET效果 79 4.2.3章節小結 80 4.3 調整混蒸位置與界面的距離 81 4.3.1 章節小結 88 4.4 阻擋界面電荷分離 89 4.4.1 章節小結 98 4.5 嘗試進一步優化亞能隙發光元件 99 第五章 結論與未來工作 101 5.1 結論 101 5.2 未來工作 102 參考文獻 103

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