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研究生: 涂朝亮
Tu, Chao-Liang
論文名稱: 鉬斜向奈米磊晶成長與表面特性之研究
Tilt growth and surface of Mo nanocrystal
指導教授: 黃榮俊
Huang, Jung-Chun
學位類別: 碩士
Master
系所名稱: 理學院 - 物理學系
Department of Physics
論文出版年: 2006
畢業學年度: 94
語文別: 中文
論文頁數: 88
中文關鍵詞: 階梯表面原子階梯自組織傾斜成長掃描穿隧顯微鏡
外文關鍵詞: tilt growth, Mo, step surface, self assemble, atomic step, scanning tunneling microscope
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  • 本論文主要是研究Mo(100)成長於Al2O3(1-102)基板上時,磊晶結構與表面形貌將會受到Mo(100)和Al2O3(1-102)之間的三維晶格匹配和張力釋放的影響,而產生一個傾斜成長的自組織奈米階梯表面。研究中我們藉由RHEED 的繞射條紋來分析Mo(100)的表面磊晶結構特性、利用X-ray 繞射儀來分析Mo(100)的磊晶結構、薄膜與基板間的傾斜角度以及薄膜厚度與晶格應力的關係。最後利用STM 來分析Mo 階梯表面形貌與特性。藉由成長溫度和厚度等參數的控制,我們成功的在溫度1000°C 和厚度100Å 的條件下成長出傾斜成長的自組織奈米階梯表面,此奈米階梯的平台寬度約20Å~60Å,是個階梯密度非常高的自組織結構。

    We have investigated the growth of surface nanostructures on a Mo(100)/Al2O3(1-102) film system. The lattice structure and surface morphology will be affected by the 3D lattice match and the tensile relaxation between Mo(100) film and Al2O3(1-102) substrate. Here we use the RHEED
    diffraction pattern to analyze the characteristic of surface lattice structures and then use X-ray diffraction to analyze the lattice structure, the tilt angle between film and substrate, and the relationship between the film thickness and lattice stress. At last we use STM to observe the morphology and characteristic of the step surface. We take advantage of controlling the parameters such as growth temperature and film thickness under the conditions of 1000°C and 100Å. Finally we successfully obtain the self-assemble nanosteps surface which is with tilt growth. The terraces width of these nanosteps are about 2nm~6nm and it’s obviously a highly density of self-assemble nanosteps.

    第一章 導論 1-1 前言⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯  1 1-2 文獻回顧⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯  4 1-3 研究動機⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯  14   Reference⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯  15 第二章 分子束磊晶 2-1 分子束磊晶系統⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯ 16 2-2 薄膜磊晶成長模式⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯ 22 2-3 實驗步驟⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯  25   Reference⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯  29 第三章 樣品分析技術 3-1 RHEED 反射式高能電子繞射儀⋯⋯⋯⋯⋯⋯⋯⋯⋯ 30 3-2 X-ray 繞射儀⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯  34 3-3 STM 掃描穿隧顯微鏡⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯ 36   Reference⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯  42 第四章 實驗結果與討論 4-0 前言⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯    43 4-1 Al2O3(1-102)/Mo(100)斜向奈米磊晶的形成原因⋯45 4-2 RHEED 表面結構分析⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯ 51 4-3 以X-ray 繞射儀分析Mo(100)和Al2O3(1-102)之間   的傾斜角度⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯ 57 4-4 以STM 分析不同成長溫度對Mo 表面形貌的影響⋯⋯ 60 4-5 以STM 分析不同成長厚度對Mo 表面形貌的影響⋯⋯ 74   Reference⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯ 86 第五章 結論   ⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯ 87

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