本論文主題可分為利用吸附劑與酸性氣體吸收之研究，和管狀金屬頁矽酸鹽生成機構之探討。
(1) 利用鹼性造粒與酸性氣體吸收之研究
利用簡單且環境友善的造粒方法，製作鈣氧化鋁造粒吸附酸性氣體(HCl,NO2,CO2…)，氯化氫 (HCl) 為無色酸性腐蝕氣體，其排放對於環境與健康有害，而NOx為強溫室氣體，控制溫室氣體排放時的主要對象；而本研究主要以不同時間參數和鍛燒溫度的控制讓造粒過程中所造成吸附上的影響，改善粉狀(Powder)材料實際使用上不僅會使反應腔體內背壓過高、容易沾黏，不易與產物分離，且粉體容易造成粉塵吸收與使用上不便，本實驗方法主要以活性氧化鋁和硝酸鋁水溶液混合，以調整pH值至中性將硝酸鋁轉相成氫氧化鋁附著在氧化鋁表面當作黏著劑(binder)，並且水熱至75℃持續6小時提供能量，接著經過加入褐藻酸鈉進行造粒過程，浸入乳酸鈣水溶液裡進行離子交換，烘乾之後改變不同鍛燒溫度，再因高溫鍛燒的環境下產生鍵結，提高造粒的機械強度即可得到研究的標的產物鈣氧化鋁孔洞吸附材料。
為取得異相成核與水熱法的最佳條件，本研究將反應參數調整成兩個面向，分別為浸泡Ca2+離子交換時間，與鍛燒溫度的影響，可以知道鈣氧化鋁孔洞材料，鍛燒溫度不同而有不同的表面積影響，在700℃的鍛燒下鈣氧化鋁孔洞材料表面積約為125 m2g-1，而在800℃鍛燒下表面積約為95 m2g-1，依不同的乳酸鈣浸泡時間離子交換下，利用FTIR以偵測HCl的初始濃度和破出濃度，可以得知出鈣氧化鋁孔洞材料之HCl氯化氫的處理容量，經過測量可以得知氯化氫的處理容量是有達到效果的，因此本實驗使用此造粒合成材料方法是更為簡便、低耗能且對環境友善。

(2) 管狀金屬頁矽酸鹽生成之形態
利用簡便且對環境友善的矽酸鹽剝蝕法，合成管狀金屬頁矽酸鹽材料，過往合成金屬頁矽酸鹽phyllosilicate需要以氨蒸發法，並且在高溫高壓的環境下合成，不僅對環境有害且耗能，本研究利用金屬硝酸水合物並且以鹼性溶液調整至適當pH值，並且在150 ℃的環境下，矽酸鹽與金屬氫氧化物進行重組並產生鍵結，再因兩者之間晶格不匹配，產物會因應力產生捲曲，最終形成本研究所探討管狀構型的phyllosilicate，並且探討其反應生成機構。

(1) The use of alkaline granulation and the study of acidic gas absorption
The use of simple and environmentally friendly granulation methods to adsorb acidic gases and this study focuses on the control of different time and calcination temperature to enable the granulation process caused by the adsorption of the past adsorption of acidic gases are mostly CaCO3, CaO, zeolite, activated carbon, silica gel material, etc. , but this method is mainly based on the mixing of activated alumina and aluminium nitrate in aqueous solution using deposition-precipitation method. And the surface area of the calcium aluminate pore material is  125 m2g-1 at 700 °C and  95 m2g-1 at 800 °C. The granulation process is followed by sodium alginate ion exchange in aqueous calcium lactate solution, and then bonding under high calcination temperature conditions to improve the mechanical strength of the granulation to obtain the calcium aluminate pore adsorption material for the study.
In order to obtain the best conditions for deposition-precipitation and hydrothermal methods, the immersion time of Ca2+ ion exchange and the effect of calcination temperature. Under different ion exchange times for calcium lactate, use of this granulation method is therefore simpler, less energy consuming and less polluting to the environment.
(2) Formation of silicate from tubular metal phyllosilicate
In the past, the synthesis of phyllosilicate required ammonia evaporation and was carried out under high temperature and pressure, which was not only harmful to the environment but also energy-consuming. Due to the lattice mismatch between the two meterial, the product will be curled in response to the force, resulting in the formation of phyllosilicate in the tubular configuration investigated in this study and reaction mechanism.

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