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研究生：	廖國綸 Liao, Kuo-Lun
論文名稱：	以水熱法成長銳鈦礦二氧化鈦結構於光電化學分解水之應用 Hydrothermal growth of anatase TiO2 structures for use in photoelectrochemical water oxidation
指導教授：	吳季珍 Wu, Jih-Jen
學位類別：	碩士 Master
系所名稱：	工學院 - 化學工程學系 Department of Chemical Engineering
論文出版年：	2017
畢業學年度：	105
語文別：	中文
論文頁數：	83
中文關鍵詞：	二氧化鈦、銳鈦礦、水熱法、光陽極、光電化學分解水
外文關鍵詞：	TiO2, anatase, hydrothermal growth, photoanode, photoelectrochemical water oxidation
相關次數：	點閱：96 下載：0
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本研究以水熱法製備銳鈦礦二氧化鈦沉積物於FTO上，並將其應用於光電化學水分解。藉由沉積參數如晶種層溫度、水熱法成長時間、前驅物濃度、水熱法成長溫度、食鹽水溶液等的調整，改變銳鈦礦二氧化鈦沉積物的形貌，並優化銳鈦礦二氧化鈦光電極的光電化學水分解效率。銳鈦礦二氧化鈦光電極在1.23 V vs RHE時，電流可達到0.279 mA/cm2。而在穩定度測試中，此銳鈦礦二氧化鈦光電極的光電流密度，在操作600秒後僅下降8%。

In this work, anatase titanium dioxide (TiO2) structures have been deposited on fluorine-doped tin oxide (FTO) by hydrothermal method for the application to photoelectrochemical water splitting. The performance of anatase TiO2 photoanode was optimized in terms of deposition conditions, including annealing temperature of seed layer, period of hydrothermal growth, concentration of titanium(IV) n-butoxide, temperature of hydrothermal growth and saturated sodium chloride solution. The optimized anatase TiO2 photoanode produces a photocurrent density of 0.279 mA/cm2 at a potential of 1.23 V versus RHE under illumination of AM 1.5G (100 mWcm-2). The photocurrent density of the anatase TiO2 photoanode over a period of 600s is reduced only 8%.

摘要	I
誌謝	VI
目錄	VII
圖目錄	XI
表目錄	XIV
第一章 緒論	1
    1-1前言	1
    1-2 Honda-Fujishima Effect	3
    1-3研究動機	5
第二章 文獻回顧	6
    2-1太陽光光譜輻照度	6
    2-2光觸媒原理	7
       2-2-1光觸媒分解水的原理	7
       2-2-2光觸媒分解水的反應步驟	10
       2-2-3光觸媒分解水裝置	12
    2-3光電化學法作用原理	16
       2-3-1光電化學法裝置介紹	16
            2-3-1-1光電極與導電基板之探討	18
            2-3-1-2對電極	18
            2-3-1-3參考電極	18
            2-3-1-4電解質	19
       2-3-2  n-type半導體光電化學法作用原理	19
    2-4二氧化鈦的結構與性質	21
       2-4-1二氧化鈦之結晶結構	21
       2-4-2一維奈米結構金紅石二氧化鈦之水分解應用	22
       2-4-3二氧化鈦金紅石與銳鈦礦之比較	26
       2-4-4銳鈦礦二氧化鈦的結構型態	26
       2-4-5銳鈦礦二氧化鈦的合成方式	28
            2-4-5-1水熱法	28
            2-4-5-2電化學法	29
            2-4-5-3氣相沉積法	30
第三章 實驗步驟與研究方法	31
    3-1實驗材料	31
       3-1-1成長二氧化鈦銳鈦礦材料	31
       3-1-2光電化學分解水之電解質材料	31
    3-2實驗製程設備	32
       3-2-1旋轉塗佈機	32
       3-2-2高壓釜	32
       3-2-3高溫爐	32
    3-3實驗流程設計	33
    3-4實驗步驟	34
       3-4-1 FTO導電玻璃基版清潔	34
       3-4-2晶種層的製備	34
       3-4-3水熱法成長二氧化鈦沉積物	35
       3-4-4光電極製作與光電化學水分解量測	36
    3-5分析與鑑定	37
       3-5-1掃描式電子顯微鏡(SEM)	37
       3-5-2 X光繞射分析(XRD)	38
       3-5-3拉曼分析儀(Raman Spectroscopy)	39
       3-5-4紫外光-可見光吸收光譜儀(UV-vis Spectroscopy)	40
       3-5-5 太陽光模擬器(Solar Simulator)	41
       3-5-6 恆電位儀(Potentiostat)	41
第四章 結果與討論	42
    4-1晶種層退火溫度	42
       4-1-1晶種層退火溫度對二氧化鈦沉積物形貌之影響	43
       4-1-2晶種層退火溫度對二氧化鈦沉積物吸收度之影響	43
       4-1-3晶種層退火溫度對二氧化鈦沉積物相態之影響	45
       4-1-4晶種層退火溫度對二氧化鈦沉積物光電化學水分解
            之影響	48
    4-2水熱法成長時間	50
       4-2-1水熱法成長時間對二氧化鈦沉積物形貌之影響	50
       4-2-2水熱法成長時間對二氧化鈦沉積物吸收度之影響	52
       4-2-3水熱法成長時間對二氧化鈦沉積物相態之影響	52
       4-2-4水熱法成長時間對二氧化鈦沉積物光電化學水分解
            之影響	54
    4-3前驅物濃度	55
       4-3-1前驅物濃度對二氧化鈦沉積物形貌之影響	55
       4-3-2前驅物濃度對二氧化鈦沉積物吸收度之影響	57
       4-3-3前驅物濃度對二氧化鈦沉積物相態之影響	57
       4-3-4前驅物濃度對二氧化鈦沉積物光電化學水分解之影響	                  
            	59
    4-4水熱法成長溫度	61
       4-4-1水熱法成長溫度對二氧化鈦沉積物形貌之影響	61
       4-4-2水熱法成長溫度對二氧化鈦沉積物吸收度之影響	63
       4-4-3水熱法成長溫度對二氧化鈦沉積物相態之影響	63
       4-4-4水熱法成長溫度對二氧化鈦沉積物光電化學水分解
             之影響	65
    4-5飽和食鹽水溶液	66
      4-5-1飽和食鹽水溶液對二氧化鈦沉積物形貌之影響	66
       4-5-2飽和食鹽水溶液對二氧化鈦沉積物相態之影響	67
       4-5-3飽和食鹽水溶液對二氧化鈦沉積物光電化學水分解
             之影響	69
    4-6不同條件製備光陽極之光電化學水分解效果與
       沉積純銳鈦礦條件	70
    4-7穩定性測試	72
第五章 總結論	73
第六章 參考文獻	75
                                    

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