本研究是針對含氟廢水，利用流體化床芬頓(FBR–Fenton)反應的鐵氧化物副產物(BT3)，作為資源再利用之吸附材，目的是找出低成本之吸附材以取代現有除氟的方法。研究中分別利用XRD、SEM與FTIR測定BT3的基本物性。吸附反應的操作變因包括：pH、反應時間、氟離子濃度(從 0.75到 6 mmol L-1)以及反應溫度(從 303 到 323K)。當反應條件在氟初始濃度為6 mmol L-1，且pH控制在3.9±0.2，溫度為303±1 K，發現BT3的最大吸附量可達 1.17 mmol g−1 (22.2 mg g-1)。等溫吸附模式最符合Langmuir模式，並計算其熱力學參數，其ΔG◦, ΔH◦ and ΔS◦ 分別為 −1.63 kJ mol−1 (at 303 K), -1.75 kJ mol−1 與 -52.4J mol−1 K−1。此外， 擬二階（pseudo-second-order）速率模式最能符合此吸附材之吸附動力模式。而BT3可利用氫氧化鈉再生，其再生效果在氫氧化鈉濃度為0.05 mol L-1，可達95.1%。本研究利用鍛燒方式改質吸附材，發現當鍛燒溫度達300°C，可使吸附材達到最大吸附量。針對陰離子效應的測試，發現磷酸氫根影響最大，而硝酸根影響最小。

This study uses a waste iron oxide material (BT3), which is a by-product of the fluidized-bed Fenton reaction (FBR–Fenton), for the treatment of a fluoride (F-) solution. The purpose of this study is to investigate a low-cost sorbent as a replacement for the current costly methods of removing fluoride from wastewater. X-ray powder diffraction (XRD), FTIR and scanning electron microscopy (SEM) are used to characterize the BT3. Contact time, pH, F- concentration (from 0.75 to 6 mmol L-1) and temperature (from 303 to 323K) are used as operation parameters to treat the fluoride solution. The highest F- adsorption capacity of the BT3 adsorbent was determined to be 1.17 mmol g−1 (22.2 mg g-1) for a 6 mmol L-1 initial F concentration at pH 3.9±0.2 and 303±1 K. Adsorption data were well described by the Langmuir model, and the thermodynamic constants of the adsorption process, ΔG◦, ΔH◦ and ΔS◦, were evaluated as −1.63 kJ mol−1 (at 303 K), -1.75 kJ mol−1 and -52.4J mol−1 K−1, respectively. Additionally, a pseudo-second-order rate model was adopted to describe the kinetics of adsorption. BT3 could be regenerated with NaOH, and the regeneration efficiency reached 95.1 % when the concentration of NaOH was 0.05 mol L-1. There is a small increase in the adsorption capacity on increasing the calcination temperature of BT3 to 300°C. Furthermore, increasing the solution temperature leads to a sharp decrease in the adsorption capacity for the calcined BT3. This may be due to structural and phase changes at high calcination temperatures. It leads to a decrease of the specific surface area and a collapse of the pores due to sintering and transformation of metal hydroxides to oxides when calcination temperatures > 300 °C. These changes might reduce the adsorption sites. The impact of major anions on fluoride adsorption followed the order of HPO42- > SO42-,> Cl- > NO3− for BT3.

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