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研究生: 黃信諭
Huang, Hsin-Yu
論文名稱: 石墨與蛭石的添加對半碳化銅/酚醛樹脂基摩擦材料機械及磨潤性質之影響
Effects of Addition of Graphite and Vermiculite on Mechanical and Tribological Properties of Semi-Carbonized Copper/Phenolic Resin-based Friction Material
指導教授: 朱建平
Ju, Chien-Ping
陳瑾惠
Chern Lin, Jiin-Huey
共同指導教授: 李國榮
Lee, Kuo-Jung
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年: 2016
畢業學年度: 104
語文別: 中文
論文頁數: 88
中文關鍵詞: 半金屬摩擦材料半碳化
外文關鍵詞: semi-metallic friction material, semi-carbonizing
相關次數: 點閱:127下載:9
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  • 本研究為延續實驗室過去半金屬摩擦材料所進行之研究,得知紅銅纖維/紅銅粉末的相對含量、半碳化溫度及石墨粉與雲母粉之添加之最佳製程參數-T3X1Y1試片具有適當的摩擦係數與低磨耗量,並且在噪音表現上較無噪音出現。
    本研究以T3X1Y1試片為出發點且以摩擦時無噪音為前提,探討是否能在不使制動力減少太多的情況下,進一步改良T3X1Y1試片磨耗量較商業試片為多的問題。主要是以蛭石取代雲母作為摩擦調整劑,藉此探討此方式對半金屬摩擦材料在機械、磨潤等性質及在摩擦過程中噪音表現之影響,並進一步開發適合單車煞車使用之摩擦材料。
    實驗結果顯示,添加蛭石之後試片摩擦係數顯著上升,但添加量過高時,反而造成摩擦係數起伏過大及磨耗量較高之現象,因此選擇適當的石墨與蛭石添加比例才能有助於自製試片磨耗性能之提升,勝過商業試片之表現,達到本研究之目的。

    SUMMARY
    This research is based on the past research of semi-metallic friction material, and we use copper fiber as reinforcement, copper powder, phenolic resin, and graphite powder as our material. In my research, I use vermiculite as the additives, and design three different series with different addition of graphite powder. In each series, I change the amount of vermiculite to investigate the influence to the properties of tribological and mechanical.
    The results show that the coefficient of friction is increased as the addition of vermiculite rises up, but dramatically decreased when the addition of vermiculite keeps going up due to unstable friction surface and excess powder-like wear debris. Besides, there’s some noise being detected during the test procedure of specimens with higher amount of vermiculite. As for the weight loss, it is increased as the addition of vermiculite rises up. Therefore, I add more graphite powder as solid lubricants in order to compromise between the coefficient of friction and the weight loss.
    In conclusion, specimen TGBVA has proper coefficient of friction, relatively low weight loss, noiseless while braking, and good mechanical properties. As a result, TGBVA is a better choice among all specimens.

    摘要 I 誌謝 VI 總目錄 VIII 圖目錄 XII 表目錄 XVI 第一章 前言 1 第二章 文獻回顧 3 2.1 摩擦材料簡介 3 2.1.1 摩擦材料的發展 3 2.1.2 摩擦材料的基本分類 4 2.1.3 摩擦材料的應用 8 2.2 摩擦材料的基本性質和自行車煞車規範 13 2.2.1 摩擦材料的基本性質 13 2.2.2 自行車煞車規範 15 2.3 半金屬基摩擦材料組成物介紹 18 2.3.1 結合材(Binders) 18 2.3.2 纖維(Fibers) 19 2.3.3 固體潤滑劑(Solid lubricants) 21 2.3.4 填充劑(Filler)、研磨劑(Abrasive)、摩擦調整劑(Friction modifier) 23 2.4 半金屬摩擦材料製程介紹 24 2.4.1 熱壓 24 2.4.2 穩定化 24 2.4.3 半碳化 25 2.5 磨潤學 27 2.5.1 簡介 27 2.5.2 摩擦原理 27 2.5.3 影響摩擦性質的因素 29 2.5.4 磨耗機制 33 第三章 實驗方法 38 3.1 實驗原料 38 3.1.1 酚醛樹脂(Phenolic resin) 38 3.1.2 紅銅纖維(Copper fiber) 39 3.1.3 紅銅粉(Copper powder) 39 3.1.4 石墨粉(Graphite powder) 40 3.1.5 蛭石(Vermiculite) 41 3.2 實驗製程 42 3.2.1 原料混合 43 3.2.2 熱壓成型 44 3.2.3 穩定化 46 3.2.4 半碳化 47 3.2.5 試片加工 48 3.3 性質測量 50 3.3.1 試片重量及厚度變化 50 3.3.2 體密度/孔隙率量測 52 3.3.3 抗壓強度測試 54 3.3.4 硬度測試 55 3.3.5 磨耗試驗 57 3.3.6 顯微結構觀察 60 3.3.7 表面粗糙度量測 60 第四章 結果與討論 62 4.1 試片厚度變化 62 4.2 試片重量變化 64 4.3 體密度/孔隙率 65 4.4 抗壓強度 67 4.5 硬度 68 4.6 磨潤性質 69 4.7 表面顯微結構觀察 77 4.8 表面粗糙度 81 第五章 結論 83 參考文獻 85

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