利用水熱/溶劑熱法，我們成功合成出兩個系統的鑭金屬有機配位聚合物。第一個系統是使用同時含硫及羧酸根的DTPC配位基，合出兩個等結構的新穎化合物，Gd∙1、Er∙2。在結構上Cu12團簇是藉由CuCl4四面體相互連結，再藉由TPC配位基連接Cu12團簇與[Ln4O4]四聚體填充在孔洞內，形成結構。
第二個系統是含羧酸根的H2OBA配位基連接鑭金屬三核配位聚合物，Nd∙3、Gd∙4。Nd∙3具有釹三核單元，且被十二個OBA配位基圍繞形成三維結構，再互相穿透成Nd∙3的最終結構。Gd∙4具有釓三核單元，以DMF分解的甲酸分子連結釓三核，形成一維的Z型釓金屬鏈。接著釓金屬三核被八個OBA配位基圍繞形成三維的Gd∙4結構。
接著利用超導磁性量子干涉儀，四個化合物的χMT值在室溫時與其理論值相差不大，都隨溫度下降而遞減，表示鑭金屬間均表現出反鐵磁性的作用力。

We have synthesized two systems of lanthanide-based coordination polymers by the mild solvothermal method.
In the first system, the unique Cu12 clusters, CuCl4 tetrahedra, [Ln4O4] tetramer and DTPC ligands fused together to form a new three-dimensional framework structure in Gd∙1 and Er∙2. The magnetic property indicates that antiferromagnetic coupling exists in two compounds. Besides, the fitting value for Gd∙1 is g = 2.00, J= – 0.195 cm-1.
In the second system, the Ln3+ trinuclear and H2OBA ligands fused together to form a new three-dimensional framework structure in Nd∙3 and Gd∙4. The magnetic property indicates that antiferromagnetic coupling also exists in two compounds.

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