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研究生: 葉韋宏
Yeh, Wei-hung
論文名稱: 固態雞尾酒有機染料敏化太陽能電池之研究
Solid-State Dye-Sensitized Solar Cells by Using Organic Dye-Cocktails
指導教授: 楊毓民
Yang, Yu-Min
學位類別: 碩士
Master
系所名稱: 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年: 2011
畢業學年度: 99
語文別: 中文
論文頁數: 80
中文關鍵詞: 染料敏化太陽能電池固態電解質雞尾酒有機染料混成共增感效應共吸附效應
外文關鍵詞: Dye sensitized solar cell, solid-electrolyte, organic dye-cocktails, co-sensitized effect, co-adsorbent effect
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  • 受到固態電解質(Spiro-OMeTAD)滲透能力不佳的影響,固態染料敏化太陽能電池的最佳厚度約為2微米。因為厚度的限制,所以就必須選擇具有高消光係數(extinction coefficient)的染料分子作為敏化劑,才能達到較好的光捕獲效率。本研究選用D149和SQ2兩種有機光敏染料分子,以不同的溶液體積比,透過雞尾酒混成法達到共增感的效應。實驗結果顯示,雞尾酒染料敏化太陽電池所得到的電流都比單一染料敏化太陽電池為高。根據雞尾酒染料敏化太陽電池的效率測定、入射光電轉換效率(IPCE)及電化學交流阻抗圖譜(EIS)等分析,當D149:SQ2溶液體積比為10:1時,電流和效率有最佳值。
    本研究亦進一步探討在不同溶液體積比時,電流獲得提升的機制。由Mercurochrome/SQ2共增感效應和D149/ Chenodeoxycholic acid(CDCA)共吸附效應的結果,與D149/SQ2系統做一個比較,提出雞尾酒混成法電流值提升的可能機制:當混成體積比相近時,由於共增感效應的貢獻使電流獲得提升。然而在混成體積比懸殊時,共吸附效應才是電流值提升的主因。

    One observed characteristic of the spiro-based solid-state dye sensitized solar cell is that the efficiency reaches a maximum value when the TiO2 film are only 2μm thickness, and this is caused by the poor pore-filling problem of the solid electrolyte(spiro-OMeTAD). High molar extinction coefficient dyes are therefore desirable in order to make thin solar cells with good light-harvesting. In this study, two organic dye molecular, D149 and SQ2, were selected as the sensitizers. Through co-sensitization of the D149 and SQ2 sensitizers, which are complimentary in their spectral responses, we have obtained a higher photocurrent than for individual dye-sensitized solar cells. By analysis of efficiency measurement, IPCE spectra and EIS spectra showed that when the volume ratio between D149 and SQ2 is 10 to 1, photocurrent and efficiency achieved maximum values.
    Furthermore, the mechanism of enhanced photocurrent under different volume ratio was investigated. Compared the results of Mer/SQ2 co-sensitized effect and D149/CDCA co-adsorbent effect to D149/SQ2 system, a possible mechanism was proposed: If the volume ratio is closed, obviously, the contributed photocurrent is caused by the co-sensitized effect. On the other hand, when the ratio different is very large, the co-adsorbent effect is the major cause to increase the photocurrent.

    目錄 中文摘要 I Abstract II 誌謝 III 目錄 IV 表目錄 VIII 圖目錄 IX 第 1 章 緒論 1 1-1 前言 1 1-2太陽能電池發展現況 2 1-3研究動機與目的 6 第 2 章 工作原理與文獻回顧 7 2-1 染料敏化太陽能電池 7 2-1.1染料敏化太陽能電池發展現況 7 2-1.2染料敏化太陽電池之工作原理 13 2-1.3染料敏化太陽能電池組成介紹 14 2-1.4 固態電解質 19 2-2光電特性測量 21 2-2.1太陽能電池之總效率 21 2-2.2光電轉換效率(Incident Photo to Current conversion efficiency, IPCE) 24 2-3 文獻回顧 25 2-3.1 有機色素 25 2-3.2 共增感效應 28 2-3.3 共吸附效應 31 2-3.4 固態電池. 34 第 3 章 實驗儀器與方法 36 3-1儀器設備 36 3-1.1 超音波震盪器(Ultrasonic cleaner) 36 3-1.2 旋轉塗佈機(Spin coater) 36 3-1.3 高溫加熱板(Hot plate) 37 3-1.4 表面輪廓儀(Alpha step) 37 3-1.5 紫外光/可見光光譜儀(UV-vis spectrophotometer) 37 3-1.6 太陽光模擬器(Solar simulator) 38 3-1.7 定電位/定電流儀(Potentiostat/Galvanostat) 39 3-1.8 光電轉化效率測定系統(IPCE measurement) 40 3-1.9 熱蒸鍍機(Thermal evaporator) 41 3-1.10 Mili-Q超純水系統 42 3-2實驗藥品 43 3-3實驗方法 45 3-3.1 TiO2漿料製備 45 3-3.2 TiO2光電極製備 45 3-3.3 染料分子吸附 46 3-3.4 吸附動力學分析 46 3-3.5電解液製備 47 3-3.6 電池組裝 48 第 4 章 結果與討論 49 4-1 共增感效應 系統(1)—D149/SQ2 49 4-1.1 吸附特性 49 4-1-2光電特性測量 54 4-2 共增感效應 系統(2)—Mercurochrome/SQ2 59 4-2.1 吸附特性 59 4-2-2光電特性測量 62 4-3 共吸附效應 67 第 5 章 結論與建議 71 5-1 結論 71 5-2建議 72 參考文獻 73

    參考文獻
    1. Michael Grätzel, Perspectives for Dye-sensitized Nanocrystalline Solar Cells. PROGRESS IN PHOTOVOLTAICS: RESEARCH AND APPLICATIONS, 2000. 8: p. 171-185.
    2. Chen, Y., Zeng, Zhanghua, Li, Chao, Wang, Weibo, Wang, Xuesong, Zhang, Baowen, Highly efficient co-sensitization of nanocrystalline TiO2 electrodes with plural organic dyes. New Journal of Chemistry, 2005. 29(6): p. 773.
    3. M. Grätzel, B., O'Regan,, A low-cost, high-efficiency solar cell based on dye-sensitized colloidal films. Nature, 1991. 353: p. 737-739.
    4. Qingjiang Yu, Y.W., Zhihui Yi, Ningning Zu, Jing Zhang, Min Zhang, Peng Wang, High-Efficiency Dye-Sensitized Solar Cells: The Influence of Lithium Ions on Exciton Dissociation, Charge Recombination, and Surface States. ACS NANO, 2010. 4: p. 6032-6038.
    5. L.Schmidtmende, M.G., TiO2 pore-filling and its effect on the efficiency of solid-state dye-sensitized solar cells. Thin Solid Films, 2006. 500(1-2): p. 296-301.
    6. Ding, I.K., Tétreault, Nicolas, Brillet, Jérémie, Hardin, Brian E., Smith, Eva H., Rosenthal, Samuel J., Sauvage, Frédéric, Grätzel, Michael ,McGehee, Michael D., Pore-Filling of Spiro-OMeTAD in Solid-State Dye Sensitized Solar Cells: Quantification, Mechanism, and Consequences for Device Performance. Advanced Functional Materials, 2009. 19(15): p. 2431-2436.
    7. H.Tsubomura, M.M., Y.Nomura, T. amamiya, Dye sensitized zinc ojide: aqueous electrolyte: platinum photocell. Nature, 1976. 261: p. 402-403.
    8. Md. K. Nazeeruddin, S.M.Z., R. Humphry-Baker, M. Jirousek, P. Liska,N. Vlachopoulos, V. Shklover, Christian-H. Fischer, and M. Grätzel, Acid-Base Equilibria of (2,2¢-Bipyridyl-4,4¢-dicarboxylic acid)ruthenium(II) Complexes and the Effect of Protonation on Charge-Transfer Sensitization of Nanocrystalline Titania. American Chemical Society, 1999. 38: p. 6298-6295.
    9. Md. K. Nazeeruddin, R.H.-B., P. Liska, and M. Grätzel, Investigation of Sensitizer Adsorption and the Influence of Protons on Current and Voltage of a Dye-Sensitized Nanocrystalline TiO2 Solar Cell. American Chemical Society, 2003. 107: p. 8981-8987.
    10. Mohammad K. Nazeeruddin, P.P., Thierry Renouard, Shaik M. Zakeeruddin, and P.C. Robin Humphry-Baker, Paul Liska, Le Cevey, Emiliana Costa, Valery Shklover, Leone Spiccia,§ Glen B. Deacon,§ Carlo A. Bignozzi, and Michael Grätzel, Engineering of Efficient Panchromatic Sensitizers for Nanocrystalline TiO2-Based Solar Cells. American Chemical Society, 2001. 123: p. 1613-1624.
    11. Mohammad K. Nazeeruddin, F.D.A., Simona Fantacci, Annabella Selloni,Guido Viscardi,Paul Liska, Seigo Ito, Bessho Takeru, and Michael Grätzel, Combined Experimental and DFT-TDDFT Computational Study of Photoelectrochemical Cell Ruthenium Sensitizers. J. AM. CHEM. SOC., 2005. 127: p. 16835-16847.
    12. Mohammad K. Nazeeruddin, F.D.A., Simona Fantacci, Annabella Selloni, Guido Viscardi,§ Paul Liska, Seigo Ito, Bessho Takeru, and and M. Graätzel, Combined Experimental and DFT-TDDFT Computational Study of Photoelectrochemical Cell Ruthenium Sensitizers. American Chemical Society, 2005. 127: p. 16835-16847.
    13. Peng Wang, S.M.Z., Robin Humphry, Jacques E. Moser, and Micheal Grätzel, Molecular-Scale Interface Engineering of TiO2 Nanocrystal: Improving the Efficiency and Stability of Dye-Sensitized Solar Cells. Advanced Materials, 2003. 15: p. 2101-2104.
    14. K Tennakone, G.R.R.A.K., I R M Kottegoda, K G U Wijayantha and V P S Perera, A solid-state photovoltaic cell sensitized with a ruthenium bipyridyl complex. J. Phys. D: Appl.Phys, 1998. 31: p. 1492-1496.
    15. Kumara, G., Dye-sensitized solid-state solar cells made from magnesiumoxide-coated nanocrystalline titanium dioxide films: enhancement of the efficiency. Journal of Photochemistry and Photobiology A: Chemistry, 2004. 164(1-3): p. 183-185.
    16. Hara, K., Kurashige, Mitsuhiko, Dan-oh, Yasufumi, Kasada, Chiaki, Shinpo, Akira, Suga, Sadaharu, Sayama, Kazuhiro, Arakawa, Hironori, Design of new coumarin dyes having thiophene moieties for highly efficient organic-dye-sensitized solar cells. New Journal of Chemistry, 2003. 27(5): p. 783-785.
    17. Tamotsu Horiuchi, H.M., Kouichi Sumioka, and Satoshi Uchida, High Efficiency of Dye-Sensitized Solar Cells Based on Metal-Free Indoline Dyes. J. AM. CHEM. SOC., 2004. 126: p. 12218-12219.
    18. Ito, S., Zakeeruddin, S.  M, Humphry-Baker, R., Liska, P., Charvet, R., Comte, P., Nazeeruddin, M.  K, Péchy, P., Takata, M., Miura, H., Uchida, S., Grätzel, M., High-Efficiency Organic-Dye- Sensitized Solar Cells Controlled by Nanocrystalline-TiO2 Electrode Thickness. Advanced Materials, 2006. 18(9): p. 1202-1205.
    19. Ito, S., Miura, Hidetoshi, Uchida, Satoshi, Takata, Masakazu, Sumioka, Koichi, Liska, Paul, Comte, Pascal, Péchy, Peter, Grätzel, Michael, High-conversion-efficiency organic dye-sensitized solar cells with a novel indoline dye. Chemical Communications, 2008(41): p. 5194.
    20. Robert Plass, S.P., Jessica Krueger, and Michael Grätzel, Quantum Dot Sensitization of Organic-Inorganic Hybrid Solar Cells. American Chemical Society, 2002. 106: p. 7578-7580.
    21. R. Vogel, P.H., and H. Weller., Quantum-Sized PbS, CdS, AgzS, Sb&, and Bi& Particles as Sensitizers for Various Nanoporous Wide- Bandgap Semiconductors. American Chemical Society, 1994. 98: p. 3183-3188.
    22. Lee, Y.-L., Chang, Chi-Hsiu, Efficient polysulfide electrolyte for CdS quantum dot-sensitized solar cells. Journal of Power Sources, 2008. 185(1): p. 584-588.
    23. Grätzel, M., Recent Advances in Sensitized Mesoscopic Solar Cells. ACCOUNTS OF CHEMICAL RESEARCH, 2009. 42: p. 1788-1798.
    24. Chia-Yuan Chen, M.W., Jheng-Ying Li, Nuttapol Pootrakulchote, Leila Alibabaei, Cevey-ha Ngoc-le, Jean-David Decoppet, Jia-Hung Tsai, Carole Grä tzel, Chun-Guey Wu, Shaik M. Zakeeruddin, and Michael Grä tzel, Highly Efficient Light-Harvesting Ruthenium Sensitizer for Thin-Film Dye-Sensitized Solar Cells. American Chemical Society, 2009. 3: p. 3103-3109.
    25. Wang, M., Liu, Jingyuan, Cevey-Ha, Ngoc-Le, Moon, Soo-Jin, Liska, Paul, Humphry-Baker, Robin, Moser, Jacques- E., Grätzel, Carole, Wang, Peng, Zakeeruddin, Shaik M., High efficiency solid-state sensitized heterojunction photovoltaic device. Nano Today, 2010. 5(3): p. 169-174.
    26. Ding, I.K., Melas-Kyriazi, John, Cevey-Ha, Ngoc-Le, Chittibabu, Kethinni G., Zakeeruddin, Shaik M., Grätzel, Michael, McGehee, Michael D., Deposition of hole-transport materials in solid-state dye-sensitized solar cells by doctor-blading. Organic Electronics, 2010. 11(7): p. 1217-1222.
    27. Yum, J.-H., Hardin, Brianâ…E, Moon, Soo-Jin, Baranoff, Etienne, Nüesch, Frank, McGehee, Michaelâ…D, Grätzel, Michael, Nazeeruddin, Mohammadâ…K, Panchromatic Response in Solid-State Dye-Sensitized Solar Cells Containing Phosphorescent Energy Relay Dyes. Angewandte Chemie International Edition, 2009. 48(49): p. 9277-9280.
    28. Wang, M., Grätzel, Carole, Moon, Soo-Jin, Humphry-Baker, Robin, Rossier-Iten, Nathalie, Zakeeruddin, Shaik M., Grätzel, Michael, Surface Design in Solid-State Dye Sensitized Solar Cells: Effects of Zwitterionic Co-adsorbents on Photovoltaic Performance. Advanced Functional Materials, 2009. 19(13): p. 2163-2172.
    29. Snaith, H.J., Petrozza, Annamaria, Ito, Seigo, Miura, Hidetoshi, Grätzel, Michael, Charge Generation and Photovoltaic Operation of Solid-State Dye-Sensitized Solar Cells Incorporating a High Extinction Coefficient Indolene-Based Sensitizer. Advanced Functional Materials, 2009. 19(11): p. 1810-1818.
    30. Francisco Fabregat-Santiago, J.B., Le Cevey, Peter Chen, Mingkui Wang, Shaik M. Zakeeruddin, and Michael Grätzel, Electron Transport and Recombination in Solid-State Dye Solar Cell with Spiro-OMeTAD as Hole Conductor. J. AM. CHEM. SOC., 2009. 131: p. 558-562.
    31. Chen, P., Yum, Jun Ho, Angelis, Filippo De, Mosconi, Edoardo, Fantacci, Simona, Moon, Soo-Jin, Baker, Robin Humphry, Ko, Jaejung, Nazeeruddin, Md K., Grätzel, Michael, High Open-Circuit Voltage Solid-State Dye-Sensitized Solar Cells with Organic Dye. Nano Letters, 2009. 9(6): p. 2487-2492.
    32. Yum, J.-H., Chen, Peter, Grätzel, Michael, Nazeeruddin, Mohammad K, Recent Developments in Solid-State Dye-Sensitized Solar Cells. ChemSusChem, 2008. 1(8-9): p. 699-707.
    33. Wendy H. Howie, F.C., Hidetoshi Miura, and Laurence M. Peter, Characterization of Solid-State Dye-Sensitized Solar Cells Utilizing High Absorption Coefficient Metal-Free Organic Dyes. J. AM. CHEM. SOC., 2008. 130: p. 1367-1375.
    34. Tobat P. I. Saragi, T.S., Achim Siebert, Thomas Fuhrmann-Lieker, and Josef Salbeck, Spiro Compounds for Organic Optoelectronics. Chem. Rev., 2007. 107: p. 1011-1065.
    35. Jennings, J.R. and L.M. Peter, A Reappraisal of the Electron Diffusion Length in Solid-State Dye-Sensitized Solar Cells. Journal of Physical Chemistry C, 2007. 111(44): p. 16100-16104.
    36. Li, B., Wang, Liduo, Kang, Bonan, Wang, Peng,Qiu, Yong, Review of recent progress in solid-state dye-sensitized solar cells. Solar Energy Materials and Solar Cells, 2006. 90(5): p. 549-573.
    37. Fabregat-Santiago, F., et al., Impedance spectroscopy study of dye-sensitized solar cells with undoped spiro-OMeTAD as hole conductor. Journal of Applied Physics, 2006. 100(3): p. 034510.
    38. Lukas Schmidt-Mende, U.B., Robin Humphry-Baker, Tamotsu Horiuchi, Hidetoshi Miura, Seigo Ito, Satoshi Uchida, and Michael Grätzel, Organic Dye for Highly Efficient Solid-State DSSC Advanced Materials, 2005. 17: p. 813-815.
    39. Clifford, J.N., Palomares, Emilio, Nazeeruddin, Md K., Grätzel, M., Nelson, Jenny, Li, X., Long, Nicholas J., Durrant, James R., Molecular Control of Recombination Dynamics in Dye-Sensitized Nanocrystalline TiO2Films: Free Energy vs Distance Dependence. Journal of the American Chemical Society, 2004. 126(16): p. 5225-5233.
    40. Udo Bach, Y.T., Jacques-E. Moser, Saif A. Haque, James R. Durrant, Michael Grätzel, and David R. Klug, Charge Separation in Solid-State Dye-Sensitized Heterojunction Solar Cells. J. Am. Chem. Soc., 1999. 121: p. 7445-7446.
    41. U. Bach*, D.L., P. Comte, J. E. Moser, F.Weissortel,J. Salbeck, H. Spreitzer,M. Gratzel, Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies. Nature, 1998. 395: p. 583-585.
    42. Henry J. Snaith, A.J.M., §,| Ce´dric Klein, Klaus Meerholz, Richard H. Friend, and Michael Grätzel, Efficiency Enhancements in Solid-State Hybrid Solar Cells via Reduced Charge Recombination and Increased Light Capture. American Chemical Society, 2007. 7: p. 3372-3376.
    43. Kohjiro Hara, T.S., Ryuzi Katoh, Akihiro Furube, Yasuyo Ohga, Akira Shinpo, Sadaharu Suga, Kazuhiro Sayama, Hideki Sugihara, and Hironori Arakawa, Molecular Design of Coumarin Dyes for Efficient Dye-Sensitized Solar Cells. J. Phys. Chem. B, 2003. 107: p. 597-606.
    44. Asok K. Janaa, B.B.B., Enhancement in power output of solar cells consisting of mixed dyes Journal of Photochemistry and Photobiology A: Chemistry 1999. 122: p. 53-56.
    45. Yoshida, T., Iwaya, Mamiko, Ando, Hiroaki, Oekermann, Torsten, Nonomura, Kazuteru, Schlettwein, Derck, W�hrle, Dieter, Minoura, Hideki, Improved photoelectrochemical performance of electrodeposited ZnO/EosinY hybrid thin films by dye re-adsorption. Chemical Communications, 2004(4): p. 400.
    46. Guo, M., Diao, P., Ren, Y., Meng, F., Tian, H., Cai, S., Photoelectrochemical studies of nanocrystalline TiO co-sensitized by novel cyanine dyes. Solar Energy Materials and Solar Cells, 2005. 88(1): p. 23-35.
    47. Kumara, G., Kaneko, S., Okuya, M., Onwonaagyeman, B., Konno, A., Tennakone, K., Shiso leaf pigments for dye-sensitized solid-state solar cell. Solar Energy Materials and Solar Cells, 2006. 90(9): p. 1220-1226.
    48. Wongcharee, K., V. Meeyoo, and S. Chavadej, Dye-sensitized solar cell using natural dyes extracted from rosella and blue pea flowers. Solar Energy Materials and Solar Cells, 2007. 91(7): p. 566-571.
    49. Yum, J.-H., Jang, Song-Rim, Walter, Pablo, Geiger, T., Nüesch, F., Kim, Sanghoon, Ko, Jaejung, Grätzel, Michael , Mohammad K.Nazeeruddin, Efficient co-sensitization of nanocrystalline TiO2 films by organic sensitizers. Chemical Communications, 2007(44): p. 4680.
    50. Sayama, K., Tsukagoshi, Shingo, Mori, Tohru, Hara, Kohjiro, Ohga, Yasuyo, Shinpou, Akira, Abe, Yoshimoto, Suga, Sadaharu, Arakawa, Hironori, Efficient sensitization of nanocrystalline TiO2 films with cyanine and merocyanine organic dyes. Solar Energy Materials and Solar Cells, 2003. 80(1): p. 47-71.
    51. A. Ehret, L.S., and M. T. Spitler, Spectral Sensitization of TiO2 Nanocrystalline Electrodes with Aggregated Cyanine Dyes. J. Phys. Chem. B, 2001. 105: p. 9960-9965.
    52. Shen, H., Lin, Hong, Liu, Yizhu, Li, Xin, Zhang, Jing, Wang, Ning, Li, Jianbao, A novel diphenylphosphinic acid coadsorbent for dye-sensitized solar cell. Electrochimica Acta, 2011. 56(5): p. 2092-2097.
    53. Mariachiara Pastore, a.F.D.A., Aggregation of Organic Dyes on TiO2 in Dye-Sensitized Solar Cells Models: An ab Initio Investigation. ACS NANO, 2010. 4 p. 556-562.
    54. Shen, H., et al., A novel diphenylphosphinic acid coadsorbent for dye-sensitized solar cell. Electrochimica Acta, 2011. 56(5): p. 2092-2097.
    55. Koh, J.K., Kim, Jeonghun, Kim, Byeonggwan, Kim, Jong Hak, Kim, Eunkyoung, Highly Efficient, Iodine-Free Dye-Sensitized Solar Cells with Solid-State Synthesis of Conducting Polymers. Advanced Materials, 2011. 23(14): p. 1641-1646.
    56. Saji, V.S. and M. Pyo, Effect of coadsorbents on DSSC sensitized by NIR absorbing poly(ethyl thieno[3,4-b]thiophene-2-carboxylate). Current Applied Physics, 2010. 10(3): p. S410-S413.
    57. Mishra, A., M.K.R. Fischer, and P. Bäuerle, Metal-Free Organic Dyes for Dye-Sensitized Solar Cells: From Structure: Property Relationships to Design Rules. Angewandte Chemie International Edition, 2009. 48(14): p. 2474-2499.
    58. Hsueh-Pei Lu, C.-Y.T., Wei-Nan Yen, Chou-Pou Hsieh, Cheng-Wei Lee, Chen-Yu Yeh, and Eric Wei-Guang Diau, Control of Dye Aggregation and Electron Injection for Highly Efficient Porphyrin Sensitizers Adsorbed on Semiconductor Films with Varying Ratios of Coadsorbate. J. Phys. Chem. C, 2009. 113: p. 20990-20997.
    59. Yum, J.H., Moon, S. J., Humphry-Baker, R., Walter, P., Geiger, T., Nüesch, F., Grätzel, M., Nazeeruddin, M. d K., Effect of coadsorbent on the photovoltaic performance of squaraine sensitized nanocrystalline solar cells. Nanotechnology, 2008. 19(42): p. 424005.
    60. Yum, J.-H., Jang, Song-rim, Humphry-Baker, Robin, Grätzel, M., Cid, Juan-José, Torres, Tomas, Nazeeruddin, Md K., Effect of Coadsorbent on the Photovoltaic Performance of Zinc Pthalocyanine-Sensitized Solar Cells. Langmuir, 2008. 24(10): p. 5636-5640.
    61. Zhipan Zhang, S.M.Z., Brian C. O'Regan, Robin Humphry-Baker, and Michael Grätzel, Influence of 4-Guanidinobutyric Acid as Coadsorbent in Reducing Recombination in Dye-Sensitized Solar Cells. J. Phys. Chem. B 2005. 109: p. 21818-21824.
    62. Peng Wang, S.M.Z., Pascal Comte, Raphael Charvet, Robin Humphry-Baker, and Michael Grätzel, Enhance the Performance of Dye-Sensitized Solar Cells by Co-grafting Amphiphilic Sensitizer and Hexadecylmalonic Acid on TiO2 Nanocrystals. J. Phys. Chem. B 2003. 107: p. 14336-14341.
    63. K Tennakone, G.R.R.A.K., A R Kumarasinghe, K G U Wijayantha and P M Sirimanne, A dye-sensitized nano-porous I solid-state photovoltaic cell. Semicond. Sd. Technol., 1995. 10: p. 1689-1693.

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