本研究為一利用有機單體 (ODA+PMDA)先合成聚醯亞胺酸，再經由鈦烷氧化合物 (TET) 以Actylacetone 作為熬合劑，發生溶膠-凝膠反應與聚醯亞胺酸均勻混合，經過高溫環化之後以形成聚醯亞胺/TiO2 複合材料。研究中使用了 TGA、TMA 來測試材料的熱穩定性質，以四點探針儀用來測試材料的絕緣性質，XRD 用來測試材料的結晶性質，IR 用來鑑定材料的官能基，ESCA 與 EDX 用來量測材料的組成以及比例，另外，也使用了 SEM 來觀察材料的表面形態，以了解其有機/無機界面是否有相分離的情形發生，利用 TEM 觀察二氧化鈦無機粒子粒徑大小。另外，為了瞭解材料本身對於耐燃性質的變化，也使用 UL-94 與 LOI兩種測試方法，去判定材料的難燃性，為了瞭解材料本身對於封裝上的影響，也做了滲水性與吸水度的測定。
　　就本實驗而言，在實驗中所量測聚醯亞胺的熱裂解溫度約為590℃，若聚醯亞胺內添加少量的 TiO2 粒子會增加材料的熱裂解溫度大約 10 ~ 15℃，約為 605℃。但當摻雜過多的 TiO2 無機粒子，其熱裂解溫度就開始下降，到摻雜約 20 wt% 時，熱裂解溫度甚至只有 480℃，此外就材料的玻璃轉移溫度(Tg)而言，加入奈米 TiO2 粒子於聚醯亞胺高分子內對於材料的玻璃轉移溫度(Tg)也是會有增加的效果。由實驗結果中，所測得聚醯亞胺其玻璃轉移溫度約為 350℃，而聚醯亞胺/TiO2 複合材料的玻璃轉移溫度高於聚醯亞胺大約 10℃，在耐燃性測試方面，由實驗的結果中可以發現，當摻雜 TiO2 無機粒子的確可以有效增加材料的難燃性質，在結果中，聚醯亞胺以及聚醯亞胺/TiO2 複合材料在 UL-94 測試方面，皆符合 V-0 級的標準，在 LOI 的測試裡，聚醯亞胺其 OI 值為 32，其結果已符合難燃材料，但在聚醯亞胺/TiO2 複合材料卻有更佳的表現，其 OI 值更可到達 40，另外，在吸濕度方面，知道聚醯亞胺吸濕率約為 3.33wt%，而在摻雜 1wt% TiO2 無機粒子的複合材料，吸濕率就降低至 2.7wt%， 利用 TEM、SEM 觀察 TiO2 粒徑大小及材料表面，低摻雜量時，可以發現 TiO2 無機粒子會和聚醯亞胺高分子的確有相當良好的互容性，但隨著摻雜量的增加，TiO2 逐漸聚集在一起，而造成相分離的情況。另外，在 TEM 的觀察中，TiO2 粒子的大小約從 5nm ~ 25nm 不等分佈在聚醯亞胺高分子內，隨著摻雜量的增多，其無機粒子粒徑也會有增加的趨勢。
　　在電泳沈積實驗方面，電泳沈積複合高分子之操作受多種因素所影響，其中有施加電位、電泳沈積時間、熱處理方式以及鍍液成份等。觀察不同組成之鍍液中發現， 絕緣膜的沉積量會隨著Acetone/NMP 之體積比降低以及三乙基胺 (triethylamine, TEA)的添加量增大而會有增加的趨勢。也會隨著施加電壓與沈積時間增加而增加，沈積絕緣膜的表面電阻值，並由數據中得知其Acetone/NMP 之體積比與TEA/COOH 之莫耳比並不會對於絕緣膜的表面電阻值造成太大的影響，但是各絕緣膜之表面電阻值都有108 Ohm/□以上的水準，本研究亦利用 SEM 與 AFM 來觀察沈積絕緣膜內是否含有 TiO2 粒子，並且觀察沈積絕緣膜的表面與斷面微結構以及是否會產生有機相和無機相之間的相容性不佳而造成相分離的情形，由結果中發現，可以確定利用電泳沈積法來製備無機奈米複合緣膜為可行的，的確在 SEM 照片中，可以清楚的看見 TiO2 無機粒子的存在，只是在照片中，也發現有些微的相分離的現象，另外，將所製絕緣膜浸泡於各種溶劑及強酸、鹼中，經過長時間，發現除了 KOH 以及 HCl 之外，會使得絕緣膜有脫落的現象，其他的溶劑中，依然是保持的相當完整。由此可知，聚醯亞胺/TiO2 複合沈積膜，對於各種化學溶劑有著相當不錯的阻值，且耐久性也是相當不錯的。

　　In this study, two kinds of monomers- 4, 4-diaminodiphenyl ether (ODA) and pyromellitic dianhydride (PMDA) were employed to synthesize the polyamic acid- a precursor of polyimide. TiO2 sol. was obtained from titanium ethoxide (TET) and acetylacetone by sol-gel method. After imidization, the PI/titania hybrid films were obtained. In order to understand whether the nano-titania particle was introduced into polymer matrix and enhanced the thermal properties, we employed instruments to test its thermal properties. Thermogravimetric analysis (TGA) and thermal mechanical analysis (TMA) were used to test the heat properties. According to the results of the TGA, the thermal decomposition temperature (Td) of the polyimide/titania hybrid films had the best value as the content of TiO2 was 1wt%. The temperature of decomposition was about 15℃ where was larger than that of the pure polyimide. From TMA results, we knew the glass transition temperature of polyimide/titania hybrids was larger than that of a pure polyimide. Besides, the dielectric properties of hybrid films as measured by four-point probe; the crystallization analyzed by X-ray spectrometer (XRD); furthermore, electron spectroscopy for chemical analysis (ESCA) and energy-dispersive spectrometer (EDS) were employed to measure the polyimide and polyimide/titaina hybrid films qualitatively and quantitatively. The surface morphology of the materials were observed with a scanning electron microscopy (SEM) and we could know the particle size of TiO2 by using transmission electron microscopy (TEM), the size of TiO2 in polyimide matrix was about 5 ~ 25nm.
　　In the second part, a precursor of 10wt% TiO2 content of polyimide/titania hybrids, changed the molar ratio of the triethylamine (TEA) and carboxyl group in polyamic acid (TEA/COOH) and the volume ratio of acetone and NMP (Acetone/NMP) solvent to obtain different electrobath which were used for electrophoretic deposition. The quantity of deposition, average deposition rate and the film thickness of the polyimide/titania passivation films changed because of the cell voltage and the electrophoresis deposition time. In this electrophoresis system, the amount of the passivation film was increased with the increasing cell voltage and the deposition time linearly. The average deposition rate only changed in the cell voltage, it also increased with cell voltage increased, and decreased with deposition time. Because of current (deposition rate) slowly decreased with the deposition time. In addition, the most important aspect about this electrophoresis process, which was controlled the thickness of the passivation films. The films thickness was controlled by the cell voltage and the deposition time, which could increase the thickness of the passivation films. SEM and SPM also observed the microstructure of the nano-titania particles and the dispersive conditions in the passivation films. The results indicated that the particles were dispersive homogeneously and without agglomeration in the passivation films. The theoretical analysis of this research showed that for the PAA with TiO2 sol. under applied voltage of 80V and based on the composition of the electrolyte which is the TEA/COOH mole ratio and the Acetone/NMP volume ratio.

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