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研究生: 李唯箏
Li, Wei-Zheng
論文名稱: 流體化床結晶技術副產物在弱酸系統以可見光芬頓法降解和礦化RB5的應用
Application of fluidized-bed crystallization by-product for degradation and mineralization of RB5 by visible-light assisted Fenton process in mild acidic system
指導教授: 黃耀輝
Huang, Yao-Hui
學位類別: 碩士
Master
系所名稱: 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年: 2023
畢業學年度: 111
語文別: 中文
論文頁數: 113
中文關鍵詞: 可見光芬頓法鐵銅雙金屬催化劑AOPsLMCTRB5
外文關鍵詞: AOPs, Visible light, RB5, LMCT, iron copper bimetallic catalyst
相關次數: 點閱:60下載:0
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  • 摘要I 致謝XVII 目錄XX 表目錄XXIV 圖目錄XXV 第一章 緒論1 1-1 研究起源1 1-2 研究目的與內容2 第二章 文獻回顧4 2-1 高級氧化處理技術(Advanced Oxidation Processes, AOPs)4 2-2 芬頓法(Fenton Process)5 2-3 光芬頓法(Photo-Fenton Process)8 2-3-1 光8 2-3-2 紫外光芬頓法 (UV-Fenton Process)10 2-3-3 可見光芬頓法(Visible Light -Fenton Process)12 2-3-4 太陽光芬頓法(Solar-Fenton Process)16 2-4 類芬頓法(Fenton-like Process)18 2-4-1 均相類芬頓(Homogeneous Fenton-like)18 2-4-2 異相類芬頓(Heterogeneous Fenton-like)20 2-4-3 雙金屬催化劑(Bimetallic catalyst)23 2-5 流體化床結晶(Fluidized bed crystallization, FBC)技術24 2-5-1 流體化床結晶技術副產物(FBC by-product)再利用27 2-6 偶氮染料(Azo dye)29 第三章 實驗設備、材料與方法33 3-1 研究架構與流程33 3-2 實驗設備35 3-2-1 Three Phase - Photo-Fenton 反應器35 3-3 符號及公式定義36 3-4 實驗藥品37 3-5 實驗步驟38 3-5-1 Three Phase – Photo-Fenton實驗步驟38 3-5-2 ESR自由基自旋捕捉實驗38 3-6 檢測儀器與分析方法40 3-6-1 總有機碳分析儀(Total Organic Carbon Analyzer)40 3-6-2 感應耦合電漿原子發射光譜儀(Inductively Coupled Plasma- Optical Emission Spectrometer, ICP-OES) 41 3-6-3 離子層析儀(Ion Chromatograph, IC)43 3-6-4 X射線光電子能譜儀(X-ray Photoelectron Spectroscopy, XPS)44 3-6-5 X射線繞射儀(X-ray Diffractometer, XRD)45 3-6-6 傅立葉轉換式紅外線光譜儀(Fourier Transform Infrared Spectrometer, FTIR) 46 3-6-7 掃描式電子顯微鏡 (Scanning Electron Microscope, SEM)48 3-6-8 能量散佈光譜儀(Energy Dispersive Spectrometer, EDS)49 3-6-9 電子自旋共振儀(Electron Spin Resonance Spectrometer, ESR) 50 3-6-10 總溶解性過氧物種濃度測定方法51 第四章 結果與討論53 4-1 Fe0.66Cu0.33-Al(OH)3顆粒固體分析53 4-1-1 SEM-EDS53 4-1-2 XRD 55 4-1-3 FTIR 56 4-1-4 XPS 59 4-2 Fe0.66Cu0.33-Al(OH)3輔助可見光芬頓系統操作條件最佳化61 4-2-1 RB5理論方程式61 4-2-2 反應pH值(pHr)之變因探討63 4-2-3 pHr 5初步空白實驗65 4-2-4 草酸添加濃度([OA]i)之變因探討72 4-2-5 雙氧水添加濃度([H2O2])之變因探討78 4-2-6 催化劑用量之變因探討80 4-3 Fe0.66Cu0.33-Al(OH)3輔助可見光芬頓系統之反應機制探討83 4-3-1 擔體空白實驗83 4-3-2 均相可見光芬頓系統84 4-3-3 從空白實驗中推測反應機制 87 4-3-4 自由基抑制實驗 89 4-3-5 ESR spin trap90 4-3-6 反應機制推測91 4-4 Fe0.66Cu0.33-Al(OH)3輔助可見光芬頓系統之應用92 4-4-1 RR195處理92 4-4-2 實驗中遇到的問題95 第五章 結論與建議98 5-1 結論98 5-2 建議100 參考文獻101 FBC反應器 112 流體化床結晶技術實驗(FBC)步驟113

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