非對稱性球體的自組裝行為以及可逆的螢光共振能量轉移主要是經由本實驗室所製備出的螢光染料官能化的雙面不對稱球體來進行研究，雙面不對稱球體主要是以500奈米的二氧化矽球體為主體，經由表面改質的方法對其中一個半球表面進行氨基的改質，並在上面接上名為Marina Blue 的螢光染料。本實驗的主體“雙面不對稱球體”為次微米等級，其製備及特性分析均在過去有深入探討。另一方面同時購買了平均粒徑80奈米之表面羧酸化聚丙烯腈微珠作自發性自組裝，這些聚丙烯腈奈米微珠已經預先帶有Chromeon 470之螢光染料在其中，可以當作螢光共振能量轉移的受體物質，而Marina Blue 螢光染料扮演的是螢光共振能量轉移的供體。球體在水中的自組裝行為主要是由500奈米帶有氨基正電荷的雙面不對稱球體與80奈米帶有羧酸基負電荷的聚丙烯腈微珠進行自組裝。在自組裝後藉由動態光散射粒徑分析儀觀察粒徑大小的變化。藉由輸入365奈米Marina Blue雙面不對稱球體的激發波長，可以觀察到611奈米Chromeon 470奈米微珠所產生的發射波長，以此來證實螢光共振能量轉移的發生。接著調整不同比例的球體也同時會造成不同的螢光共振能量轉移效應，因此接著在可逆自組裝的研究中同時導入超音波處理來分離自組裝聚集，觀察可逆的粒子自組裝以及組裝的時間相關係數可以發現雙面不對稱球體的自組裝行為以及與自組裝相關的螢光共振能量轉移為一個與時間相關的粒徑變化以及螢光共振能量轉移。

Fluorescence dye-functionalized Janus particles were synthesized for the asymmetric particle self-assembly and the reversible Forster Resonance Energy Transfer (FRET). A Janus particle cored with a 500 nm silica colloid was bi-functionalized with the amino-silane on one of its hemispheric surface and a fluorescence dye, Marina Blue, attached to this hemispheric surface. These Janus particles in the submicron scale were carefully fabricated and characterized, following the prior works. Commercially-available polyacrylonitrile (PAN) nanobeads with 80 nm in diameter and carboxylic surface-functionalities were employed as the self-assembly counterpart. These PAN nanobeads also contained a fluorescence dye, Chromeon 470, to be utilized as the FRET acceptor, while the Marina Blue Janus particles served as the FRET donor. Self-assembly of these two particles in an aqueous solution was performed by the positively-charged asymmetric 500 nm Janus particles and the negatively-charged 80 nm PAN nanobeads. The sizes of the assembled clusters were monitored by the dynamic light scattering (DLS). Successful FRET was confirmed by the 365 nm excitation to the Marina Blue Janus particles accompanied by the 611 nm emission of Chromeon 470 nanobeads. Variation of the particle ratios also resulted in the proportional FRET effects. Reversible particle self-assembly was also investigated by the introduction of ultrasonic treatment that separated the assembled clusters. Time-resolved FRET and DLS with the reversible particle self-assembly and the assembly correlation time revealed the asymmetric particle self-assembly from Janus particles and the assembly-dependent FRET performance.

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