有機發光二極體材料近年來為一非常重要的電激發光材料，在相
關文獻報導中，具1,3,4-oxadiazole 與carbazole 環衍生物，具有良好傳
輸電子及阻擋洞子傳輸的功能，且其相關的衍生物也常被運用於發藍
光的電激發光材料中。
本論文研究之目的，乃先合成出具藍色發光團之1,3,4—oxadiazole 或
carbazole環之pyridine 類化合物，再利用實驗室所開發出獨特的α-
氯醯基芳香hydrazine 氯化氫與pyridine 類化合物反應，合成出具
1,3,4-oxadiazole 環, carbazole 環及1,2,4- triazdo 環三種發光基團的
多雜環化合物，並將此所得之產物進行螢光性質(UV,PL)之測試，探
討取代基的改變對其光電性質的影響。
希望藉由光電性質的探討，拓展α-氯醯基芳香hydrazine 氯
化氫在合成小分子有機電激發光材料上的應用。希望藉由光電性質的探討，拓展α-氯醯基芳香肼 氯化氫在合成小分子有機電激發光材料上的應用。

Organic compounds, which can be used to make organiclight-emitting diodes, have recently become an interesting and important material. Research in looking for potential target compounds has been studied intensively. Compounds derived from 1,3,4-oxadiazoles and carbazoles had been reported having good electron-transporting and hole-transporting properties andhad been applied as blue light-emitting material.
The aims in this study are to synthesis potential blue light-emitting compounds and characterize the light-emitting properties. Polyheterocyclic compounds containing the moiety of 1,3,4-oxadiazole,carbazole, or 1,2,4-triazdo are our target compounds. The synthetic method for synthesizing these target compounds was reacting pyridines, which have both carbazole and 1,2,4-triazdo rings attached, with -chloroformylaryl-
hydrazine hychochloride. And the synthesized compounds were tested to study the effects of the various substituted groups on the electroluminescent properties.
The UV-visible and fluorescence studies indicated that derivatives of polyheterocyclic compounds containing the moieties of 1,3,4-oxadiazole and 1,2,4-triazdo (compounds 47) or the moieties 1,3,4-oxadiazole,carbazole and 1,2,4-triazdo (compounds
53) showed having the property of emitting green light. Compound such as the type 45, 46, and 52 containing only either
1,3,4-oxadiazole,carbazole and 1,2,4-triazdo moiety showed having the property of emitting blue light. In this study we have shown that by starting from -chloroformylaryl- hydrazine hychochloride
polyheterocyclic compounds, it is possible to synthesize potential target compounds with which to make OLED device.

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