簡易檢索 / 詳目顯示

研究生: 李楷為
LI, KAI-WEI
論文名稱: 雙相不銹鋼(SAF2304)在不同溫度下之動態壓縮變形行為與顯微結構特徵分析
Dynamic compressive deformation behavior and microstructural evolution of SAF 2304 duplex stainless steel over a wide range of temperatures
指導教授: 李偉賢
Lee, Woei-Shyan
學位類別: 碩士
Master
系所名稱: 工學院 - 機械工程學系
Department of Mechanical Engineering
論文出版年: 2016
畢業學年度: 104
語文別: 中文
論文頁數: 139
中文關鍵詞: 雙相不銹鋼(SAF2304)高溫變形高應變速率肥粒鐵相沃斯田鐵相差排密度
外文關鍵詞: SAF 2304 duplex stainless steel, high temperature deformation, high strain rate, ferrite phase, austenite phase, dislocation density
相關次數: 點閱:170下載:3
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 本文主要是探討雙相不銹鋼(SAF2304)在不同溫度及高速與應變速率之撞擊特性與微觀結構分析。利用壓縮式霍普金森桿撞擊試驗機(Hopkinson bar)及加溫裝置,分別於應變速率2800 s-1、4000 s-1和5400s-1及實驗環境溫度25℃、450℃、900℃各條件下,進行高速撞擊變形,以分析材料在塑變形為中巨觀與微觀結構變化,並導入構成方程式以描述材料之應力應變關係。
    實驗結果顯示,雙相不銹鋼(SAF2304)機械性質隨溫度和應變速率的不同而有顯著差異。在相同的溫度下,塑流應力值、加工硬化率、應變速率敏感性係數、溫度敏感性係數及理論溫升量皆隨應變速率增加而上升;在當固定應變速率時,其塑流應力值、加工硬化率、應變速率敏感性係數、溫度敏感性係數及理論溫升量則會隨溫度之增加而下降,而熱活化體積則是呈現相反的趨勢。所有之應力與應變特性可藉由結合BCC及FCC之Zerilli-Armstrong構成方程式準確的描述。
    在微觀結構方面,利用光學顯微鏡下觀察金相結構,並使用Feritscope MP30儀器量測肥粒鐵相及沃斯田鐵相含量的變化率,同時亦觀測相關動態回復與動態再結晶之特徵,以了解不同之溫度及應變速率對相變化之影響。經由穿透式電子顯微鏡觀察下則可發現差排密度隨著應變速率上升及溫度下降而上升,而差排密度與塑流應力之關係可藉由Bailey-Hirsch type關係式來定量描述。

    Dynamic impact response and microstructural characteristics of SAF 2304 duplex stainless steel are investigated under strain rates of 2800s−1, 4000s−1 and 5400s−1 and different temperatures of 25ºC, 450ºC and 900ºC, respectively, using a compressive split-Hopkinson pressure bar. The results indicate that mechanical properties of SAF 2304 duplex stainless steel are sensitive to temperature and strain rate. The flow stress, work hardening rate, strain rate sensitivity and temperature sensitivity all increase with increasing strain rate, but decrease with increasing temperature. However, the thermal activation volume and activation energy decrease with increasing strain rate, but increase with increasing temperature. The Zerilli-Armstrong constitutive equation can be used to describe the deformation behavior of SAF 2304 duplex stainless steel under current tested conditions. The height reduction and microhardness increase with the strain rate. OM observations reveal scattered island austenite phase appear within the ferrite phase matrix. The amount of ferrite phase decreases as the strain rate increases. TEM observations show that the dislocation density increases with increasing strain rate, but decreases with increasing temperature.

    中文摘要 I ABSTRACT II 致謝 VIII 總目錄 IX 表目錄 XII 圖目錄 XIII 符號說明 XX 第一章 前言 1 第二章 理論與文獻回顧 3 2-1雙相不銹鋼之介紹 3 2-1-1影響雙相不銹鋼強化機構的合金元素 3 2-1-2影響雙相不銹鋼性質的顯微組織 4 2-2雙相不銹鋼(SAF2304)之介紹 6 2-3塑性變形之機械測試類別 6 2-4一維波傳理論 8 2-5霍普金森撞擊試驗機之原理 10 2-6塑性變形機制 12 2-7構成方程式 16 第三章 實驗方法及步驟 31 3-1實驗流程 31 3-2實驗儀器與設備 31 3-2-1 CNC放電加工線切割機 31 3-2-2金相研磨拋光機 32 3-2-3動態機械性質測試系統:霍普金森撞擊試驗機 32 3-2-4加熱裝置 34 3-2-5低速切割機 34 3-2-6雙噴式電解拋光機 34 3-2-7微硬度試驗機 34 3-2-8肥粒鐵含量測定儀(Feritscope MP30) 35 3-2-9光學顯微鏡 (OM) 35 3-2-10穿透式電子顯微鏡 (TEM) 35 3-3實驗步驟 36 3-3-1實驗試件製備 36 3-3-2動態衝擊試驗 37 3-3-3微硬度實驗 38 3-3-4肥粒鐵含量之測定 38 3-3-5試件金相之觀察(OM) 38 3-3-6穿透式電子顯微鏡(TEM)試片製備 38 第四章 實驗結果與討論 42 4-1應力-應變曲線 42 4-2加工硬化 43 4-3應變速率敏感性係數 44 4-4熱活化體積 46 4-5活化能 47 4-6溫度敏感性係數 48 4-7應變速率及溫度綜合效應 49 4-8理論溫升量 50 4-9材料構成方程式 51 4-10 微硬度變化 52 4-11 OM金相組織觀察 53 4-12 TEM顯微結構觀察 54 第五章 結論 132 參考文獻 134

    [1] J.-O. Nilsson, "Super duplex stainless steels," Materials science and technology, vol. 8, pp. 685-700, 1992.
    [2] R. M. Davison and J. D. Redmond, "Practical guide to using duplex stainless steels," Materials performance, vol. 29, pp. 57-62, 1990.
    [3] J. A. Jiménez, M. Carsí, O. Ruano, and F. Penalba, "Characterization of a δ/γ duplex stainless steel," Journal of materials science, vol. 35, pp. 907-915, 2000.
    [4] A. Weisbrodt-Reisch, M. Brummer, B. Hadler, B. Wolbank, and E. Werner, "Influence of temperature, cold deformation and a constant mechanical load on the microstructural stability of a nitrogen alloyed duplex stainless steel," Materials Science and Engineering: A, vol. 416, pp. 1-10, 2006.
    [5] A. Iza-Mendia, A. Pinol-Juez, J. Urcola, and I. Gutierrez, "Microstructural and mechanical behavior of a duplex stainless steel under hot working conditions," Metallurgical and Materials Transactions A, vol. 29, pp. 2975-2986, 1998.
    [6] N. C. Renton, A. M. Elhoud, and W. F. Deans, "Effect of Plastic Deformation on the Corrosion Behavior of a Super-Duplex Stainless Steel," Journal of Materials Engineering and Performance, vol. 20, pp. 436-444, 2011.
    [7] R. Andersson, "Deformation characteristics of stainless steels," Luleå University of Technology, 2005.
    [8] I. M. Association and T. Stainless, Practical guidelines for the fabrication of duplex stainless steels: International Molybdenum Association, 2009.
    [9] 李東明, "不同冷卻速率對雙相不銹鋼顯微組織與衝擊試驗的影響," 2003.
    [10] J. Charles and S. Bernhardsson, "Duplex Stainless Steels'91. Vol. 1," Beaune, France, 28-30 Oct. 1991, p. 1991, 1991.
    [11] M. A. Meyers, Dynamic behavior of materials: John wiley & sons, 1994.
    [12] U. Lindholm, "High strain rate tests, Techniques of metal research vol. 5 part 1, Ed. J," ed: Wiley, 1971.
    [13] U. Lindholm and L. Yeakley, "High strain-rate testing: tension and compression," Experimental Mechanics, vol. 8, pp. 1-9, 1968.
    [14] J. Achenbach, Wave propagation in elastic solids vol. 16: Elsevier, 2012.
    [15] W.-S. Lee and C.-F. Lin, "Plastic deformation and fracture behaviour of Ti–6Al–4V alloy loaded with high strain rate under various temperatures," Materials Science and Engineering: A, vol. 241, pp. 48-59, 1998.
    [16] J. Fagbulu and O. Ajaja, "Dislocation distributions and creep mechanisms," Journal of materials science letters, vol. 6, pp. 894-896, 1987.
    [17] A. Kumar, F. Hauser, and J. Dorn, "Viscous drag on dislocations in aluminum at high strain rates," Acta Metallurgica, vol. 16, pp. 1189-1197, 1968.
    [18] J. Campbell and W. Ferguson, "The temperature and strain-rate dependence of the shear strength of mild steel," Philosophical Magazine, vol. 21, pp. 63-82, 1970.
    [19] R. Broudy, "Dislocations and Mechanical Properties of Crystals," Journal of the American Chemical Society, vol. 80, pp. 5009-5010, 1958.
    [20] G. E. Deiter, "Mechanical metallurgy," McGraw-Hill, pp. 221-227, 1986.
    [21] H. Conrad, "Thermally activated deformation of metals," JOM, vol. 16, pp. 582-588, 1964.
    [22] W. Ferguson, A. Kumar, and J. Dorn, "Dislocation damping in aluminum at high strain rates," Journal of Applied Physics, vol. 38, pp. 1863-1869, 1967.
    [23] J. Campbell, "Dynamic plasticity: macroscopic and microscopic aspects," Materials Science and Engineering, vol. 12, pp. 3-21, 1973.
    [24] J. Campbell and A. Dowling, "The behaviour of materials subjected to dynamic incremental shear loading," Journal of the Mechanics and Physics of Solids, vol. 18, pp. 43-63, 1970.
    [25] W. Johnson, Impact strength of materials: Edward Arnold London, 1972.
    [26] Z. Gronostajski, "The constitutive equations for FEM analysis," Journal of Materials Processing Technology, vol. 106, pp. 40-44, 2000.
    [27] G. R. Johnson and W. H. Cook, "A constitutive model and data for metals subjected to large strains, high strain rates and high temperatures," in Proceedings of the 7th International Symposium on Ballistics, 1983, pp. 541-547.
    [28] L. Meyer, N. Herzig, T. Halle, F. Hahn, L. Krueger, and K. Staudhammer, "A basic approach for strain rate dependent energy conversion including heat transfer effects: An experimental and numerical study," Journal of materials processing technology, vol. 182, pp. 319-326, 2007.
    [29] D. Umbrello, R. M’saoubi, and J. Outeiro, "The influence of Johnson–Cook material constants on finite element simulation of machining of AISI 316L steel," International Journal of Machine Tools and Manufacture, vol. 47, pp. 462-470, 2007.
    [30] F. J. Zerilli and R. W. Armstrong, "Constitutive equation for HCP metals and high strength alloy steels," High strain rate effects on polymer, metal and ceramic matrix composites and other advanced materials, pp. 121-126, 1995.
    [31] F. J. Zerilli and R. W. Armstrong, "Dislocation‐mechanics‐based constitutive relations for material dynamics calculations," Journal of Applied Physics, vol. 61, pp. 1816-1825, 1987.
    [32] F. H. Abed and G. Voyiadjis, "A consistent modified Zerilli-Armstrong flow stress model for BCC and FCC metals for elevated temperatures," Acta Mechanica, vol. 175, pp. 1-18, 2005.
    [33] T. Holmquist and G. Johnson, "Determination of constants and comparison of results for various constitutive models," Le Journal de Physique IV, vol. 1, pp. C3-853-C3-860, 1991.
    [34] Y. Lin and X.-M. Chen, "A combined Johnson–Cook and Zerilli–Armstrong model for hot compressed typical high-strength alloy steel," Computational Materials Science, vol. 49, pp. 628-633, 2010.
    [35] Y. Lin and X.-M. Chen, "A critical review of experimental results and constitutive descriptions for metals and alloys in hot working," Materials & Design, vol. 32, pp. 1733-1759, 2011.
    [36] H. Sieurin, "Fracture toughness properties of duplex stainless steels," 2006.
    [37] D. Klahn, A. Mukherjee, and J. Dorn, "STRAIN-RATE EFFECTS," California Univ., Berkeley. Lawrence Radiation Lab.1970.
    [38] M. Meyers, D. Benson, O. Vöhringer, B. Kad, Q. Xue, and H.-H. Fu, "Constitutive description of dynamic deformation: physically-based mechanisms," Materials Science and Engineering: A, vol. 322, pp. 194-216, 2002.
    [39] S. Tavares, J. Pardal, L. Lima, I. Bastos, A. Nascimento, and J. de Souza, "Characterization of microstructure, chemical composition, corrosion resistance and toughness of a multipass weld joint of superduplex stainless steel UNS S32750," Materials Characterization, vol. 58, pp. 610-616, 2007.
    [40] G. F. V. Voort, G. M. Lucas, and E. P. Manilova, "Metallography and Microstructures of Heat-Resistant Alloy," Materials Park, OH: ASM International, 2004., pp. 820-859, 2004.
    [41] J. Y. Choi, J. H. Ji, S. W. Hwang, and K.-T. Park, "TRIP aided deformation of a near-Ni-free, Mn–N bearing duplex stainless steel," Materials Science and Engineering: A, vol. 535, pp. 32-39, 2012.
    [42] S. Esmaeili, L. Cheng, A. Deschamps, D. Lloyd, and W. Poole, "The deformation behaviour of AA6111 as a function of temperature and precipitation state," Materials Science and Engineering: A, vol. 319, pp. 461-465, 2001.
    [43] B. Viguier, "Dislocation densities and strain hardening rate in some intermetallic compounds," Materials Science and Engineering: A, vol. 349, pp. 132-135, 2003.
    [44] D. Chu and J. Morris, "The influence of microstructure on work hardening in aluminum," Acta materialia, vol. 44, pp. 2599-2610, 1996.
    [45] U. Andrade, M. Meyers, and A. Chokshi, "Constitutive description of work-and shock-hardened copper," Scripta metallurgica et materialia, vol. 30, pp. 933-938, 1994.
    [46] L. Shi and D. Northwood, "The mechanical behavior of an AISI type 310 stainless steel," Acta metallurgica et materialia, vol. 43, pp. 453-460, 1995.
    [47] M. Hättestrand, P. Larsson, G. Chai, J.-O. Nilsson, and J. Odqvist, "Study of decomposition of ferrite in a duplex stainless steel cold worked and aged at 450–500° C," Materials Science and Engineering: A, vol. 499, pp. 489-492, 2009.
    [48] C. Zener and J. Hollomon, "Effect of strain rate upon plastic flow of steel," Journal of Applied physics, vol. 15, pp. 22-32, 1944.
    [49] J. Jonas, C. Sellars, and W. M. Tegart, "Strength and structure under hot-working conditions," Metallurgical Reviews, vol. 14, pp. 1-24, 1969.
    [50] M. Barnett, "Influence of deformation conditions and texture on the high temperature flow stress of magnesium AZ31," Journal of Light Metals, vol. 1, pp. 167-177, 2001.
    [51] R. H. A. Abas and N. K. Taieh, "Experimental Study of the Thermal Diffusivity and Heat Capacity Concerning Some Duplex Stainless Steel," Khwarizmi Engineering, vol. 11, pp. 51-61, 2015.
    [52] A. Dehghan-Manshadi, M. Barnett, and P. Hodgson, "Microstructural evolution during hot deformation of duplex stainless steel," Materials science and technology, vol. 23, pp. 1478-1484, 2007.
    [53] L. Duprez, B. De Cooman, and N. Akdut, "Flow stress and ductility of duplex stainless steel during high-temperature torsion deformation," Metallurgical and Materials Transactions A, vol. 33, pp. 1931-1938, 2002.
    [54] N. Ryan and H. McQueen, "Flow stress, dynamic restoration, strain hardening and ductility in hot working of 316 steel," Journal of Materials Processing Technology, vol. 21, pp. 177-199, 1990.
    [55] H. Tan, Z. Wang, Y. Jiang, Y. Yang, B. Deng, H. Song, et al., "Influence of welding thermal cycles on microstructure and pitting corrosion resistance of 2304 duplex stainless steels," Corrosion Science, vol. 55, pp. 368-377, 2012.
    [56] W.-Y. Hsiao, S.-H. Wang, C.-Y. Chen, J.-R. Yang, and W.-S. Lee, "Effects of dynamic impact on mechanical properties and microstructure of special stainless steel weldments," Materials Chemistry and Physics, vol. 111, pp. 172-179, 2008.
    [57] A. Ramirez, J. Lippold, and S. Brandi, "The relationship between chromium nitride and secondary austenite precipitation in duplex stainless steels," Metallurgical and materials transactions A, vol. 34, pp. 1575-1597, 2003.
    [58] R. Ham, "The determination of dislocation densities in thin films," Philosophical Magazine, vol. 6, pp. 1183-1184, 1961.
    [59] Y. Tomota, P. Lukas, S. Harjo, J. Park, N. Tsuchida, and D. Neov, "In situ neutron diffraction study of IF and ultra low carbon steels upon tensile deformation," Acta materialia, vol. 51, pp. 819-830, 2003.
    [60] W.-S. Lee, C.-F. Lin, T.-H. Chen, and M.-C. Yang, "Effects of prestrain on high temperature impact properties of 304L stainless steel," Journal of Materials Research, vol. 25, pp. 754-763, 2010.

    下載圖示 校內:立即公開
    校外:立即公開
    QR CODE