本研究以一定比例之黏稠劑添加於漁船用油中，改變新配方漁船燃料油之顏色外觀並增加新配方漁船燃料油之黏滯性，減少新配方漁船燃料油於車用柴油引擎之適用性，如此可嚇阻漁船用油非法使用於路上行駛中車輛。
為達成上述目標，本研究按下列工作項目執行：1.與油公司進行油品協談，擬定二種新漁船用油之配方(RDS0.5及PFO0.5)；2.觀察高級柴油(PDF)、甲種漁船用油(FBFA)、甲種漁船用油添加0.5%加氫脫硫殘渣油(RDS0.5)及甲種漁船用油添加0.5%熱解燃料油(PFO)之油品顏色外觀；3.分析各油品之硫、總芳香烴含量、動力黏滯度及蒸餾溫度T90；4.於柴油引擎動力計進行高級柴油、甲種漁船用油、RDS0.5及PFO0.5之性能及污染測試；5.進行甲種漁船用油、RDS0.5及PFO0.5之漁船實船測試作業。
經過實驗分析得到結果如下：1. 若擬以油品之顏色外觀進行稽查取締非法油品之初步篩選時，以RDS0.5為未來新配方漁船用油之較佳選擇。2. 若FBFA被非法流用至路上行駛中車輛，預期柴油車排放廢氣之硫氧化物(SOX)排放量將增加約162倍，且總芳香烴化合物亦將顯著增加。以質量平衡之方法計算之，添加0.5% RDS或0.5% PFO後，漁船用油之硫含量變化不大。3. 重型柴油引擎動力計測試，使用FBFA、RDS0.5及PFO0.5之PM排放係數分別高出使用PDF者五成以上，而Total-PAHs 排放係數亦分別高出使用PDF者，漁船用油非法流用至路上行駛中車輛，將大幅增加PM及Total-PAHs之排放量。4. 漁船之實船測試結果顯示，與使用FBFA或PFO0.5於漁船比較，使用RDS0.5為漁船之燃料油可減少PM約為43.5%，增加Total-PAHs之排放係數約為31.2%，而Total-BaPeq之排放係數則無顯著影響。若以RDS0.5為未來新配方漁船用油，不但可由油品之顏色外觀來區別PDF或RDS0.5，且可於RDS0.5用於漁船之實船運轉時減少PM 排放及且Total-BaPeq 之排放無顯著影響。
對未來應用方面，可建議政府實行RDS0.5替代FBFA方案，並加設汽車攔檢站實施抽油比對，此法可快速初步判斷是否有違法使用FBFA情形，如顏色深黑則另行對該車燃油進行含硫率檢驗，以進一步確認是否違用。

In order to change the color of FBFA appearance, enhance the viscosity of FBFA and reduce the feasibility of FBFA being used in the traveling diesel-vehicles (TDVs), the working items and method of study were as follows. 1. A discussion of manufacturing process and additives of FBFA and the establishment of two new ingredients of FBFA (RDS0.5 and PFO0.5); 2. Understanding the numbers, tonnage, horse power, tones per fishing boat and horse power per tone of fishing boat in Taiwan from 1992 to 2006; 3.Observing the color appearance of PDF, FBFA, RDS0.5 and PFO0.5; 4.The measurements of sulfur and total-aromatic contents, dynamic viscosity and T90 of PDF, FBFA, RDS and PFO; 5.The tests of mechanical performance and pollutant emissions for PDF, FBFA, RDS0.5 and PFO0.5, respectively on a diesel-engine dynamometer; 6.The test of FBFA, RDS0.5 and PFO0.5, respectively being used in three real-scale fishing boats; 7. The feasibility assessments of FBFA with new ingredients being used in road traveling diesel vehicles and real-scale fishing boats, respectively; 8. Proposing a leading direction of policy performance for new ingredient FBFA.
The major results and conclutions of this study are as follows：
(1). By using the appearance and color of fuel oil for the preliminary screening of illegal diesel fuel, the RDS0.5 will be a better choice for fishing-boat fuel.
(2). If the fishing boat fuel being used in the traveling diesel vehicles, the emission amount of SOx will be increased approximately by 162 times and the total-PAH emission will be also elevated very significantly. This is one of the major reasons why the fishing boat fuel being used illegally in the traveling diesel vehicle needs to be strongly prohibited. By using the mass balance analysis, by adding 0.5% RDS or 0.5% PFO in the fishing boat fuel (FBFA), the sulfur content of FBFA will be no significant change.
(3). The mean PM emission factors from the FBFA, RDS0.5 and PFO0.5 fueled diesel engines were higher than that of PDF by 72.2%, 63% and 87.4%, respectively and the mean total-PAH emission factors from the FBFA, RDS0.5 and PFO0.5 fueled diesel engines were higher than that of PDF by 72.2%, 63% and 87.4%, respectively. The fishing boat fuel being used in the traveling diesel vehicles did increase the emissions of both PM and PAHs.
(4). The results of real-boat testing displayed that by using RDS0.5 as fishing boat fuel can reduce the emission factors of PM by 43.5%, increase the emission factors of total-PAHs by 43.5% and showed no significant difference in total-BaPeq. It revealed that by using RDS0.5, the majority of advantage will be very positive.
(5). Performance of New policy: Replace the FBFA as RDS0.5. By looking the appearance and color of fuel oil, if a dark-brown color diesel-fuel is found during the preliminary screening process, the diesel fuel needs a further analysis for sulfur content.

Abu-Qudais M., Haddad O., Qudaisat M., “The effect of alcohol fumigation on diesel engine performance and emissions,” Energy Conversion & Management, 41, 389-399, (2000).
Agreement on Subsidies and Countervailing Measures, World Trade Organization, (1995).
Ajava E.A., Bachchan Singhb, T.K. Bhattacharyac,“Experimental study of some performance parameters of a constant speed stationary diesel engine using ethanol-diesel blends as fuel,” Biomass and Bioenergy 17: 357-365, (1999).
Akhemdov, A. I., Chemistry and Technology of Fuels and Oils, V.23, N. 3-4, p. 147, ( 1987).
Akhemdov, A. I., Levshina, A. M., Petroleum Chemistry: USSR, V. 26, N. 1, p.10, (1986).
Akhmedov, A. I. and Isakov, E. U.,Chemistry and Technology of Fules and Oils, V. 25, N.3-4 , p.156,(1989).
Akio Kamiya, Youki Ose, “Mutagenic activity and PAH analysis in municipal incinerators.” The Science of The Total Environment, V. 61, P. 37-49, (1987).
Article 1 and 3, General Agreement on Tariffs and Trade., (1994).
Badger G. M. and Spotswood T. M., J., Chem. Soc., 4420, (1960)
Bang-Quan Hea, Shi-Jin Shuaia, Jian-Xin Wanga, and Hong Heb, “The effect of ethanol blended diesel fuels on emissions from a diesel engine,” Atmospheric Environment, Vol 37, pp4965–4971 , (2003).
Barbara, K., Kames, N., “Atmospheric Chemistry: Fundamatals and Experimental Techniques”, (1986)
Barfknecht, T. R., Prog. Energy Combust. Sci., Vol.9, pp.199-237, (1983)
Bjorseth, A. and Ramahl, T., “Sources and Emission of PAH”, Handbook of Polycyclic Aromatic Hydrocarbons, Vol.1, Marcel Dekker, Inc., New York and Basel, (1983)
Carol D. Soontjens, Kristina Holmberg, Roger N. Westerholm and Joseph J. Rafter, “Characterization of polycyclic aromatic compounds in diesel exhaust particulate extract responsible for aryl hydrocarbon receptor activity,” Atmospheric Environment, V.31, I.2, P.219-225, (1997)
Chen, S. J., Liao, S. H., Jian, W. J., Lin, C. C., “Particle size distribution of aerosol carbons in ambient air”, Environmental International, Vol.23, No.4, pp.475-488, (1997)
Cheng Kang Li and Richard M. Kamens, “The use of polycyclic aromatic hydrocarbons as source signatures in receptor modeling,” Atmospheric Environment, Part A. General Topics, Volume 27, Issue 4, March 1993, Pages 523-532
Collier AR, Rhead MM, Trier CJ, Bell MA. Polycyclic aromatic compound profiles from a light-duty direct-injection diesel engine. Fuel 74:363-367 (1995)
Douglas H. Lowenthal, Barbara Zielinska, Judith C. Chow, John G. Watson, Mridul Gautam, Donald H. Ferguson, Gary R. Neuroth and Kathy D. Stevens, “Characterization of heavy-duty diesel vehicle emissions,” Atmospheric Environment, V.28, I.4, P.731-743, (1994)
Eva S Hansen. “Mortality of mastic asphalt workers.” Scand J work Environ Hlth;17:20-24, (1991).
Frenklach, M., Clary, D. W., Yuan T., Gardine C.W., and Stein S.E., “Detailed kinetic Modeling of Soot Sybposium (International) on Combustion”, The Conmbustion Institute, Pittsburgh, pp.887, (1985)
Grimmer, G., “Environmental Carcinogens: Polycyclic Aromatic Hydrocarbons”, CRC Press Inc, (1983)
Hansen Alan C., Zhang Qin, aand Lyne Peter W.L., “Ethanol-diesel fuel blends — a review,” Bioresource Technology, 96, pp 277-285, (2005).
Harrison, R. M., Smith, D. J. T., Luhana, L., “Source Apportionment of Atmospheric Polycyclic Aromatic Hydrocarbons Collected from an Urban Location in Birmingham, U.K.”, Environmental Science & Technology, Vol.30, pp.825-832, (1996).
Henrik Simonsen and Jerzy Chomiak , 1995 ,”Testing and Evaluation of Ignition Improvers for Ethanol in a DI Diesel Engine “,SAE Paper NO.952512.
Heywood, J. B., Internal combustion engine fundamentals, Mcgraw-Hill, 1988
Howard S., Hess and Andre’L., Boehman,”Experimental Studies of the Impact of CETANERTM on Diesel Combustion and Emissions”,SAE Paper NO.2000-01-2886, (2000).
IARC, “Polynuclear aromatic compounds. Part1. Chemical, environmental and experimental data,” Office of Health and Environmental Assessment, U.S. Environmental Protection Agency, Washington, DC, (1983)
Josephson, J., “Polynuclear Aromatic Hydrocarbons”, Environmental Science & Technology, Vol.18, No.3, pp.93A-95A, (1984)
Karcher, W., “Reference Materials for the Analysis of Polycyclic Aromatic Compounds” Handbook of Polycyclic Aromatic Hydrocarbons, Marcel Dekker, Inc., (1983)
Katz, M. Chan, C., “Comparative Distribution of Eight Polycyclic Aromatic Hydrocarbons in Airbone Particulates Collected by Conventional High-Volume Sampling and by Size Fractionation”, Environmenatl Science & Technology, Vol 14, pp.838-843, (1980)
Lee W.J., Wang Y.F., Lin T.C., Chen Y.Y., Lin W.C., Ku C.C., and Cheng J.T., “PAH characteristics in the ambient air of traffic-source”, The Science of the Total Environment, pp.185-200, (1995).
Leonardi, H. Burtscher and H. C. Siegmann, “Size-dependent measurement of aerosol photoemission from particles in diesel exhaust,” Atmospheric Environment. Part A. General Topics, V. 27, I. 8, P. 1251-1254, (1993)

Li De-gang, Huang Zhen, Lu Xingcai, Zhang Wu-gao, and Yang Jian-guang, “Physical-chemical properties of ethanol–diesel blend fuel and its effect on performance and emissions of diesel engines,” Renewable Energy, 30, pp967–976, (2005).
Lin Y. C., Lee W.J., Li H.W., Chen C.B., Fang G.C., and Tsai P.J., “Impact of using fishing boat fuel with high poly aromatic content on the emission of polycyclic aromatic hydrocarbons form the diesel engine”, Atmospheric Environment, Vol.40, pp.1601-1609, (2006).
Litt, Fredric A., Lubrication Engineering, V. 42, N. 5,May, p. 287, (1986).
Lu H. B., Huang Z., Jiang D. M., Liu B., Zhang J. Q. and Wang X. B.,“Engine performance and emissions of a compression ignition engine operating on the diesel-methanol blends,” Proc. Instn. of Mech. Engrs., Part D: J. of Automobile engineering, Vol. 218, www.paper.edu.cn, (2004).
Masclet P., Mouvier g., and Nikolaou K., “Relative Decay Index and Sources of Polycyclic Aromatic Hydrocarbons”, Atmospheric Environment, Vol.20, pp.439-445, (1986)
Menzie C.A., Potocki, B.B., Santodonato, J., “Exposure to Carcinogenic PAHs in the Environment.” Environ. Sci. J. Environ. Sci. Health, Vol.31A, pp.1981-2003, (1992)
Mi H.H., Lee W.J., Chen C.B., Yang H.H., and Wu S.J., “Effect of fuel aromatic content on PAH emission from a heavy-duty engine”, Chemosphere, Vol.41, pp.1783-1790, (2000).
Mi H.H., Lee W.J., Wu T.L., Lin T.C., Wang L.C., andChao H.R., “PAHs Emission form a Gasoline-Powered Engine”, J.Environ.Sci.Health, Vol. A31(8), pp.1981-2003, (1996)
Mi. H. H.; Lee, W. J., Chen, S. J.; Lin, T. C., Wu, T. L., Hu, J. C. "Effect of the Gasoline Additives on PAH Emission", Chemosphere, Vol. 36, No. 9, pp. 2031-2041.(1998).
Nisbet, I.C.T., “Review and evaluation of the evidence for cancer assotiated with air pollution,” U.S. Environmental Protection Agency, Washinton, DC, (1984).
Parkinson, P., “Casarett and Doull’s Toxicology, the basic science of poisons, unit 2: Disposition of toxicants, ” 5th Ed., New York Pergamon Press., : 114-125., (1992).
Perena,F.P. and Ahmed,A.K., Respirable Particles, Ballinger Publish Co., (1979)
Redmond C. K. et al. lnog-term mortality study of steel-works:mortality from malignant neoplasms amog coke oven works.J Occup Med, 14, 621-29, (1972).
Rui de Abrantes, João V. de Assunção, Célia R. Pesquero, “Emission of polycyclic aromatic hydrocarbons from light-duty diesel vehicles exhaust,” Atmospheric Environment, V. 38, I. 11, P. 1631-1640, (2004)
Schinder KP. Integrated diesel European action(IDEA): study of diesel combustion. SAE Paper 920591, (1992).
Scott D. Schwab, Gregory H. Guinther and Keith T. Miller., 1999,“The Effects of 2-Ethylhexyl Nitrate and Di-Tertiary –Butyl Peroxide on the Exhaust Emissions from an Heavy –Duty Diesel Engine”, SAE Paper NO.1999-01-1478, (1999).
Sheu H.L., Lee W.J., Tsai J.H., Fan Y.C., Su C.C., Chao H.R., “Particle Size Distribution Of Polycyclic Aromatic Hydrocarbons In The Ambient Air Of A Traffic Intersection”, J. Environ. Sci. Health, Vol.A31(6), pp.1293-1316, (1996A)
Shuichi K., H. Usisaki ,Clasen, S. Campbell, and K.T.Rhee,”MTBE for Improved Diesel Combustion and Emission?”,SAE Paper NO.941688, (1994).
Sisovic, A., Fugas, M., “Smoke Concentration as an Indicator of Polycyclic Aromatic Hydrocarbons Levels in the Air”, Environmental Monitoring and Assessment, Vol.45, No.2, pp.201-207, Apr, (1997)
Sjögren M, Li H, Rannug U, Westerholm R. “A multivariate statistical analysis of chemical compositions and physical characteristics of ten diesel fuels.” Fuel 74: 983-989, (1995).
Tadashi M., Ming Z., Takemi C., and Young –Taig Oh, “Simultaneous Reduction of Smoke and NOx from a DI Diesel Engine with EGR and Dimethyl Carbonate”, SAE Paper NO.952518, (1995).
Takashi Sakamoto, “Combustion control of direct injection methanol engine using a combination of charge heating and exhaust gas recirculation,” JSAE Review 16, pp 369-373, (1995).
Tuominen, J., Salomass, S., Pysalo, H., Skytta, E., Tikkanen, L., Nurmela, T., Sorsa, M., et al., “Polynuclear Aromatic Hydrocarbons and genotoxicity in particulate and vapor phase of ambient air: Effect of traffic season and metrological conditions, “Environ. Sci. & Technol., 22: 1228-1234., (1988)
US EPA, “Locating and Estimating Air Emission from Sources of the Polycyclic Organic Matter (POM)”, EPA-45014-84-007p, (1987)
Van der Waal,G., J. Synthetic Lubrication, V. 4, N. 4 , p.267, (1987).
Van Rooij, G.M., Bodelier-Bade, M.M., Hopmans, P.J., Jongeneelen, F.J., “Reduction of urinary 1-hydroxypyrene excretion in coke-oven workers exposed to polycyclic aromatic hydrocarbons due to improved hygienic skin protective measures,” Ann Occup Hyg, 38(3):247-256, (1994).
Van Rooij, G.M., Bodelier-Bade, M.M., Jongeneeien, F.J., “Estimation of individual dermal and respirstory uptake of polycyclic aromatic hydrocarbons in 12 coke oven workers,”Brit J Ind Med, 50: 623-632, (1993).
Veli-Matti, Kerminen, “The effects of particle chemical character and atmospheric processes on particle hygroscopic properties,” Journal of Aerosol Science, V. 28, I. 1, P. 121-132, (1997)
Ver Strate, G. and Struglinski, M. J., “The Proceedings of the ACS.” Div. of Polymeric Materials Science and Engineering, V.61, p. 252.
Westerholm R, Li H. “A multivariate statistical analysis of fuel-related polycyclic aromatic hydrocarbon emissions from heavy-duty diesel vehicles.” Environ Sci Technol 28:965-971, (1994).
Williams, P.T., Abbass, M.K., and Andrews, G.E., “Diesel particulate emission: the role of unburned fuel,” Combust Flame V. 75, P. 1-24, (1989).
World Trade Organization, G/SCM/N/38/KOR., (1998)
World Trade Organization, TN/RL/W/111、115、119、130, (2003)
Yang H. H., Chiang C. F., Lee W. J., Hwang K. P., and Wu M. F., “Size Distribution and Dry Deposition of Road Dust PAHs”, Environment. International,.25(8), p.585-597, (1999).
Yang H.H., Lee W.J., Mi H.H., and Wong C.H., “PAH Emissions Influenced by Mn-Based Additive and Turbocharging from a Heavy-Duty Diesel Engine”, Environment.International, 24(4), pp.389-403, (1998).
Yoshio Sato, Akira Noda,
Zandere M., “Physical and Chemical Properties of Polycyclic Aromatic Hydrocarbons”, Marcel Dekker Inc., (1985)
中國石油協會，石油煉製工業淺說，1982。
中華民國漁業法第五十九條, 2008
中華民國漁業法實行細則第二十八條, 2000
中華民國營業稅法第八條, 2003
王琳麒, “石化廢棄物焚化爐排放多環芳香烴化合物之研究”, 國立成功大學環境工程學系碩士論文, 1996
王雅芬, “交通污染源大氣中多環芳香烴化合物特徵之探討”, 國立成功大學環境工程學系碩士論文, 1993
吳炎東, “柴油引擎二階段混燒與燃料添加劑間交互作用之特性”, 國立雲林科技大學機械工程系碩士論文, 2004
林成原, “探討車用天然氣成份之引擎性能和污染排氣特性”，1997台北天然氣公車研討會財團法人車輛研究測試中心, 台北, 1997.
林淵淙, “生質柴油及乳化柴油對引擎排放廢氣污染減量及提升能源效率之研究”,國立成功大學環境工程學系博士論文, 2006.
林淵淙, “餐廳廚房排放廢氣及周圍大氣中多環芳香烴化合物之特徵”, 國立成功大學環境工程學系碩士論文, 2000
張育誠, 柴油機燃料添加二次丙基二醇之研究，國立台灣海洋大學機械工程研究所碩士論文, 1999.
張勝, “PAO 聚合反應及其做為潤滑油添加劑之性質研究”, 國立清華大學化學工程研究所碩士論文, 1987.
莊茂隆, “石化工業區及交通污染源區之多環芳香烴化合物的濃度特徵與粒徑分佈”, 國立成功大學環境工程系碩士論文, 1995.
彭一航, “模擬汽油與含氧化合物添加劑的熱力學性質” 靜宜大學應用化學研究所, 2001.
黃志成, “ 變動進氣條件下柴油添加劑對於引擎性能和排氣微粒特性的影響”, 國立海洋大學航運技術研究所碩士論文, 1999.
黃志偉, “柴油車排放廢氣中多環芳香烴化合物之特徵研究”, 國立成功大學環境工程學系碩士論文, 1999.
黃榮茂、王禹文、林聖富、楊得仁, 化學化工百科辭典，曉園出版社, 1992.
楊錫賢, “大氣環境中多環芳香烴化合物與金屬元素之特徵”, 國立成功大學環境工程學系博士論文, 1998.
趙雯蕙, “瀝青廠排放多環芳香烴化合物之特徵”, 國立成功大學環境工程學系碩士論文,1999
劉逸群, “機油黏度係數增進劑的合成與研究─飽和星狀聚異戊二烯之合成”, 國立中正大學化學工程研究所碩士論文, 1999.
賴順安, “鋼鐵廠煙道排放多環芳香烴化合物及金屬元素之特徵”, 國立成功大學環境工程學系碩士論文, 1998.
薛宏榮, “碳黑業勞工多環芳香烴碳黑化合物(PAHs)之暴露調查及其健康危害風險評估”, 國立成功大學環境醫學研究所碩士論文, 1999.
羅美滔, “添加異丙醇對柴油機性能與廢氣排放影響之研究”, 國立海洋大學機械與機電工程學系碩士論文, 2005.