| 研究生: |
鄧偉傑 Teng, Wei-Chieh |
|---|---|
| 論文名稱: |
上發光有機元件透明陰極層之研究 The characteristics of transparent cathode layer of top-emission organic light emitting device |
| 指導教授: |
周榮華
Chou, Jung-Hua |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 工程科學系碩士在職專班 Department of Engineering Science (on the job class) |
| 論文出版年: | 2014 |
| 畢業學年度: | 102 |
| 語文別: | 中文 |
| 論文頁數: | 61 |
| 中文關鍵詞: | 磁控濺鍍 、上發光有機元件 、氧化銦鋅 、透明陰極 |
| 外文關鍵詞: | magnetron sputtering, top-emission organic light emitting device, Indium-Zinc Oxide, transparent cathode |
| 相關次數: | 點閱:108 下載:0 |
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近年來隨著顯示器像素(Pixel)尺寸的日益縮減,電晶體所佔有的面積比例就越大,元件發光效率所受的影響也將更甚。上發光型OLED因為不受到下方TFT基板阻隔的影響,理論上能獲得更優異的發光效率,亦有助於增加有機材料的使用壽命,此時位於出光面的透明陰極所扮演的角色將更顯重要。本論文主要即是針對透明陰極進行相關的研究探討。實驗首先選擇含有10 wt.%氧化鋅的氧化銦鋅靶材,並利用直流磁控濺鍍的方式於玻璃基板上沉積IZO薄膜;藉由相關製程參數的調整以得到最佳特性的導電薄膜,其製程條件分別是在腔體壓力0.07 Pa、濺鍍功率200 W、所通入的氧氣流量比例為3.3%,當鍍膜厚度為100 nm時,其片電阻值可達38.6 Ω/□,而薄膜的可見光穿透率亦可維持約90%以上的水準。
然而IZO導電膜目前仍不適合直接製備於上發光有機元件之透明陰極上,除了電子注入效率不佳之外,更存有因濺鍍而損傷下層有機材料的疑慮,但若採用薄金屬搭配導電膜此複合結構的方式,不僅可提昇元件整體的發光效率,更可增強金屬陰極對於水氧氣的耐受度。當我們利用100 nm厚度的IZO導電膜搭配7 nm厚度的鎂銀合金,所製備出的上發光有機元件其電流-電壓特性與使用15 nm合金陰極接近。若將鎂銀合金厚度提高至10 nm 的厚度,則其元件在5 V時更可獲得超過6000 cd/m2的最高亮度。
This experiment is mainly to study the characteristics of transparent cathode layer of top emission organic light emitting device. First of all, the method to use sputter deposits IZO films deposition by sputtering film, and change the experimental parameter in order to prepare out the best IZO film. When thickness is 100 nm, sheet resistance is 38.6 Ω/□ and visible transmittance can also keep more than about 90% of the levels. While making the top emission organic light emitting device, the Mg-Ag alloy film can increase the electron and run into efficiency and prevent sputter damage. IZO film can increase luminosity completely of device and delay the moisture and oxygen invade. Use Mg-Ag alloy of 10 nm thickness to combine with IZO film of 100 nm thickness, device has the high most light one that exceeds 6000
cd/m2 when 5 V.
[1]S. T. Kim, the 6th International Meeting on Information Display and the International Display Manufacturing Conference (IMID/IDMC 2006), Keynote Address 1, Aug. 22-25, 2006, Daegu, Korea.
[2]顧鴻壽,“光電有機電激發光顯示器技術及應用”,第二版,新文京開發出版社,2006。
[3]NPD DisplaySearch, Inc.( 2011, January 3). Quarterly Advanced Global TV Shipment and Forecast Report. Retrieved August 13, 2013, from http://www.displaysearch.com/cps/rde/xchg/displaysearch/hs.xsl/110103_global_lcd_tv_market_to_grow_31_in_2010_slowing_to_13_in_2011.asp
[4]M. Pope, H. P. Kallmann, P. J. Magnante, “Electroluminescence in organic crystals” J. Chem. Phys., 38, 2042, 1963.
[5]W. Tang, and S. A. VanSlyke, “Organic electroluminescent diodes” Appl. Phys. Lett., 51, 913, 1987.
[6]J. H. Burroughes, D. D. C. Bradley, A. R. Brown, R. N. Marks, K. Mackay, R. H. Friend, P. L. Burns, and A. B. Holmes, “Light-emitting diodes based on conjugated polymers” Nature, 347, 539, 1990.
[7]D. R. Baigent, R. N. Marks, N. C. Greenham, R. H. Friend, S. C. Moratti, and A. B. Holmes, “Conjugated polymer light-emitting diodes on silicon substrates” Appl. Phys. Lett., 65, 2636, 1994.
[8]H. K. Kim, S. H. Han, T. Y. Seong, and W. K. Choi, “Low-resistance Ti/Au ohmic contacts to Al-doped ZnO layers” Appl. Phys. Lett., 77, 1647-1649, 2000.
[9]Y. R. Ryu, S. Zhu, D. C. Look, J. M. Wrobel, H. M. Jeong, and H. W. White, “Synthesis of p-type ZnO films” Journal of Crystal Growth, 216, 330-334, 2000.
[10]H. Sheng, N. W. Emanetoglu, S. Muthukumar, B. V. Yakshinskiy, S. Feng, and Y. Lu, “Ta/Au ohmic contacts to n-type ZnO” J. Electron Mater, 32, 935-938, 2003.
[11]H. K. Kim, K. K. Kim, S. J. Park, and T. Y. Seong, “Formation of low resistance nonalloyed Al/Pt ohmic contacts on n-type ZnO epitaxial layer” J. Appl. Phys., 94, 4225-4227, 2003.
[12]Y. G. Wang, S. P. Lau, X. H. Zhang, H. H. Hng, H. W. Lee, S. F. Yu, B. K. Tay, “Enhancement of near-band-edge photoluminescence from ZnO films by face-to-face annealing” Journal of Crystal Growth, 259, 335–342, 2003.
[13]古俊能,“工業材料雜誌”,第169期,106,2001。
[14]李玉華,“透明導電膜及其應用”,科儀新知,第十二卷第一期,1990。
[15]楊明輝,“金屬氧化物透明導電材料的基本原理”,工業材料雜誌,第 179期,134-144,2001。
[16]T. Minami, H. Sonohara, T. Kakumu, and S. Takata, “Highly transparent and conductive Zn2In2O5 thin films prepared by R.F. magnetron sputtering” Jpn. J. Appl. Phys., 34, 971-974, 1995.
[17]T. Minami, T. Kakumu, Y. Takeda, and S. Takata, “Preparation of transparent conducting Zn2In2O5 films by d.c. magnetron sputtering” Thin Solid Films, 317, 326-329, 1998.
[18]N. Naghavi, A. Rougier, C. Marcel, C. Guery, J. B. Leriche, and J. M. Tarascon, “Characterization of indium zinc oxide thin films prepared by pulsed laser deposition using a Zn3In2O6 target” Thin Solid Films, 360, 233-240, 2000.
[19]J. M. Phillips, R. J. Cava, G. A. Thomas, S. A. Carter, J. Kwo, T. Siegrist, J. J. Krajewski, J. H. Marshall, W. F. Peck Jr. and D. H. Rapkine, “Zinc‐indium‐oxide: a high conductivity transparent conducting oxide” Appl. Phys. Lett., 67, 2246-2248, 1995.
[20]P. J. Cannard, and R. J. D. Tilley, “New intergrowth phases in the ZnO-In2O3 system” J. Solid State Chem., 73, 418-426, 1998.
[21]M. A. Martinez, J. Herrero, and M. T. Gutierrez, “Deposition of transparent and conductive Al-doped ZnO thin films for photovoltaic solar cells” Solar Energy Materials & Solar Cell., 45, 75-86, 1997.
[22]J. L. Vossen, “Transparent conducting films” Physics of Thin Films, 9, 1-64, 1997.
[23]T. Minami, T. Kakumu, and Y. Takeda, “Preparation of transparent conducting Zn2In2O5 films by d.c. magnetron sputtering” Thin Solid Films, 317, 326-329, 1998.
[24]M. Mikawa, T. Moriga, Y. Sakakibara, Y. Misaki, K. Murai, I. Nakabayashi, K. Tominaga, “Characterization of ZnO–In2O3 transparent conducting films by pulsed laser deposition” Materials Research Bulletin, 40, 1052-1058, 2005.
[25]M. P. Taylor, D. W. Readey, C. W. Teplin, M. F. A. M. van Hest, J. L. Alleman, M. S. Dabney, L. M. Gedvilas, B. M. Keyes, B. To, J. D. Perkins, D. S. Ginley, “The electrical, optical and structure properties of InxZn1-xOy(0≦x≦1)thin films by combinatorial techniques” Meas. Sci. Technol., 16, 90-94, 2005.
[26]D. H. Park, K. Y. Son, J. H. Lee, J. J. Kim, and J. S. Lee, “Effect of ZnO addition in In2O3 ceramics:defect chemistry and sintering behavior” Solid State lonics, 172, 431-434, 2004.
[27]J. D. Perkins, M. F. A. M. van Hest, C. W. Teplin, J. L. Alleman, M. S. Dabney, L. M. Gedvilas, B. M. Keyes, B. To, and D. S. Ginley, “Amorphous transparent conducting oxides (TCOS) deposited at T ≤ 100 °C” Nat. Renewable Energy Lab., Golden, CO., 202-204, 2006.
[28]莊達人,“VLSI製造技術”,高立圖書股份有限公司,1995。
[29]王福貞、聞立時, “表面沉積技術”,機械工業出版社,114-204,1987。
[30]賴耿陽,“IC製程之濺射技術”,復漢出版社,1997。
[31]J. Venables, G. D. T. Spiller, and M. Hanbucken, “Nucleation and growth of thin films”, Rep. Prog. Phys., 47, 399, 1984.
[32]D. Ammermann, A. Böhler and W. Kowalsky, “Multilayer organic light emitting diodes for flat panel displays” Institut für Hochfrequenztechnik, TU Braunschweig, 48, 1995.
[33]A. L. Burin, and M. A. Ratner, “Exciton migration and cathode quenching in organic light emitting diodes” J. Phys. Chem. A, 4704-4710, 2000.
[34]C. W. Tang, and S. A. VanSlyke, “Organic electroluminescent diodes” Appl. Phys. Lett., 51, 913-915, 1987.
[35]C. Adachi, S. Tokito, T. Tsutsui, and S. Saito, “Electroluminescence in organic films with three-layer structure” Jpn. J. Appl. Phys., 27, 269-271, 1988.
[36]W. B. Kim, H. K. Hwang, J. G. Lee, K. Han, and Y. Kim, “Bright pure blue emission from multilayer organic electroluminescent device with purified unidentate organometallic complex” Appl. Phys. Lett., 79, 1387, 2001.
[37]M. Matsumura, T. Akai, and M. Saito, “Comparison of electroluminescence and photoluminescence efficiencies of organic electroluminescent” Jpn. J. Appl. Phys., 35, 3468-3472, 1996.
[38]D. Troadec, G. Veriot, R. Antony, and A. Moliton, “Organic light-emitting diodes based on multilayer structures” Synth. Met., 124, 49, 2001.
[39]D. K. Schroder, “Semiconductor material and device characterization” John Wiley & Sons Inc., 2-21, 1998.
[40]D. K. Schroder, “Semiconductor material and device characterization” John Wiley & Sons Inc., 713-715, 1998.
[41]D. K. Schroder, “Semiconductor material and device characterization” John Wiley & Sons Inc., 594-597, 1998.
[42]邱國峰、莫文皓,“離子磁控濺鍍之薄膜微架構與物性研究”,真空科技,第14卷,第3期,22-28, 2001。
[43]H. Ma, J. S. Cho, and C. H. Park, “A study of Indium tin oxide thin film deposited at low temperature using facing target sputtering system”, Surface and Coatings Technology, 153, 131-137, 2002.
[44]H. L. Hartnagel, A. L. Dawar, A. K. Jain, and C. Jagadish, “Semiconductor Transparent Thin Films” IOP Publishing Ltd., 10-15, 1995.
[45]K. Tominaga, T. Murayama, I. Mori, T. Okamoto, K. Hiruta, T. Moriga, and I. Nakabayashi, “Conductive transparent films deposited by simultaneous sputtering of zinc-oxide and indium-oxide targets” Vacuum, 59, 546-552, 2000.
[46]P. Nunes, E. Fortunato, and R. Martins, “Influence of the post-treatment on the properties of ZnO thin films” Thin Solid Films, 383, 277-280, 2001.
[47]M. Bender, W. Seeling, C. Daube, H. Frankenberger, B. Ocker, J. Stollenwerk, “Dependence of oxygen flow on optical and electrical properties of DC-magnetron” Thin solid film, 326, 72-77, 1998.
[48]Y. S. Jung, and S. S. Lee, “Development of indium tin oxide film texture during DC magnetron sputtering deposition” Journal of Crystal Growth, 259, 343-351, 2003.
[49]H. C. Lee, and O. O. Park, “Behaviors of carrier concentrations and mobilities in indium–tin oxide thin films by DC magnetron sputtering at various oxygen flow rates” Vacuum 77, 67-77, 2004.
[50]I. H. Kazi, P. M. Wild, T. N. Moore, and M. Sayer, “Voltage-independent pure red devices based on a carbazole-functionalized europium complex” Thin Solid Films, 433, 337-343, 2003.
[51]L. I. Belic, K. Pozun, and M. Remskar, “AES, AFM and TEM studies of NiCr thin film for capacitive humidity sensors” Thin Solid Films, 317, 173-177, 1998.
[52]H. K. Kim, K. S. Lee, and H. A. Kang, “Characteristics of indium zinc oxide top cathode layers grown by box cathode sputtering for top-emitting organic light-emitting diodes” J. Electrochemical Soc., 153(2), 29-33, 2006.
[53]H. Xin, M. Sun, K. Z. Wang, Y. A. Zhang, L. P. Jin, and C. H. Huang, “Voltage-independent pure red devices based on a carbazole-functionalized europium complex” Chem. Appl. Phys. Lett. 388, 55, 2004.
[54]陳志強,“OLED有機發光二極體顯示器技術”,全華科技,2007。
[55]T. Dobbertin, O. Werner, J. Meyer, A. Kammoun, D. Schneider, T. Riedl, E. Becker, H. H. Johannes, and W. Kowalsky, “Inverted hybrid organic light-emitting device with polyethylene dioxythiophene-polystyrene sulfonate as an anode buffer layer” Appl. Phys. Lett., 83, 5071, 2003.
[56]G. Gu, V. Bulovic, P. E. Burrows, S. R. Forrest, and M. E. Thompson, “Transparent organic light emitting devices” Appl. Phys. Lett., 68, 2606, 1996.
校內:2019-02-13公開