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研究生: 王捷
Wang, Jei
論文名稱: 少層AA和ABC堆疊石墨在電場下的電子和光學性質
Electronic & Optical Properties of few-layer AA- and ABC-stacked graphites in an electric field
指導教授: 林明發
Lin, Min-Fa
學位類別: 碩士
Master
系所名稱: 理學院 - 物理學系
Department of Physics
論文出版年: 2006
畢業學年度: 94
語文別: 中文
論文頁數: 24
中文關鍵詞: 石墨能帶電子性質吸收
外文關鍵詞: graphite, energy band, electronic properties, absorption
相關次數: 點閱:66下載:4
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  • 在這篇論文之中,我們以緊束模型討論了在外加垂直於石墨層的電場下,少層AA及ABC兩種不同堆疊石墨系統的電子和光學性質。這些不同堆疊石墨系統的電子和光學性質將隨著堆疊序列、石墨的層數、鉛直方向(垂直石墨面)的靜電場強度而有著特性上的變化。不論有無電場的作用,在低能附近的AA堆疊石墨吸收光譜都是呈現出肩狀的跳躍結構。在無電場存在時,N層ABC堆疊石墨的吸收光譜有著不一樣的特徵,其呈現出尖峰和跳躍結構。所施加的電場對能帶結構產生影響,像是變化了態能量,改變了副能帶間的空間,產生震盪能帶而且增加了能帶邊緣態。因此,電場調制了吸收光譜,包括產生了新的峰結構,改變了峰的位置和峰的高度。更進一步地,我們可以預期峰結構的頻率很顯著地決定於層數和電場強度。最重要的是,這些預測出的吸收光譜和相關的電子性質可以由光學量測來証實。

    Optical properties of the AA- and ABC-stacked few-layer graphites

    under application of the electric field (F), perpendicular to the layers, is

    explored through the gradient approximation. They are closely related to

    the geometric structure (layer number, interlayer interactions and stacking

    sequences) and the field strength. In the absence or presence of an electric

    field, the low-energy absorption spectra of the AA-stacked few-layer

    graphites exhibit the jumping structures. In the absence of an electric field

    , the ABC-stacked few-layer graphites show the spectra with the different

    feature, including the jumping structures and sharp peaks. The application

    of an electric field, F, influences the energy dispersions, e.g., the change

    of band feature and subband spacing, the production of oscillating bands ,

    and the increases of the band-edge states. As a result, F modifies the

    absorption spectra, including the generation of new peaks, the change of

    peak position and peak height. Moreover, the frequency of peak is

    predicted to be strongly dependent on the layer number and the field

    strength. Above all, the predicted absorption spectra and the associated

    electronic properties could be verified by the optical measurements.

    第一章 導論..............................................1 第二章 理論和方法........................................4 Fig. 1. 幾何結構..................................9 第三章 電子和光學性質...................................10 Fig. 2. AA堆疊的能帶結構.........................16 Fig. 3. ABC堆疊的能帶結構........................17 Fig. 4. 態密度(DOS)..............................18 Fig. 5. 聯合態密度(JDOS).........................19 Fig. 6. 光吸收譜(A(ω))..........................20 第四章 結論.............................................21 參考文獻.................................................22

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