| 研究生: |
蔡誌昌 Tsai, Chih-Chang |
|---|---|
| 論文名稱: |
疏水改質羥乙基纖維素與非離子型界面活性劑交互作用力於水溶液之研究探討 Interaction between hydrophobically modified hydroxyethyl celluloses and nonionic surfactants in Aqueous Solution |
| 指導教授: |
陳炳宏
CHEN, Bing-Hung |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 化學工程學系 Department of Chemical Engineering |
| 論文出版年: | 2007 |
| 畢業學年度: | 95 |
| 語文別: | 中文 |
| 論文頁數: | 71 |
| 中文關鍵詞: | 疏水性改質 、非離子型界面活性劑 、過氧苯醯 、交互作用 、疏水改質羥乙基纖維素 |
| 外文關鍵詞: | hydrophobically modified hydroxyethyl cellulose, nonionic surfactants, benzoyl chloride, interaction |
| 相關次數: | 點閱:139 下載:0 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
疏水修飾的高分子與界面活性劑的系統在工業上有許多應用。因此,兩者之間的交互作用越來越受到重視。本實驗探討的系統是非離子型高分子 (疏水改質羥乙基纖維素) 與非離子型界面活性劑(Tergitol 15-S-7、LE207、Neodol 25-7 and Pannox 69C)間的交互作用。實驗分成兩部分,第一部分為羥乙基纖維素與過氧苯醯經由酯化反應做疏水性改質的高分子。第二部分為探討疏水改質羥乙基纖維素在加入非離子型界面活性劑之後,對黏度、活化能及螢光圖譜的影響,來了解兩者交互作用的行為。
Hydrophobically modified polymer and surfactants system have been applied in industry many years. So, interaction between hydrophobically modified polymer and surfactants has attracted growing attention. In this experiment, we study the interaction between nonionic polymer (hydrophobically modified hydroxyethyl cellulose) and nonionic surfactants (Tergitol 15-S-7、LE207、Neodol 25-7 and Pannox 69C). The first step in experiment is preparation of hydrophobically modified hydroxyethyl cellulose with benzoyl chloride. The second step in experiment is to discuss interaction between hydrophobically modified hydroxyethyl cellulose and nonionic surfactants and to compare results with literatures. Observing interaction with viscosity (η)、dissociation energy (Em) and fluorescence.
Antunes FE, Thuresson K., Lindman B., Miguel MG, “A Rheological Investigation of the Association between a Nonionic Microemulsion and Hydrophobically Modified PEG. Influence of Polymer Architecture”, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 215, 87-100 (2003)
Bai D, Khin CC, Chen SB, Tsai CC, Chen BH, “Interaction between A Nonionic Surfactant and A Hydrophobically Modified 2-Hydroxyethyl Cellulose”, Journal of Physical Chemistry B, 109, 909-4916 (2005)
Bras NC, Collet A., Viguier M., “Synthesis and Linear Viscoelasticity of Fluorinated Hydrophobically Modified Ethoxylated Urethanes (F-HEUR)”, Macromolecules, 31, 1305-1311 (1998)
Brown DG, Nuaimi KSA, “Nonionic Surfactant Sorption onto the Bacterial Cell Surface: A Multi-interaction Isotherm”, Langmuir, 21, 11368-11372 (2005)
Chronakis IS, Alexandridis P., “Rheological Properties of Oppositely Charged Polyelectrolyte-Surfactant Mixtures: Effect of Polymer Molecular Weight and Surfactant Architecture”, Macromolecules, 34, 5005-5018 (2001)
Deo P., Somasundaran P., “Interactions of Hydrophobically Modified Polyelectrolytes with Nonionic Surfactants”, Langmuir, 21, 3950-3956 (2005)
Deo P., Jockusch S., Ottaviani MF, A. Moscatelli, Turro NJ, Somasundaran P., “Interactions of Hydrophobically Modified Polyelectrolytes with Surfactants of the Same Charge”, Langmuir, 19, 10747- 10752 (2003)
Egermayer M., Norrman J., Piculell L., “Gels of Hydrophobically Modified Hydroxyethyl Cellulose Cross-Linked by Amylose: Competition by Added Surfactants”, Langmuir, 19, 10036-10043 (2003)
Gräbner D., Liebert T., Heinze T., “Synthesis of Novel Adamantoyl Cellulose Using Differently Activated Carboxylic Acid Derivatives”, Cellulose, 9, 193-201 (2002)
Heinze T., Liebert TF, Pfeiffer KS, Hussain MA, “Unconventional Cellulose Esters: Synthesis, characterization and Structure-property relations”, Cellulose, 10, 283-296 (2003)
Hoff E., Nyström B., Lindman B., “Polymer-Surfactant Interactions in Dilute Mixtures of a Nonionic Cellulose Derivative and an Anionic Surfactant”, Langmuir, 17, 28-34 (2001)
Kondo Y., Yoshino N., “Hybrid Fluorocarbon/Hydrocarbon Surfactants”, Current Opinion in Colloid & Interface Science, 10, 88-93 (2005)
Kopperud HM, Hansen F. K., Nyström B., “Effect of Surfactant and Temperature on the Rheological Properties of Aqueous Solutions of Unmodified and Hydrophobically Modified Polyacrylamide”, Macromolecular Chemistry and Physics, 199, 2385–2394 (1998)
Larson R.G., “The structure and Rheology of Complex Fluids”, Oxford university, New york, pp. 12-18 (1999)
Lin CE, “Determination of Critical Micelle Concentration of Surfactantsby Capillary Electrophoresis”, Journal of Chromatography A, 1037, 467-478 (2004)
Lin IJ, “The Hydrophile-Lipophile Balance (HLB) of Fluorocarbon Surfactantsand Its Relation to the Critical Micelle Concentration (cmc)”, The Journal of Physical Chemistry, 76, 2019-2023 (1972)
Materna K., Milosz I., Miesiac I., Cote G., Szymanowski J., “Removal of Phenols from Aqueous Streams by the Cloud Point Extraction Technique with Oxyethylated Methyl Dodecanoates As Surfactants”, Environmental Science and Technology, 35, 2341-2346 (2001)
McCormick CL, Callais PA, “ Derivatization of Cellulose in Lithium Chloride and N-N-Dimethylacetamide Solutions”, Polymer, 28, 2317-2323 (1987)
McCormick CL, Callais PA, Hutchinson BH, “Solution Studies of Cellulose in Lithium Chloride and N,N- Dimethylacetamide”, Macromolecules, 18, 2394-2401 (1985)
Nahringbauer I., “Polymer-Surfactant Interaction As Revealed by the Time Dependence of Surface Tension. The EHEC/SDS/Water System”, Langmuir, 13, 2242-2249 (1997)
Nishikawa K., Yekta A., Pham HH, Winnik MA, “Fluorescence Studies of Hydrophobically Modified Hydroxyethylcellulose (HMHEC) and Pyrene-Labeled HMHEC”, Langmuir, 14, 7119-7129 (1998)
Ogino K., Abe M., “Mixed Surfactant Systems”, Marcel Dekker, New York (1993)
Panmai S., Prud’homme RK, Peiffer DG, Jockusch S., Turro NJ, “Interactions between Hydrophobically Modified Polymers and Surfactants: A Fluorescence Study”, Langmuir, 18, 3860-3864 (2002)
Piculell L., Egermayer M., Sjöström J., “Rheology of Mixed Solutions of an Associating Polymer with a Surfactant. Why Are Different Surfactants Different?”, Langmuir , 19, 3643-3649 (2003)
Piculell L., Thuresson K., Lindman B., “Mixed Solutions of Surfactant and Hydrophobically Modified Polymer”, Polymers forAadvanced Technologies, 12, 44-69 (2001)
Regiani AM, Frollini E., Marson GA, Arantes GM, O. A. E. Seoud, “Some Aspects of Acylation of Cellulose Under Homogeneous solution Conditions”, Journal of Polymer Science Part A: Polymer Chemistry, 37, 1357-1363 (1999)
Rosen MJ, “Surfactants and Interfacial Phenomena”, Wiley-VCH, New York, pp. 326-329 (1989)
Sastry NV, Hoffmann H., “Interaction of Amphiphilic Block Copolymer Micelles with Surfactants”, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 250, 247–261 (2004)
Stokes RJ, Evans DF, “Fundermentals of Interfacial Engineering”, Wiley-VCH, New York (1997)
Tanaka R., Meadows J., Williams PA, Phillips GO, “Interaction of Hydrophobically Modified (Hydroxyethy1)cellulose with Various Added Surfactants”, Macromolecules, 25, 1304-1310 (1992)
Thuresson K., Lindman B., Nyströ1m B., “Effect of Hydrophobic Modification of a Nonionic Cellulose Derivative on the Interaction with Surfactants. Rheology”, Journal of Physical Chemistry B, 101, 6450-6459 (1997)
Tirtaatmadja V., Tam KC, Jenkins RD, “Effects of Temperature on the Flow Dynamics of a Model HASE Associative Polymer in Nonionic Surfactant Solutions”, Langmuir, 15, 7537-7545 (1999)
Vasilescu M., Anghel DF, “Fluorescence Probe Study of the Interactions between Nonionic Poly(oxyethylenic) Surfactants and Poly(acrylic acid) in Aqueous Solutions”, Langmuir, 13, 6951-6955 (1997)
Winnik FM, Regismond STA., “Fluorescence Methods in the Study of the Interactions of Surfactants with Polymers”, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 118, 1-39 (1996)
校內:2106-08-29公開