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研究生: 蔡誌昌
Tsai, Chih-Chang
論文名稱: 疏水改質羥乙基纖維素與非離子型界面活性劑交互作用力於水溶液之研究探討
Interaction between hydrophobically modified hydroxyethyl celluloses and nonionic surfactants in Aqueous Solution
指導教授: 陳炳宏
CHEN, Bing-Hung
學位類別: 碩士
Master
系所名稱: 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年: 2007
畢業學年度: 95
語文別: 中文
論文頁數: 71
中文關鍵詞: 疏水性改質非離子型界面活性劑過氧苯醯交互作用疏水改質羥乙基纖維素
外文關鍵詞: hydrophobically modified hydroxyethyl cellulose, nonionic surfactants, benzoyl chloride, interaction
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  • 疏水修飾的高分子與界面活性劑的系統在工業上有許多應用。因此,兩者之間的交互作用越來越受到重視。本實驗探討的系統是非離子型高分子 (疏水改質羥乙基纖維素) 與非離子型界面活性劑(Tergitol 15-S-7、LE207、Neodol 25-7 and Pannox 69C)間的交互作用。實驗分成兩部分,第一部分為羥乙基纖維素與過氧苯醯經由酯化反應做疏水性改質的高分子。第二部分為探討疏水改質羥乙基纖維素在加入非離子型界面活性劑之後,對黏度、活化能及螢光圖譜的影響,來了解兩者交互作用的行為。

    Hydrophobically modified polymer and surfactants system have been applied in industry many years. So, interaction between hydrophobically modified polymer and surfactants has attracted growing attention. In this experiment, we study the interaction between nonionic polymer (hydrophobically modified hydroxyethyl cellulose) and nonionic surfactants (Tergitol 15-S-7、LE207、Neodol 25-7 and Pannox 69C). The first step in experiment is preparation of hydrophobically modified hydroxyethyl cellulose with benzoyl chloride. The second step in experiment is to discuss interaction between hydrophobically modified hydroxyethyl cellulose and nonionic surfactants and to compare results with literatures. Observing interaction with viscosity (η)、dissociation energy (Em) and fluorescence.

    摘要 I ABSTRACT II 誌謝 III 目錄 IV 表目錄 VI 圖目錄 VI 第一章 緒論 1 第二章 文獻回顧 2 2-1 界面活性劑簡介 2 2-2 微胞 (micelle) 4 2-3 高分子與疏水改質高分子 5 2-4-1 螢光光譜分析 6 2-4-2 表面張力 10 2-4-3 流變學上的探討 12 第三章 實驗 28 3-1實驗藥品 28 3-1-1 實驗藥品簡介 28 3-2實驗儀器及裝置 29 3-3儀器基本原理 29 3-3-1核磁共振儀 29 3-3-2毛細管黏度計 33 3-4實驗方法與步驟 34 3-4-1羥乙基纖維素的疏水性改質 34 3-4-2 羥乙基纖維素的疏水性改質理論基礎 35 3-4-2-1羥乙基纖維素的溶解 35 3-4-2-2疏水支鏈的接枝 36 3-4-2-3產物的純化 36 3-4-3疏水改質羥乙基纖維素的鑑定 38 3-4-3-1 NMR圖譜的分析 38 3-4-4疏水改質羥乙基纖維素與界面活性劑交互作用的分析 38 3-4-4-1黏度的測量 38 3-4-5 螢光圖譜的測定 39 第四章 結果與討論 40 4-1羥乙基纖維素的疏水性改質 40 4-1-1鑑定羥乙基纖維素是否有疏水性改質 40 4-1-2疏水性改質羥乙基纖維素的水溶性 41 4-1-3 接枝率 (DS)的計算 42 4-2 GPC的檢測 44 4-3疏水改質羥乙基纖維素與界面活性劑的交互作用 44 4-3-1黏度的變化 45 4-3-2 網絡結構解離活化能的計算 46 4-3-3螢光圖譜 47 第五章 結論 67 5-1未來工作的改進 67 參考文獻 68

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