簡易檢索 / 詳目顯示

研究生: 石嘉嘉
Shi, Jia-JIa
論文名稱: 創新超疏水性微結構的物性研究
Physical investigation on an innovative microstructure with superhydrophobic surface
指導教授: 李森墉
Lee, Sen-Yung
學位類別: 碩士
Master
系所名稱: 工學院 - 機械工程學系
Department of Mechanical Engineering
論文出版年: 2012
畢業學年度: 100
語文別: 中文
論文頁數: 78
中文關鍵詞: 蓮花效應接觸角PDMS超疏水性自潔
外文關鍵詞: Lotus effect, Contact angle, PDMS, Superhydrophobicity, Self-cleaning
相關次數: 點閱:85下載:1
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 自然界中的蓮花葉面具有超疏水之特性,其接觸角約150˚、滑動角約5˚。其表面具能防水、自潔和流體滑動於界面之能力,可應用於玻璃清潔、太陽能電池、古蹟之保存、高樓、浴室及交通工具之清潔,而其滑動之邊界效應具應用於生物醫學方面之潛能。基於仿生學建立超疏水表面之結構,在近幾年引發極廣泛的基礎應用研究。然而該結構之結構強度低、大量複製困難,並易受外力受損失去自潔性的缺點。
    本研究在於設計一不具奈米纖維之創新微結構,其與自然者大不相同。提出一種多層次之凹洞狀微結構,半封閉性反蓮花結構之PDMS,其接觸角大於165˚、滑動角小於10˚水滴可於微結構表面反彈。具彈性和超疏水之PDMS可清潔灰塵避免灰塵致太陽能電池效率的降低,提出此超疏水表面用於太陽能電池上的可行性。

    In nature, leaves of Lotus are superhydrophobic surfaces. The contact angle is about 150° and slilding angle is below 5˚. The surfaces have the abilities of water-repellent, self-cleaning and slipping at the fluid-surface interface. Dominant applications can be found in the self-cleaning of glasses (window panes and windshields) and surfaces of solar cell, the protection of ancient remains, tall buildings, cars, bathrooms and structures in mountains. In addition, its slip boundary condition effect can potentially be applied in biomedicine. Based on the biomimicry, the study on creating super hydrophobic structures has triggered intense basic and applied research over the past several years. However, this kind of structures have some disadvantages, such as low structure strength and hard to replicate. It is easy to loss the ability of self-cleaning by the damage result from the external force.
    In this study, we have to investigate an innovative novel superhydrophobic micro-structure without nano-fibers, a multi-leveled concaved structure of PDMS. This PDMS micro-structure showed an excellent water-repellent property with a contact angle higher than 165˚ and a sliding angle lower than 10˚. Droplets will rebound on the micro-structure of the surface. Such flexible and superhydrophobic surface showed a dust cleaning effect to prevent the degradation by dust particles of solar cell and provides possibility of a practical application in solar cells.

    目錄 摘  要 I Abstract II 誌 謝 III 目錄 IV 表目錄 VII 符  號 XII 第一章 緒論 1 1.1 前言 1 第二章 基本理論 6 2.1 接觸角(Contact Angle) 6 2.1.1 楊氏接觸角或本質接觸角(Intrinsic contact angle) 6 2.1.2 Wenzel模型 9 2.1.3 The Cassie-Baxter模型 10 2.1.4 過渡狀態(Transition State) 10 2.2 動態接觸角 12 2.2.1 前進角與後退角(Advancing and receding contact angle) 12 2.2.2 滑動角 14 2.2.3 接觸角遲滯值(Contact angle hysteresis) 15 2.3 動態效應 15 2.3.1 水滴撞擊微結構 15 2.4灰塵之性質 18 2.4.1 灰塵的意義: 18 2.5 太陽能電池的工作原理[22] 21 2.5.1 太陽光的頻譜照度 21 2.5.2 太陽能電池的電路模型 22 第三章 實驗材料與方法 26 3.1 實驗材料—聚二甲基矽氧烷 26 3.2 實驗儀器 27 3.2.1 接觸角量測儀 27 3.2.2 影像高速攝影機 28 3.2.3 太陽光模擬量測系統(Solar Simulator) 29 3.3 實驗方法 31 3.3.1 實驗樣本製作 31 3.3.2 靜態接觸角量測實驗 36 3.3.3 前進角、後退角與滑動角量測實驗: 36 3.3.4 水滴撞擊材料表面之動態量測實驗: 37 3.3.5 太陽光模擬量測系統 40 3.3.6 自潔效率實驗 42 第四章 實驗結果與探討 44 4.1 實驗結果 44 4.1.1 實驗試片介紹 44 4.1.2 接觸角、滑動角量測 47 4.1.3 水滴撞擊材料表面之動態量測 52 4.2 自潔效率實驗 60 4.2.1 太陽光模擬量測系統 60 4.2.2 自潔實驗 69 4.3 實驗結果探討 71 第五章 總結 75 參考文獻 77

    [1] Bhushan, B., and Jung, Y. C., and Koch, K., 2009. Self-Cleaning efficiency of artificial superhydrophobic surfaces. Langmuir. 25(5), 3240–3248.
    [2] Bhushan, B., and Jung, Y. C., 2010. Natural and biomimetic artificial surfaces for superhydrophobicity, self-cleaning, low adhesion, and dragreduction. Prog. Mater. Sci.
    [3] Cassie, A. B. D., and Baxter, S., 1944. Wettability of porous surfaces. Trans. Faraday Soci. 40, 546-551 .
    [4] Choi, S.J., and Huh S.Y., 2010. Direct structuring of a biomimetic anti-reflective, self-cleaning surface for lightharvesting in organic solar cells. Macromol. Rapid Commun. 31:539–44.
    [5] Elminir, H. K., Ghitas, A. E., Hamid, R. H., El-Hussainy, F., Beheary, M. M.,and Abdel-Moneim, K. M., 2006. Effect of dust on the transparent cover of solar collectors. Energy Convers. Manage. 47, 319.
    [6] Furmidge, C. G. 1962. Studies at phase interfaces: Sliding of liquid drops on solid surfaces and a theory for spray retention. J. Colloid Sci. 17(4), 309 .
    [7] Fürstner, R., Barthlott, W., Neinhuis, C., and Walzel, P., 2005. Wetting and self-cleaning properties of aritificial superhydrophobic surfaces. Langmuir. 21, 956.
    [8] Gao, L., and McCarthy, T. J., 2006. Contact angle hysteresis explained. Langmuir. 22, 6234–6237.
    [9] Jung, Y. C., and Bhushan, B., 2006. Dynamic effects of bouncing water droplets on superhydrophobic surfaces. Nanotechnology. 17, 4970–4980 .
    [10] Kwon, Y.-J., Patankar, N. A., Choi ,J.-K., and Lee,J.-H., 2009. Design of surface hierarchy for extreme hydrophobicity.Langmuir. 25, 6129.
    [11] Neinhuis, C., and Barthlott, W. 1997. Characterization and distribution of water-repellent, self-cleaning plant surfaces. Annals. Botany. 79, 667–677 .
    [12] Park, Y. B., and Choi, Y. K., 2011. Self-cleaning effect of highly water-repellent microshell structures for solar cell applications. J. Mater. Chem. 21:633–36.
    [13] Quéré, D.2006. Bouncing transitions on microtextured materials. Europhys. Lett. 74, 306.
    [14] Richard, D., and Quéré, D. 2000. Bouncing water drops. Europhys. Lett. 50, 769 .
    [15] Tsai, P., Pacheco, S., Pirat, C., Lefferts, L. and Lohse, D. 2009. Drop impact upon micro- and nanostructured superhydrophobic surfaces. Langmuir. 25(20), 12293-12298.
    [16] Wenzel, R. N. 1936. Resistance of solid surface to wetting by water. Ind. Eng.Chem. 28, 988.
    [17] Young, T. 1805. An essay on the cohesion of fluids. Phil. Trans. R. Soc. Lond. 95, 65–87 .
    [18] Zhu J, Hsu CM, Yu ZF, Fan SH, Cui Y. 2010. Nanodome solar cells with efficient light management and self-cleaning. Nano Lett. 10:1979–84 2005.
    [19] 張維仁,1993,影響灰塵污染建築外壁材料諸因子之研究,國中央大學碩士論文。
    [20] 陳彥君,2011,國立成功大學機械工程學系碩士論文。
    [21] 廖士貴, 2010,國立成功大學機械工程學系碩士論文。
    [22] 蔡進譯,2005,超高效率太陽電池-從愛因斯坦的光電效應談起,物理雙月刊,二十七卷,五期,頁702-719。

    下載圖示 校內:2014-09-03公開
    校外:2014-09-03公開
    QR CODE