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| 研究生： |
林宏穎 Lin, Hung-Ying |
|---|---|
| 論文名稱： |
氮化鋁量產製程技術開發 Process Development for Scale-Up Production of Aluminum Nitride |
| 指導教授： |
鍾賢龍
Chung, Shyan-Lung |
| 學位類別： |
碩士 Master |
| 系所名稱： |
工學院 - 化學工程學系 Department of Chemical Engineering |
| 論文出版年： | 2010 |
| 畢業學年度： | 98 |
| 語文別： | 中文 |
| 論文頁數： | 139 |
| 中文關鍵詞： | 氮化鋁 、燃燒合成法 |
| 外文關鍵詞： | Aluminum Nitride, Combustion synthesis |
| 相關次數： | 點閱：58 下載：0 |
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在現今市場上對氮化鋁的需求已經越來越大，主要實驗目標為氮化鋁量產化製程開發，相較於之前本實驗室以燃燒合成法製程，每批次產量約為三百五十克，反應時間約為一個小時，但經過量產研究過後每批次產量已經可達到一千兩百克，而反應時間約為一個半小時，最佳操作條件整體轉化率可達到99.5%以上，而整體氧含量也可有效的降至1wt%以下，相較於前製程可說是以達到相同的水平。
由於在市場上所需求氮化鋁粒徑較小，因此本實驗室所生產的氮化鋁必須經過研磨才能符合需求，但是氮化鋁在小粒徑時非常容易水解，因此必須在研磨當中加入改質劑同時進行表面改質使得研磨出的粉體具有良好的抗濕效果。依照不同研磨條件得到不同粒徑(D50 3~4μm、D50 1~2μm)及添加不同表面改質劑(APS、PA)，分別做恆溫恆濕測試、增重測試、pH值測試，並依實驗結果選擇出各種粒徑搭配不同改質劑之最佳操作條件。
In the current market the demand for aluminum nitride has been growing,so the main propose of this thesis is developing scale-up process.Compare with the original process,every batch 350g,reaction time about one hour.After the research,every batch was magnified to 1200g,reaction time about one and half hour.At the best operating condition,the total conversion is above 99.5% and the total oxygen content is effectively down below 1wt%.Compared to the original process can be said to achieve the same level. The demand of particle size is smaller in the market.So the product synthesized by our lab must be mill to smaller particle in order to meet the needs of market.However aluminum nitride powder in smaller size has the property of easier reaction with water. So we have to do some surface treatment while ball-milling time in order to prevent hydrolysis.Depend on different size of aluminum nitride powder and different surface treatment(APS or Phosphoric Acid),we have to add different amount of APS and Phosphoric Acid.After the anti-hydrolysis test,we choose the best performance as the best operating condition.
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