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研究生: 賴韋翰
Lai, Wei-Han
論文名稱: 主族金屬硫族化合物之結構分析與物理性質探討
Structural Analyses and Physical Properties of Main-Group Metal Chalcogenides
指導教授: 許桂芳
Hsu, Kuei-Fang
學位類別: 碩士
Master
系所名稱: 理學院 - 化學系
Department of Chemistry
論文出版年: 2011
畢業學年度: 99
語文別: 中文
論文頁數: 99
中文關鍵詞: 助熔長晶法非中心對稱二倍頻
外文關鍵詞: flux-growth techniques, non-centrosymmetric, second-harmonic-generation
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  • 本論文利用助熔長晶法,合成出五個金屬硫族化合物。五個化合物有相同的3D結構,其晶系屬於非中心對稱的空間群,由化合物的能隙、紫外-可見光區的穿透度、及二倍頻訊號皆顯示出在紅光區具有應用性。

    Five new compounds have been synthesized through solid state reactions using the flux-growth techniques to promote crystal growth. The five compounds adopt the same three-dimensional structure crystallizing in the non-centrosymmetric space group. The characterizations of band gap, transmission in the uv-vis range, and second-harmonic-generation signals support that these compounds have the potential application as the non-linear optical crystals applied in the infrared ranges.

    致謝 III 摘要 IV Abstract V 目錄 VI 圖目錄 VIII 表目錄 XI 第一章 緒論 1 第二章 金屬硫族化合物Ba-Ag-Sn-Q (Q=S,Se)系統之合成與鑑定 7 2.1 合成方法 7 2.2 單晶X光繞射分析 (Single Crystal X-ray Diffraction Analysis) 11 2.3 粉末X光繞射分析 (Powder X-ray Diffraction Analysis) 14 2.4 高解析穿透式電子顯微鏡(High-ResolutionTransmission Electron Microscopy) 16 2.5 能量散佈光譜分析(Energy Dispersive Spectroscopy, EDS) 18 2.6 紫外-可見-近紅外光光譜儀 (UV-Vis and near IR reflection spectrometer) 18 2.7 紅外光光譜分析(IR Reflection Spectroscopy) 20 2.8 顯微拉曼散射光譜分析(Microscopes Raman Scattering Spectroscopy) 21 2.9 結晶粉末的非線性光學 23 第三章 結果與討論 27 3.1 結構討論 27 3.1.1 結構描述 27 第三章 38 3.1.2 結構對稱性的探討 38 3.2 物理性質 44 3.2.1 純相鑑定 44 3.2.2 固溶體(Solid Solution)現象與能隙改變的探討 46 3.2.3 透光範圍檢測 55 3.2.4 拉曼光譜分析 57 3.2.5 二次諧波產生(Second Harmonic Generation) 63 第四章 結論 70 參考文獻 72 附錄 74

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