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研究生: 林清源
Lin, Ching-Yuan
論文名稱: 疏水改質羥乙基纖維素與非離子型界面活性劑於吡啶與水混合溶劑中交互作用之研究
Interaction between hydrophobically modified hydroxyethyl cellulose and nonionic surfactant in pyridine and water mixed solvent
指導教授: 陳炳宏
Chen, Bing-Hung
學位類別: 碩士
Master
系所名稱: 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年: 2006
畢業學年度: 94
語文別: 中文
論文頁數: 77
中文關鍵詞: 疏水改質羥乙基纖維素Tergitol 15-S-5疏水性改質月桂醯氯交互作用
外文關鍵詞: interaction, lauroyl chloride, hydrophobically modified hydroxyethyl cellulose, Tergitol 15-S-5, preparation
相關次數: 點閱:123下載:2
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  • 疏水修飾的高分子與界面活性劑的系統在工業上有許多應用。因此,兩者之間的交互作用越來越受到重視。本實驗探討的系統是非離子型高分子 (疏水改質羥乙基纖維素) 與非離子型界面活性劑 (Tergitol 15-S-5) 間的交互作用。實驗分成兩部分,第一部分為羥乙基纖維素與月桂醯氯經由酯化反應後作疏水性改質。第二部分為探討疏水改質羥乙基纖維素在加入Tergitol 15-S-5之後,對黏度、活化能、粒徑的影響,來了解兩者交互作用的行為,並且將實驗結果與文獻所提的交互作用機制相比較,驗證文獻中所提的交互作用機制是否可以通用於本系統。

    Hydrophobically modified polymer and surfactant system have been applied in industry many years. So, interaction between hydrophobically modified polymer and surfactant has attracted growing attention. In this experiment, we study the interaction between nonionic polymer (hydrophobically modified hydroxyethyl cellulose) and nonionic surfactant (Tergitol 15-S-5). The first step in my experiment is preparation of hydrophobically modified hydroxyethyl cellulose with lauroyl chloride. The second step in my experiment is to discuss interaction between hydrophobically modified hydroxyethyl cellulose and Tergitol 15-S-5 and to compare my results with literatures. We observe interaction with viscosity (η)、dissociation energy (Em)、hydrodynamic radius (RH).

    摘要 I Abstract II 誌謝 IV 目錄 IV 圖目錄 VI 符號 VIII 第一章 緒論 1 第二章 文獻回顧 2 2-1.界面活性劑簡介 2 2-2.微胞 (micelle) 3 2-3.高分子與疏水改質高分子4 2-4.界面活性劑與改質高分子間的交互作用5 2-4.1螢光光譜分析 5 2-4.2表面張力 9 2-4.3流變學上的探討 10 2-4.4其它研究方法 22 第三章 實驗 23 3-1實驗藥品 23 3-2實驗儀器及裝置 23 3-3儀器基本原理 23 3-3-1核磁共振儀 23 3-3-2粒徑分析儀 24 3-3-3毛細管黏度計 24 3-4實驗方法與步驟 25 3-4-1羥乙基纖維素的疏水性改質 25 3-4-2羥乙基纖維素的疏水性改質理論基礎 26 3-4-3疏水改質羥乙基纖維素的鑑定 30 3-4-4疏水改質羥乙基纖維素與界面活性劑交互作用的分析 32 第四章 結果與討論 35 4-1羥乙基纖維素的疏水性改質 35 4-1-1鑑定羥乙基纖維素是否經過疏水性改質 35 4-1-2接枝率 (DS) 的控制 36 4-2疏水改質羥乙基纖維素分子量的量測結果 37 4-3疏水改質羥乙基纖維素與界面活性劑的交互作用 38 4-3-1黏度的變化 39 4-3-2活化能的計算 41 4-3-3粒徑的改變 42 第五章 結論 66 參考文獻 67 附錄 71

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