| 研究生: |
林清源 Lin, Ching-Yuan |
|---|---|
| 論文名稱: |
疏水改質羥乙基纖維素與非離子型界面活性劑於吡啶與水混合溶劑中交互作用之研究 Interaction between hydrophobically modified hydroxyethyl cellulose and nonionic surfactant in pyridine and water mixed solvent |
| 指導教授: |
陳炳宏
Chen, Bing-Hung |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 化學工程學系 Department of Chemical Engineering |
| 論文出版年: | 2006 |
| 畢業學年度: | 94 |
| 語文別: | 中文 |
| 論文頁數: | 77 |
| 中文關鍵詞: | 疏水改質羥乙基纖維素 、Tergitol 15-S-5 、疏水性改質 、月桂醯氯 、交互作用 |
| 外文關鍵詞: | interaction, lauroyl chloride, hydrophobically modified hydroxyethyl cellulose, Tergitol 15-S-5, preparation |
| 相關次數: | 點閱:123 下載:2 |
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疏水修飾的高分子與界面活性劑的系統在工業上有許多應用。因此,兩者之間的交互作用越來越受到重視。本實驗探討的系統是非離子型高分子 (疏水改質羥乙基纖維素) 與非離子型界面活性劑 (Tergitol 15-S-5) 間的交互作用。實驗分成兩部分,第一部分為羥乙基纖維素與月桂醯氯經由酯化反應後作疏水性改質。第二部分為探討疏水改質羥乙基纖維素在加入Tergitol 15-S-5之後,對黏度、活化能、粒徑的影響,來了解兩者交互作用的行為,並且將實驗結果與文獻所提的交互作用機制相比較,驗證文獻中所提的交互作用機制是否可以通用於本系統。
Hydrophobically modified polymer and surfactant system have been applied in industry many years. So, interaction between hydrophobically modified polymer and surfactant has attracted growing attention. In this experiment, we study the interaction between nonionic polymer (hydrophobically modified hydroxyethyl cellulose) and nonionic surfactant (Tergitol 15-S-5). The first step in my experiment is preparation of hydrophobically modified hydroxyethyl cellulose with lauroyl chloride. The second step in my experiment is to discuss interaction between hydrophobically modified hydroxyethyl cellulose and Tergitol 15-S-5 and to compare my results with literatures. We observe interaction with viscosity (η)、dissociation energy (Em)、hydrodynamic radius (RH).
N. C. Bras, A. Collet, M. Viguier, “Synthesis and Linear Viscoelasticity of Fluorinated Hydrophobically Modified Ethoxylated Urethanes (F-HEUR)”, Macromolecules, 31, 1305-1311 (1998)
F. E. Antunes, K. Thuresson, B. Lindman, M. G. Miguel, “A Rheological Investigation of the Association between a Nonionic Microemulsion and Hydrophobically Modified PEG. Influence of Polymer Architecture”, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 215, 87-100 (2003)
D. Bai, C. C. Khin, S. B. Chen, C. C. Tsai, B. H. Chen, “Interaction between A Nonionic Surfactant and A Hydrophobically Modified 2-Hydroxyethyl Cellulose”, Journal of Physical Chemistry B, 109, 909-4916 (2005)
D. G. Brown, K. S. A. Nuaimi, “Nonionic Surfactant Sorption onto the Bacterial Cell Surface: A Multi-interaction Isotherm”, Langmuir, 21, 11368-11372 (2005)
I. S. Chronakis, P. Alexandridis, “Rheological Properties of Oppositely Charged Polyelectrolyte-Surfactant Mixtures: Effect of Polymer Molecular Weight and Surfactant Architecture”, Macromolecules, 34, 5005-5018 (2001)
P. Deo, P. Somasundaran, “Interactions of Hydrophobically Modified Polyelectrolytes with Nonionic Surfactants”, Langmuir, 21, 3950-3956 (2005)
P. Deo, S. Jockusch, M. F. Ottaviani, A. Moscatelli, N. J. Turro, P. Somasundaran, “Interactions of Hydrophobically Modified Polyelectrolytes with Surfactants of the Same Charge”, Langmuir, 19, 10747- 10752 (2003)
M. Egermayer, J. Norrman, L. Piculell, “Gels of Hydrophobically Modified Hydroxyethyl Cellulose Cross-Linked by Amylose: Competition by Added Surfactants”, Langmuir, 19, 10036-10043 (2003)
D. Gräbner, T. Liebert, T. Heinze, “Synthesis of Novel Adamantoyl Cellulose Using Differently Activated Carboxylic Acid Derivatives”, Cellulose, 9, 193-201 (2002)
T. Heinze, T. F. Liebert, K. S. Pfeiffer, M. A. Hussain, “Unconventional Cellulose Esters: Synthesis, characterization and Structure-property relations”, Cellulose, 10, 283-296 (2003)
E. Hoff, B. Nyström, B. Lindman, “Polymer-Surfactant Interactions in Dilute Mixtures of a Nonionic Cellulose Derivative and an Anionic Surfactant”, Langmuir, 17, 28-34 (2001)
Y. Kondo, N. Yoshino, “Hybrid Fluorocarbon/Hydrocarbon Surfactants”, Current Opinion in Colloid & Interface Science, 10, 88-93 (2005)
H. M. Kopperud, F. K. Hansen, B. Nyström, “Effect of Surfactant and Temperature on the Rheological Properties of Aqueous Solutions of Unmodified and Hydrophobically Modified Polyacrylamide”, Macromolecular Chemistry and Physics, 199, 2385–2394 (1998)
R. G. Larson, ”The structure and Rheology of Complex Fluids”, Oxford university, New york, pp. 12-18 (1999)
C. E. Lin, “Determination of Critical Micelle Concentration of Surfactantsby Capillary Electrophoresis”, Journal of Chromatography A, 1037, 467-478 (2004)
I. J. Lin, “The Hydrophile-Lipophile Balance (HLB) of Fluorocarbon Surfactantsand Its Relation to the Critical Micelle Concentration (cmc)”, The Journal of Physical Chemistry, 76, 2019-2023 (1972)
C. L. McCormick, P. A. Callais, “ Derivatization of Cellulose in Lithium Chloride and N-N-Dimethylacetamide Solutions”, Polymer, 28, 2317-2323 (1987)
C. L. McCormick, P. A. Callais, B. H. Hutchinson, “Solution Studies of Cellulose in Lithium Chloride and N,N- Dimethylacetamide”, Macromolecules, 18, 2394-2401 (1985)
K. Materna, I. Milosz, I. Miesiac, G. Cote, J. Szymanowski, “Removal of Phenols from Aqueous Streams by the Cloud Point Extraction Technique with Oxyethylated Methyl Dodecanoates As Surfactants, Environmental Science and Technology, 35, 2341-2346 (2001)
I. Nahringbauer, “Polymer-Surfactant Interaction As Revealed by the Time Dependence of Surface Tension. The EHEC/SDS/Water System”, Langmuir, 13, 2242-2249 (1997)
K. Nishikawa, A. Yekta, H. H. Pham, M. A. Winnik, “Fluorescence Studies of Hydrophobically Modified Hydroxyethylcellulose (HMHEC) and Pyrene-Labeled HMHEC”, Langmuir, 14, 7119-7129 (1998)
K. Ogino, M. Abe, “Mixed Surfactant Systems”, Marcel Dekker, New York (1993)
S. Panmai, R. K. Prud’homme, D. G. Peiffer, S. Jockusch, N. J. Turro, “Interactions between Hydrophobically Modified Polymers and Surfactants: A Fluorescence Study”, Langmuir, 18, 3860-3864 (2002)
L. Piculell, M. Egermayer, J. Sjöström, “Rheology of Mixed Solutions of an Associating Polymer with a Surfactant. Why Are Different Surfactants Different?”, Langmuir , 19, 3643-3649 (2003)
L. Piculell, K. Thuresson , B. Lindman, “Mixed Solutions of Surfactant and Hydrophobically Modified Polymer”, Polymers forAadvanced Technologies, 12, 44-69 (2001)
A. M. Regiani, E. Frollini, G. A. Marson, G. M. Arantes, O. A. E. Seoud, “Some Aspects of Acylation of Cellulose Under Homogeneous solution Conditions”, Journal of Polymer Science Part A: Polymer Chemistry, 37, 1357-1363 (1999)
M. J. Rosen, “Surfactants and Interfacial Phenomena”, Wiley-VCH, New York, pp. 326-329 (1989)
N.V. Sastry, H. Hoffmann, “Interaction of Amphiphilic Block Copolymer Micelles with Surfactants”, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 250, 247–261 (2004)
R. J. Stokes, D. F. Evans, “Fundermentals of Interfacial Engineering”, Wiley-VCH, New York (1997)
R. Tanaka, J. Meadows, P. A. Williams, G. O. Phillips, “Interaction of Hydrophobically Modified (Hydroxyethy1)cellulose with Various Added Surfactants”, Macromolecules, 25, 1304-1310 (1992)
K. Thuresson, B. Lindman, B. Nyströ1m, “Effect of Hydrophobic Modification of a Nonionic Cellulose Derivative on the Interaction with Surfactants. Rheology”, Journal of Physical Chemistry B, 101, 6450-6459 (1997)
V. Tirtaatmadja, K. C. Tam, R. D. Jenkins, “Effects of Temperature on the Flow Dynamics of a Model HASE Associative Polymer in Nonionic Surfactant Solutions”, Langmuir, 15, 7537-7545 (1999)
M. Vasilescu, D. F. Anghel, “Fluorescence Probe Study of the Interactions between Nonionic Poly(oxyethylenic) Surfactants and Poly(acrylic acid) in Aqueous Solutions”, Langmuir, 13, 6951-6955 (1997)
F. M. Winnik, S. T. A. Regismond, “Fluorescence Methods in the Study of the Interactions of Surfactants with Polymers”, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 118, 1-39 (1996)