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研究生: 賴致廷
Lai, Chih-Ting
論文名稱: 鎂添加對SS400低碳鋼於高溫下沃斯田鐵晶粒成長之影響
Effect of Mg Addition on the Grain Growth Behavior of Austenite in SS400
指導教授: 郭瑞昭
Kuo, Jui-Chao
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年: 2017
畢業學年度: 105
語文別: 中文
論文頁數: 99
中文關鍵詞: 低碳鋼鎂含量沃斯田鐵晶粒成長氧化物冶金
外文關鍵詞: low carbon steel, magnesium content, austenite grain growth, oxide metallurgy
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  • 低碳鋼在銲接時,於銲處周圍的粗晶熱影響區會產生沃斯田鐵晶粒成長的現象,為了解決這個問題,添加鎂於低碳鋼中,可有助於阻止晶粒成長。本研究探討添加不同鎂含量的低碳鋼SS400在高溫下晶粒成長的影響,使用晶粒成長公式預測不同熱處理溫度及時間下沃斯田鐵晶粒尺寸。
    本研究將試片使用高溫共軛焦雷射掃描顯微鏡(HT-CLSM)做熱處理實驗,並使用光學顯微鏡分析軟體分析高溫沃斯田鐵晶粒,取樣至少300個晶粒。接著運用統計學的概念,求得出平均數、中位數、眾數3個不同意義的特徵值。本研究將3個晶粒成長公式的模型以及3個平均值逐一比較,最終選擇眾數作為晶粒尺寸,並採用新發展的晶粒成長公式。接著,本研究使用晶粒尺寸、晶粒成長公式求得出晶粒成長速率及晶界遷移速率。
    實驗結果顯示,晶粒成長公式中的活化能Q值,以0 ppm Mg最大,1.6 ppm Mg最小,隨著鎂含量的增加,Q值也會隨之提升。在相同溫度下,晶粒尺寸由大到小依序為0ppm、7.7ppm、1.6ppm、25ppm Mg SS400。在1200°C下,不含鎂的SS400與含鎂的SS400的晶粒成長速率(持溫20分鐘)與晶界遷移速率差異不大;隨著溫度升高,兩者的差異漸趨明顯,晶粒成長速率(持20分鐘)及晶界遷移速率由快到慢依序為0ppm、7.7ppm、1.6ppm、25ppm Mg SS400。

    For the large heat input welding technique using heat input over 50kJ/cm, as increasing the heat input energy, coarsening in austenite grains will be enhanced in the heat-affected zone (HAZ) during welding and coarse grains have detrimental effect on impact toughness of weldments. Thus, Mizoguchi et al. firstly proposed oxide inclusions for improving HAZ impact toughness in the case of large heat input welding. Titan and magnesium oxides can be called the “first” and “second” generation of oxide inclusions for acicular ferrite (AF) formation in terms of development time, respectively.
    In this study we mainly investigated on the effect of Mg addition on the austenite grain growth in low carbon steel of SS400 using thermal etching. Furthermore, in-situ observations of austenite grain growth were also performed with a high-temperature confocal scanning laser microscope (HT-CSLM). The results show that the austenite grain size and grain growth rate decrease with the increase of magnesium content.

    摘要.......................................I Extended Abstract.........................II 誌謝....................................VIII 目錄......................................IX 表目錄....................................XI 圖目錄...................................XII 第一章 前言................................1 第二章 文獻回顧............................3 2.1銲接與熱影響區..........................3 2.2介在物冶金技術..........................6 2.2.1釘扎效應.............................7 2.2.2誘發晶內針狀肥粒鐵....................9 2.2.3介在物冶金技術的演進..................11 2.3沃斯田鐵晶界顯現方法-熱腐蝕法...........15 2.4晶粒成長公式...........................19 2.4.1推導................................19 2.4.2 延伸...............................24 第三章 實驗方法...........................26 3.1 實驗材料.............................26 3.2沃斯田鐵晶粒成長實驗...................28 3.2.1試片製備............................28 3.2.2熱處理實驗..........................29 3.3晶粒尺寸分析..........................34 3.3.1取樣晶粒方法........................34 3.3.2晶粒數量取樣........................39 3.4晶粒成長公式..........................40 第四章 結果與討論.........................44 4.1取樣晶粒數量的影響.....................44 4.1.1不同取樣數量lognormal分布............44 4.1.2 不同取樣數量與晶粒尺寸及標準差的關係..46 4.2 平均晶粒尺寸計算方法的比較.............47 4.2.1晶粒尺寸分布.........................47 4.2.2晶粒尺寸............................61 4.3特徵值與晶粒成長公式之選擇..............64 4.3.1特徵值的選擇.........................64 4.3.2晶粒成長公式模型的選擇................66 4.3.2最終晶粒成長公式.....................74 4.4 加熱溫度的影響........................77 4.4.1加熱溫度對晶粒尺寸的影響..............77 4.4.2加熱溫度對晶粒成長速率的影響..........79 4.3.3加熱溫度對晶界遷移率的影響............82 4.5鎂含量的影響...........................85 4.5.1鎂含量對晶粒尺寸的影響................85 4.5.2鎂含量對晶粒成長速率的影響............87 4.5.3鎂含量對晶界遷移率的影響..............90 第五章 結論..............................93 參考文獻.................................94

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