本研究探討光觸媒光纖薄膜結合紫外光，對微囊藻細胞破壞和對其代謝物(微囊藻毒素)的降解，主要分為兩個部分。
第一部分是材料製備實驗，配製光觸媒光纖薄膜之覆膜二氧化鈦(TiO2)溶膠，使用浸漬提拉法進行光觸媒光纖薄膜。本研究使用光纖薄主要是要克服光在水中傳輸之影響，提升對系統之效能，且並以不同拉提次數測試出最佳之TiO2光纖光觸媒薄膜鍍膜方法。結果顯示5次以下之提拉鍍膜之TiO2光觸媒覆膜效果最完整，並比較光催化效果，其中2次提拉鍍膜效果可產生8.32×10-15 M 氫氧自由基量最多，因此後續之藻類氧化試驗均以此最適條件下進行。
第二部分則針對藻類進行批次氧化實驗，研究項目包括自由基生成濃度分析、細胞完整性趨勢分析、微囊藻毒素變化分析、細胞計數；最後再以實驗所得數據對細胞破裂及藻毒素的釋出及降解趨勢進行模式模擬分析。結果顯示，單純UV光系統下，於8小時藻類明顯破裂，隨之藻毒釋出，而釋出的微囊藻毒素24小時內降解約40%；而UV光搭配TiO2薄膜系統，由於石英玻棒上TiO2薄膜使UV透光度下降，因此在24小時內藻細胞完整性無明顯變化，微囊藻毒素也無明顯釋出；針對微囊藻毒素進行光催化降解探討，比較有無TiO2薄膜對UV系統，結果顯示，反應到24小時後，TiO2/UV系統較僅有UV時去除率可從70%提升至80%，且系統中TOC在24小時內能被去除15%。
針對模式推估，本論文以Delayed Chick-Watson Model動力模式，分析氫氧自由基對細胞破裂的影響；並以上述模式及藻毒素二階降解模式，模擬氧化試驗系統中藻毒素釋出與降解趨勢，結果顯示該模式可有效模擬細胞破裂、及後續的總微囊藻毒素降解，可作為後續TiO2薄膜/UV系統應用之參考。

This study investigated the lysis of Microcystis aeruginosa cells and degradation of microcystins in the system of titanium dioxide-coated quartz rod under UV light condition. Two major portions are included in this study, materia preparation and selection, and tests of cell lysis and microcystin degradation.
In the first part of this study, material was prepared by coating a titanium dioxide (TiO2) slurry and using dip coating method for preparing a photocatalytic fiber film. The quartz rod used in this study is to overcome the influence of light transmission in water, improving the performance of photooxidation in the system. The experimental results show that the TiO2 film layer coated on the quartz rod dip may remain integral if the coating was below 5 times. When coated with 2 times, the production of hydroxyl radicals reached the highest, at 8.32×10-15 M, among the tested conditions.
The second part of this study is oxidation experiment. The parameters monitored during the experiments include free radical concentration, cell integrity, microcystins concentration, and cell counting. Use oxidant kinetic model to simulate the cell integrity of Microcystis and the microcystins release and degradation. The results showed that in the UV light only system, the cell integrity changed significantly in 8 hours, and then the microcystins was released, and the released microcystins were degraded by about 40% within 24 hours. In UV/TiO2 system, the TiO2 film on the rod reduces the UV transmittance, leading to no impact on cell integrity and no microcystin degardation within 24 hours. Experimental results for microcystin degradation indicte that in the the TiO2/UV and UV only systems, microcystin was degraded by 80% and 70%, repsctively, after 24 hr of reaction. In the mean time, TOC was destructed by 15% for the TiO2/UV. It is shown that hydroxyl radical produced in the system can improve the degradation of the microcystins and degrade the TOC in the water.
To simulate cell lysis and microcystin degradation in the studied systems, the Delayed Chick-Watson Model model was employed. The results show that this model can effectively simulate cell rupture and subsequent degradation of microcystins for the TiO2 film/UV system.

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