| 研究生: |
劉玉梅 Liu, Yu-Mei |
|---|---|
| 論文名稱: |
向陽絹雲母礦中葉蠟石水熱合成方沸石之研究 A study on the hydrothermal synthesis of analcime from pyrophyllite in Hsiang-Yang Sericite Ore |
| 指導教授: |
雷大同
D.Ray |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 資源工程學系 Department of Resources Engineering |
| 論文出版年: | 2006 |
| 畢業學年度: | 94 |
| 語文別: | 中文 |
| 論文頁數: | 127 |
| 中文關鍵詞: | 絹雲母 、葉蠟石 、方沸石 、水熱合成 |
| 外文關鍵詞: | sericite, hydrothermal synthesis, analcime, pyrophyllite |
| 相關次數: | 點閱:122 下載:1 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
本研究以向陽礦業公司所生產之雲母粉為起始原料,絹雲母(鉀及鈉雲母)含量約為57 %,其它為葉蠟石及極少量綠泥石,利用水熱反應方式進行方沸石之合成,使用之主礦化劑有Na2SiO3、NaOH、Na2CO3、NaCl,次礦化劑有NaF、NaCl、NaOH、Na2CO3、Na3PO4,在150 ℃~240 ℃的溫度下進行反應,探討主及次礦化劑種類、濃度、固/液比、反應溫度及時間對方沸石相的產生及晶形的影響,建立方沸石生成之條件。
In this study, the mica powders produced by Sunshine Mineral Company was used as the starting material. The content of sericite is about 57 % (muscovite and paragonite) with the other major mineral pyrophyllite and very small amount of chlorite. Hydrothermal reactions was used to synthesize analcime. The primary mineralizers used were Na2SiO3, NaOH, Na2CO3, NaCl, while NaF, NaCl, NaOH, Na2CO3, Na3PO4 as minor mineralizers. Reaction temperatures were between 150oC~240 oC. The reaction conditions, i.e. type and concentration of mineralizers, solid/liquid ratio, reaction temperature and time were investigated to find their effects on the phase and morphology of analcime produced, so as to establish the primary synthesis conditions.
1. 魏稽生及譚立平編著,台灣經濟礦物第二卷台灣非金屬經濟礦物,經濟部中央地質調查所,民國88年12月。
2. 向陽礦業專業區規劃開發計劃書報告,台灣省礦務局(民國84年8月)。
3. 陳其瑞,”台東縣向陽雲母礦成因之初步研究,”經濟部中央地質調查所特刊第3號,第161-169頁(民國73年12月)。
4. 李宗銘,”半導體封裝材料發展趨勢,”工業材料139期,第108-116頁(民國87年7月)。
5. 范玉玫,”IC 構裝材料發展趨勢,”工業材料151期,第69-77頁(民國88年7月)。
6. 王春山及何宗漢,”低應力半導體封裝材料之簡介,”工程,第.19-28頁(民國89年11月)。
7. 溫紹炳,雷大同及黃紀嚴,台灣片狀矽酸鹽礦物之利用開發計劃書報告,經濟部礦業司 (民國89年11月)。
8. Klein, C. and C.S. Hurlbut, Jr., Manual of Mineralogy, 21st Ed, 2000.
9. 張振輝,向陽絹雲母礦中絹雲母及葉蠟石水熱改質研究,國立成功大學資源工程研究所碩士論文,2005年。
10. Grim, R. E., Clay Mineralogy, McGraw-Hill, New York, 1953.
11. 張仲民,普通土壤學,國立編譯館出版,台北市,民國77年。
12. 王明光,土壤環境礦物學,藝軒圖書出版社,台灣,2000年1月1日。
13. Altaner, S. P. and N. Vergo, “Sercite from the Silverton caldera, Colorado : Discussion,” American Mineralogist, Vol.73, pp.1472-1474, 1998.
14. Eberl, D. D., J. Srodon, M. C. Lee and P.H. Nadeau, “Sericite from the Silverton caldera, Colorado: Reply,” American Mineralogist, Vol.73, pp.1475-1477, 1988.
15. Abe H., M. Aoki and H.Konno, “Synthesis of analcime from volcanic sediments in sodium silicate solution,” Contributions to mineralogy and petrology . Vol.42, pp.81-92, 1973.
16. 趙杏媛及張有瑜,黏土礦物與粘土礦物分析,海洋出版社,北京,1990年5月。
17. Velten, U., R. A. Shelden, W. R. Caseri, U. W. Suter and Y. Z. Li, “Polymerization of styrene with peroxide initiator ionically bound to high surface area mica,” Macromolecules, Vol.32, pp.3590-3597, 1999.
18. 任磊夫,黏土礦物與粘土岩,地質出版社,北京市,1992年2月。
19. Sand, L. B. and F. A. Mumpton, “Natural Zeolites, Occurrence, Properties, Use” Pergamon Press, 1976.
20. 彭國文,利用台灣東部安山岩製造沸石粉體之研究,國立成功大學礦冶及材料科學工程系碩士論文,1990年。
21. Yokomori, Y. and S. Idaka, “The crystal structure of analcime,” Microporous and Mesoporous Materials, 21, pp.365-370, 1998.
22. 溫紹炳, “Synthesis of zeolites from fly ash,” 行政院國家科學委員會補助專題研究報告, 81-0405-E006-028.
23. Kerr, G.T. “Chemistry of crystalline aluminosilicates. I. Factors affecting the formation of zeolite A.” J. Phys. Chem., vol.70 , pp.1047-1050, 1966.
24. Breck, D.W. and E. M. Flanigen, “Molecular Sieves,” Society of Chemical Industry, London., pp.47-61, 1968.
25. Culfaz, A. and L.B. Sand, “Mechanism of nucleation and crystallization of zeolites from gels,” Adv. Chern. Ser, vol.121, pp.141-151, 1973.
26. Fournier, R. and J.J. Rowe “The solubility of amorphous silica in water at high temperature and high pressure,” Amer. Mineral., vol.62, pp. 1052-1056, 1977.
27. Lo, H.J. “Hydrothermal Synthesis of analcime and zeolite P from andesitic tuff,” Proc. Geol. Soc, China, No.28, pp.70-82, 1985.
28. Flanigen, E. M. and D. W. Breck, American Chemical Society, 137th Meeting, Cleveland, Ohio, 1960.
29. Morgan, S. “Aquatic chemistry :An Introduction emphasizing chemical equilibria in natural water” 2nded., Wiley, New York, 1981
30. Cronstedt, A.F., “Observation and description of an unknown kind of rock to be named zeolites, ” Kongl. Vetenskaps. Acad. Handl. Stockh, vol.17, pp.120-123, 1756.
31. Sameshima, J., “Sorption of gas by mineral. I. Heulandite and chabazite”, Bull. Chem. Soc. Jpn., vol.4, pp.96-103, 1929.
32. Barrer, R.M. “The sorption of polar and non-polar gases by zeolites,” Proc. 6th Int. Conf. Zeolite, Butterworths, Guildford, pp.584-594, 1938.
33. Breck, D.W. “Zeolite Molecular Sieves,” John Wiley and Sons, New York, 1974.
34. Dunham, K.C., “Crystal cavities in lava from the Hawaiian Island,” Amer. Mineral., vol.19, pp.369-385, 1933.
35. Hay, R.L., “Geological occurrence of zeolites,” In Natuarl Zeolite, Occurrence, Properties, Use, Pergamon Press, Ltd., London, pp.135-144, 1978.
36. Iijima, A., “Geological occurrences of zeolites in marine environments,” In Natural Zeolites: Occurrence, Porperties, Use, Pergamon Press Ltd., London, pp.175-198, 1978.
37. Surdam, R.C. and R.A. Sheppard, “Zeolites in saline, alkaline-lake deposits,” Natural Zeolites: Occurrence, Porperties, Use, Pergamon Press Ltd., London, pp.145-174, 1978.
38. Taylor, M.W. and R.C. Surdam, “Zeolite reactions in the tuffaceous sediments at Tells March, Nevada,” Clays and Clay Min., 29(5), pp.341-352, 1981.
39. Gottardi, G. E. and Galli, “Natural Zeolites,” Springer-Verlag Berlin Heidelberg, 1985.
40. Howden, M. and J. Pilot, “The choice of ion exchanger for British Nuclear Fuels Ltd’s site ion exchage effluent plant,” In Ion Exchange Technology, pp.66-73, 1984.
41. Kallo, D., “Wastewater purification in Hungary using natural zeolites,” Natural Zeolites ’93, Occurrence, Properties, Use, Brockport, New York, pp.341-350, 1995.
42. Robbinson, S.M., T.E. Kent and W.D. Arnold, “Treatment of contaminated wastewater at Oak Ridge Natural Laboratory by zeolites and other ion exchangers,” Natural Zeolites ’93, Occurrence, Properties, Use, Brockport, New York, pp.579-586, 1995.
43. Yang, S.Y., A.G. Vlessidis and N.P. Evmiridis, “Synthesis of zeolites in the system Na2O-Al2O3-SiO2-H2O-glycerol,” Microporous Materials, vol.9, pp.273-286, 1997.
44. 楊金臻,由玄武岩玻璃及非晶質二氧化矽合成絲光沸石,國立台灣大學碩士論文,1988年。
45. Lo, H.J., “Hydrothermal synthesis of analcime, erionite and phillipsite from natural basaltic glass,” Pro. Nat. Sci. Council., Part A, vol.7, pp.69-74, 1983.
46. Juan, V.C. and H.J. Lo, “Phase relation in the system NaAlSi3O8 - CaAl2Si2O8 - H2O at low temperatures and pressures,” Proc. Geol. China., 12, pp.21-29, 1969.
47. Novotna, M., V. Satava, J. Maixner, A. Klouzkova, P. Kostka, and D. Ležal, “Preparation and Characterisation of Analcime powders,” Journal of Optoelectronics and Advanced Materials, vol. 5, No. 5, pp.1405-1409, 2003.
48. 陳惠芬,Na2O.Al2O3.nSiO2,CaO.Al2O3.nSiO2,xCaO.(1-x)Na2O.Al2O3.nSiO2及xNa2O.(1-x)K2O.Al2O3.nSiO2系統中合成沸石之研究,國立台灣大學地質科學研究所博士論文,2003年。
49. Lo, H.J., “The grain size effect on the synthesis of analcime from the glassy basalt,” Memoir. Geol. Soc, China, No8, April, pp.87-94, 1987.
50. Ouerol, X., “Synthesis of Na zeolites from fly ash,” Fuel, 76, (8). pp.793-799, 1997.
51. Chaisena, A. and K. Rangsriwatananon, “Synthesis of sodium zeolites from natural and modified diatomite,” Material letters, vol.59, pp.1474-1479, 2005.
52. Barrer, R.M. and E.A.D. White, “The hydrothermal chemistry of the silicates. Part Ⅱ. Synthetic crystalline sodium aluminosilicates,” Jour. Chem. Soc., Faraday Trans, London, pp.1561-1571, 1952.
53. Senderov, E.E. and N.I. Khitarov, “Synthesis of thermodynamically stable zeolites in the Na2O-Al2O3-SiO2-H2O system,” In Molecular Sieve Zeolites. I., Amer. Chem. Soc. Adv. Chem. Ser., vol.101, pp.149-154, 1971.
54. Gevorgyan, R.G., H.H. Sargsyan, G.G. Karamyan, G.M. Aleksanyan and Y. Keheyan, “Experimental study of Hydrothermal Transformations of Clinoptilolite in NaOH water solutions,”Herald of the Department of Earth Sciences RAS, No 1(22), 2004
55. 胡植慶,由安山凝灰岩及安山凝灰岩-矽酸合成沸石,國立台灣大學碩士論文,1989年。
56. Ueda S. and M. Koizumi, “Crystallization of analcime solid solution from aqueous solution,” Amer. Mineral., vol.64, pp.172-179, 1979.