金屬有機骨架(Metal–Organic Framework, MOF)由於具備規律的孔洞結構和高比表面積，近年來被大量使用於在各項應用中。其中，以MOF製成的修飾電極由於能提升單位體積的電化學活性位點，在眾多電化學應用領域中極具吸引力與潛力。但是大多數的MOF缺乏化學穩定性以及是電的不良導體，大幅限縮其在電化學領域上的應用。
因此，於本篇研究中，我們選擇以鋯為節點的金屬有機骨架(Zirconium-based MOF, Zr-MOF)-UiO-66-NH2作為MOF材料，並結合導電高分子聚苯胺(Polyaniline, PANI)形成奈米複合材料。並且，本研究為首次透過具策略性的實驗方法，選擇性地將PANI限制生成於MOF的奈米孔洞中，同時可以避免大量成堆的聚苯胺(Bulk PANI)生成於MOF晶體間，進而得到所需的奈米複合材料(PANI/UiO-66-NH2 Nanocomposites)。
以PANI/UiO-66-NH2製備的修飾電極在電化學測試中除了表現出擬電容性質外，由於孔洞限制，使其具有優於Bulk PANI的電化學活性以及電荷儲存的容量，同時也在長期充放電過程中(6000 cycles)展現優異的循環穩定性，為適合用作超電容器的材料。

In this thesis, a strategy that can result in the polyaniline (PANI) solely confined within the nanopores of a metal–organic framework (MOF) without forming obvious bulk PANI between MOF crystals is developed. A water-stable zirconium-based MOF, UiO-66-NH2, is selected as the MOF material. The polymerization of aniline is initiated in the acidic suspension of UiO-66-NH2 nanocrystals in the presence of excess poly(sodium 4-styrenesulfonate) (PSS).
Since the pore size of UiO-66-NH2 is too small to enable the insertion of the bulky PSS, the quick formation of pore-confined solid PANI and the slower formation of well dispersed PANI:PSS occur within the MOF crystals and in the bulk solution, respectively. By taking advantage of the resulting homogeneous PANI:PSS polymer solution, the bulk PANI:PSS can be removed from the PANI/UiO-66-NH2 solid by successive washing the sample with fresh acidic solutions through centrifugation. As this is the first time reporting the PANI solely confined in the pores of a MOF, as a demonstration, the obtained PANI/UiO-66-NH2 composite material is applied as the electrode material for supercapacitors. The PANI/UiO-66-NH2 thin films exhibit a pseudocapacitive electrochemical characteristic, and their resulting electrochemical activity and charge-storage capacities are remarkably higher than those of the bulk PANI thin films.

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