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研究生: 方議陞
Fang, Yi-Sheng
論文名稱: 以攪拌式膜蒸餾法純化乙醇
Ethanol Purification by Membrane Distillation with Stirring
指導教授: 周榮華
Chou, Jung-Hua
學位類別: 碩士
Master
系所名稱: 工學院 - 工程科學系
Department of Engineering Science
論文出版年: 2014
畢業學年度: 102
語文別: 中文
論文頁數: 70
中文關鍵詞: 薄膜表面剪應力分離因子極化現象攪拌式葉片
外文關鍵詞: Wall shear, Separation factor, Polarization, Rotation blade
相關次數: 點閱:73下載:2
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  • 本研究利用AGMD(Air gap membrane distillation)加上攪拌式葉片應用於乙醇分離純化系統,使膜面表層附近溫度和濃度邊界厚度降低,增加薄膜表面剪應力,基於此原理上運用CFD軟體配合田口分析,選擇最佳模組條件進行實驗,探討AGMD在不同的攪拌速度、進料溫度、進料流量、進料濃度對於通量及乙醇分離因子的影響,結果顯示滲透通量和分離因子會隨著溫度上升,攪拌的速度愈快分離因子愈高,表示系統受極化現象愈少,另外實驗也顯示此系統薄膜蒸餾,可以有效純化乙醇水溶液,經由連續兩次純化分離後濃度可以由5%濃度提升至48.6%以上。

    Applying rotation blade to increase turbulence intensity of flow nearby the membrane can decrease both temperature and concentration polarizations and therefore can enhance the permeating flux and separation factor. The thesis uses numerical simulation to investigate the wall shear field in a hot cavity circulation region of an air gap membrane distillation system for ethanol extraction by computational fluid dynamics (CFD) and Taguchi analysis to find the optimal parameters. The results validate that wall shear near the membrane increases greatly with rotational motion. Different inpouring feed flux, concentration, stirring speed, and feed temperature will influence the permeating flux and separation factor.

    目錄 摘要 I Abstract II 誌謝 V 目錄 VI 表目錄 IX 圖目錄 X 符號說明 XIII 第一章 緒論 1 1-1前言與研究動機 1 1-2文獻回顧 4 1-3研究目標 16 1-4研究流程 17 第二章 薄膜蒸餾系統 18 2-1薄膜蒸餾概述 18 2-2薄膜蒸餾優點 19 2-3 薄膜蒸餾種類 20 2-4 薄膜性質 25 2-5 極化現象影響 28 2-6 影響薄膜蒸餾的因素 30 第三章 模擬分析 34 3-1 前言 34 3-2 流體假設 34 3-3 模擬控制方程式 35 3-3-1 質量守恆方程 35 3-3-2 動量守恆方程 35 3-3-3 κ-ε紊流模型 36 3-4數值方法 36 3-4-1流體計算域之建立 37 3-4-2網格獨立性分析 39 3-5田口實驗設計法[26] 40 3-6 邊界條件之設定 41 第四章 實驗設備與步驟 44 4-1實驗模組 44 4-2實驗設備 45 4-3實驗藥品與薄膜材料 50 4-4實驗步驟 50 4-5實驗條件 51 4-6 氣相層析儀(Gas Chromagraphy)實驗步驟 52 4-7穩定狀態滲透氣化 54 第五章 結果與討論 55 5-1 前言 55 5-2 田口分析結果探討 55 5-3 各操作條件對通量、分離因子的影響 57 5-2-1 溫度的影響 58 5-2-2 流量的影響 61 5-2-3 濃度的影響 62 5-2-4 轉速的影響 64 第六章 結論與建議 66 6-1結論 66 6-2建議 67 參考文獻 68

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