本論文主要進行兩項研究: 一為氮化硼塗料開發，另一為氮化鋁之燃燒合成及表面改質製程研究。氮化硼具有耐高溫、防沾黏金屬液等特性，故可做成塗料供冶金相關產業應用。本研究開發之氮化硼塗料為水性塗料，採用PVA和Al(H2PO4)3作為其常溫和高溫黏結劑，以使塗層具備良好的附著度與機械強度。吾人採用ASTM D 3359 Test Method B之百格測試，量測塗層的附著度等級。本研究探討塗料成份組成及製程條件對塗層附著度及機械強度之影響。此外，藉由SEM、EDS分析可證實含Al(H2PO4)3之塗料在400℃固化熱處理後，會經脫水反應形成不同結晶相或非結晶相的磷酸鋁鹽類，此鹽類會藉由其反應機制來固化塗層，以增強氮化硼對基材的附著度。在氮化鋁之燃燒合成及表面改質製程研究方面，本研究發現本實驗室一批次生產5kg的製程，若使用高純度氮氣且壓力為0.6MPa，可獲得更多最高之轉化率及最低之氧含量的AlN。在改質方面，本研究發現研磨中改質之AlN具有接近研磨後改質的AlN之抗濕能力，且研磨後以室溫改質之AlN具有與加熱至60℃改質之AlN相當之抗濕效果。這些發現將有助於AlN表面改質之製程簡化及成本降低。

This study was divided into two parts, one was process development for boron nitride coating, another was combustion synthesis of aluminum nitride and its surface treatment. Boron nitride had many good properties like excellent thermal stability and poor wettability against metal melts, so it can be used to produce coatings applied in metallurgy industries. In this research, we chose water as liquid carrier, PVA and Al(H2PO4)3 as binder for better adhesion and mechanical strength for boron nitride coatings. The adhesion of coating layer was measured with ASTM D 3359 Test Method B. This research explored the influence of composition of coatings and process conditions on adhesion and mechanical strength of coating. In addition, it was proved that heating of the coating layer containing Al(H2PO4)3 at 400℃ caused dehydration and formation of crystalline and amorphous aluminum phosphates by SEM and EDS analysis. These aluminum phosphates can seal the coating due to its reaction mechanism, and enhance adhesion of boron nitride on the substrates. In the study of combustion synthesis of aluminum nitride and its surface treatment, it found that if it synthesized 5kg level of AlN with high-purity nitrogen in 0.6MPa, and it can get more products of AlN with lowest O% and highest conversion. In surface treatment part, it found that the moisture resistance of AlN treated from surface treatment during grinding process was close to that of AlN treated from surface treatment after grinding process, and treating AlN after grind without heating had almost the same effect as treating AlN at 60℃. These findings will be helpful for simplifying the surface treatment process of AlN and reducing costs.

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