| 研究生: |
林士琦 Lin, Shih-Chi |
|---|---|
| 論文名稱: |
以第一原理計算研究MAPbBr3之電域調變光學性質 Study of the domain modulated optical properties of MAPbBr3 based on First-Principles Calculations |
| 指導教授: |
許文東
Hsu, Wen-Dung |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 材料科學及工程學系 Department of Materials Science and Engineering |
| 論文出版年: | 2024 |
| 畢業學年度: | 112 |
| 語文別: | 中文 |
| 論文頁數: | 126 |
| 中文關鍵詞: | MAPbBr3 、有機鹵素鈣鈦礦材料 、電域調變 |
| 外文關鍵詞: | methylammonium lead tribromide(MAPbBr3), organometal halide perovskite, domain modulated |
| 相關次數: | 點閱:82 下載:0 |
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MAPbBr3屬於有機鹵素鈣鈦礦材料,其具有良好的光學表現,故多數應用集中於光電元件,例如電光調變器。其中電光調變器(Electro-Optic Modulator, EOM)的工作原理是基於電光效應(Electro-Optic Effect),這是一種材料在電場作用下其折射率生變化的現象。在實際應用中,電光調變器通常被用於光纖通信系統,用來對傳輸的光信號進行調控,從而提高數據傳輸速率和質量。此外,MAPbBr3這類的鐵電材料可以透過外加電場影響材料內部的電域形式,意即,外加電場可以控制材料內部屬於單一電域或者(有電域壁存在的)多電域形式,而不同的電域形式將會影響系統內部的光路表現。本研究將研究預期透過影響光路表現達到相位調變器的效果,模擬分成兩步驟:第一原理計算:計算材料光學性質,以及COMSOL Multiphysics:模擬單一電域系統中,無折射率差異(無相位調變)的電域中之光路情形;以及多電域系統中,相鄰電域存在折射率差異(有相位調變)導致光路改變的情形。
本研究成功以COMSOL Multiphysics歸納出具穩定且明顯的折射角度變化的體系,包含合適的入射波長以及入射角度,以及不同界面類型對折射情形的影響。
The refraction behavior of incident beam of different wavelengths passing through various DW interfaces at 50 K, 150 K, 200 K, 350 K were simulated via COMSOL Multiphysics. It is anticipated that light paths with no deflection (single domain) or with large angle deflection (multi-domain) can be used to describe the changes in domain distribution under the influence of an external electric field, and further applied to electro-optic modulator applications. This research successfully used COMSOL Multiphysics to establish a system with stable and significant refraction angle variations. This includes identifying suitable incident wavelengths and angles, as well as understanding how different interface types affect the refraction behavior.
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校內:2029-09-12公開