本文主要分為兩部份，第一部份為離子液體[BMP]^+ 〖[DCA]〗^-中探討含有0.1M GaCl3的電化學行為，以及利用定電位沉積法電鍍鎵金屬及銻化鎵合金。以玻璃碳電極探討Ga(Ⅲ) complex anions的氧化還原行為，可發現於電位-1.45V與-1.9V (vs. Ag)有二還原峰，經由chlorogallate混合方式判定，此二還原峰可能為〖[GaCl_x DCA_y]〗^- (x+y=4)及〖[GaCl_4]〗^-還原成Ga(0)的還原反應；電位0V有一寬廣的氧化峰，受到鎵金屬性質影響所導致其特殊現象。利用定電位沉積鎵金屬，以掃描式電子顯微鏡觀測形貌為球型顆粒，而隨著電位愈負球型尺寸愈小。
在含有50mM GaCl3+25mM SbCl3 [BMP]^+ 〖[DCA]〗^-中定電位共鍍GaSb合金，以鎳金屬為基材，發現於60℃的條件下，定電位-1.1V可共鍍得GaSb合金。沉積樣品以描式電子顯微鏡(SEM)、能量分散光譜儀(EDS)、粉末式X-ray繞射儀(XRD)、化學分析電子光譜儀(XPS)進行結構特徵分析。
第二部份主要探討離子液體與電極表面間的電雙層結構與陽離子吸附現象。在含有In(Ⅲ)的〖[BMP]〗^+ 〖[DCA]〗^-的系統中，以玻璃碳電極進行循環伏安法可發現不尋常的電化學行為，經由不同離子液體的比較(〖[EMI]〗^+ 〖[DCA]〗^-)，以及不同的電化學分析方法，可確定此系統中陽離子吸附電極表面會影響其電化學行為，最後總結不同電位時陽離子與電極表面之間的關係。

The electrochemical behaviors of GaCl3 were investigated in 1-butyl-1-methylpyrrol -idinium ionic liquids. The CV shows two reduction peaks were observed at -1.45V and -1.9V, which are assigned to the reduction of 〖[GaCl_x DCA_y]〗^- (x+y=4) and 〖[GaCl_4]〗^- to Ga(0), and a broad oxidation peak at 0 V on GC electrode. The
morphologies of the electrodeposits are investigated by SEM show that nanoscale spherical Ga can be obtained and the sizes of gallium decreased at larger overpotential. Electrodeposition of GaSb alloy from [BMP]^+ 〖[DCA]〗^- containing 25mM SbCl3 and 50mM GaCl3 at -1.1V under 60ºC. The XRD pattern indicated GaSb deposit is amorphous.
Ionic liquids (ILs) are widely used for electrochemical studies. However, electrochemical reactions taking place in ILs could be complicated by the interfacial IL ion layers at the electrode/IL interface. In this work, such complications are revealed via the electrochemical study of indium(III)/indium redox couple in the [BMP]^+ 〖[DCA]〗^- IL. Anomalous voltammetric behavior is observed with static cyclic voltammetry, convective rotating disk electrode voltammetry, and potential step chronoamperometry. The results indicate that the In(III) reduction process is complicated by the adsorption/desorption of the [BMP]+ cations. Meanwhile, less anomalous voltammetric behavior is observed in the 1-ethyl-3-methylimidazolium dicyanamide ([EMim]+[DCA]−) IL, in agreement with the weaker adsorption strength of the [EMim]+ cation. The impact of the cation adsorption is weakened by raising the temperature

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