簡易檢索 / 詳目顯示

研究生: 楊榮瑋
Yang, Jung-Wei
論文名稱: 利用微波製備並以氧化鍶催化將廢食用油進行生質柴油轉化效能之探討
The Research on Biodiesel Conversion Efficacy Processed by Microwave Heating with Waste Cooking Oil and Strontium Oxide Catalysis
指導教授: 廖峻德
Liao, Jiunn-Der
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年: 2015
畢業學年度: 103
語文別: 英文
論文頁數: 82
中文關鍵詞: 生質柴油微波加熱法氧化鍶廢食用油
外文關鍵詞: biodiesel, microwave, strontium oxide, waste cooking oil
相關次數: 點閱:67下載:0
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 時至今日,再生能源的長遠發展逐步備受關切與重視,生質柴油便是其一。它的特點是對環境友好的,因此被視為一種綠能的表現。在本研究中,為了製造生質柴油,透過微波加熱方式使反應經過酯交換並使用氧化鍶做為催化劑來加速其進行。
    由化學方程式得知,油和醇是必須的反應材料。於本實驗中,使用新鮮大豆沙拉油和廢棄食用油做為主要來源油,另使用甲醇原因是低成本。為了製造高轉化率的油,催化劑用量、醇油摩爾比、微波輸出功率、作用時間等均為決定因素。於微波中,為了不同用途,將使用批次處理系統和連續流系統。批次處理系統將有利於調整參變量,而連續流系統將聚焦於相對大量生產。
    於分析測試中,使用氣相色譜法以驗證食用油之轉化率,並運用掃描電鏡以觀察催化劑表面形態,同時搭配X射線衍射和能量色散譜以進行催化劑物質組成和表徵分析。
    實驗結果表明,對於廢棄食用油的最優工藝條件為微波功率500 W、催化劑用量3%、醇油摩爾比6:1,和流速160 mL/min。最優油轉化率為93.13%。於此,比較批次系統和連續流系統,便可得知連續流系統可大幅度地提升微波爐使用之效益,尤其是在反應時間縮短的成效上特別顯著。
    內容討論方面,於本論文中之四個參變量,如:催化劑添加量、油醇摩爾比、微波使用瓦數,及反應時間等,均會影響轉脂化轉化率之高低,過量或不適當的配置將導致反應不周全,如形成逆反應、皂化作用、機械器具過熱、反應時間延宕等。
    本研究希望能藉由收集住家或餐館產生之廢食用油做為原料,以提供大量生質柴油反饋於民,達到正向循環關係。

    Biodiesel fuel has characteristics that feature environmentally friendly properties and thus is thought of as a kind of green energy. To produce biodiesel, in this study, a microwave apparatus is utilized for heating in association with a transesterification reaction. In addition, strontium oxide is exploited as a catalyst to expedite the process.
    Based on the chemical formula, reactant oil as well as alcohol are required. In this experiment, both clean soybean oil and waste cooking oil are tested, and methanol is adopted for the sake of its low cost. To generate high conversion in oil, the amount of catalyst, the molar ratio of methanol-to-oil, and the output power as well as the reaction time in the microwave are all considered as parameters. Regarding the microwave, both a batch system and a continuous flow system are applied for different proposes. The batch system highlights the ease of adjusting parameters while the continuous flow system focuses on a relatively larger quantity of oil production.
    To verify the oil conversion, GC is used. Meanwhile, a SEM is responsible for the morphology observation of the catalyst. Furthermore, an XRD and an EDS are used in the component analysis of the catalyst.
    The final results indicate that a set of optimal parameters for waste cooking oil is 500 W with 3% catalyst and a molar ratio of 6:1 of methanol-to-oil under 160 mL/min of flow velocity, reaching a 93.13% oil conversion. It is compared with the batch system one and is proven to have better efficacy especially in regard to time-consumption.
    In discussion, these factors may have impacts on the conversion, including a backward reaction, saponification formation, overheating, and a postponement situation.
    It is expected to generate in a larger quantity to supply the citizens by collecting the daily waste cooking oil to promote a positive cycle relation.

    摘要 I Abstract II Acknowledgement III List of Contents V List of Tables VIII List of Figures IX Chapter 1 Introduction 1 1.1 Preface 1 1.2 Motivation 2 1.3 Literature Survey 5 1.3.1 Optimization of Experiment by Taguchi Method 5 1.3.2 Comparison of Heterogeneous Catalysts 8 1.3.3 Transesterification under SrO Catalysis 12 1.3.4 Quantity Decision of Methanol and Catalyst Amount 15 1.4 Objective 17 Chapter 2 Theoretical Basis 19 2.1 Brief Study of Biodiesel 19 2.2 Main Classification of Catalysts 22 2.3 Microwave Application and the Related Discussion 27 Chapter 3 Materials and Method 35 3.1 Experimental Concept 35 3.2 Experimental Design 35 3.3 Experimental Procedure 38 3.4 Experimental Instruments 41 3.4.1 Microwave Heating System 41 3.4.2 Gas Chromatograph (GC) 43 3.4.3 Scanning Electron Microscope (SEM) 44 3.4.4 X-ray Diffractometer (XRD) 46 Chapter 4 Results and Discussion of the Batch System 48 4.1 Effects of Applied Microwave Power and Reaction Time 48 4.2 Verification of Catalyst Amount 51 4.3 Ratio Between Methanol and Oil 53 4.4 Recycle Time Estimation 56 4.4.1 Oil Conversion Test using a Gas Chromatograph 56 4.4.2 Catalyst Morphology Observation using a Scanning Electron Microscope 58 4.4.3 Catalyst Microstructure Analysis using an X-ray Diffractometer and an Energy Dispersive Spectroscope 60 Chapter 5 Performance of Continuous Flow System 65 5.1 Relationships Between Flow Velocity and Oil Conversion 65 5.2 Measurement of Corresponding Reaction Temperature 68 Chapter 6 Conclusion 70 6.1 Conclusions 70 6.2 Prospects 71 References 73

    [1] E. M. Shahid and Y. Jamal, "Production of biodiesel: A technical review," Renewable and Sustainable Energy Reviews, vol. 15, pp. 4732-4745, 2011.
    [2] U. S. Energy Information Administration, "International energy outlook 2013," 2013.
    [3] A. L. Ahmad, N. H. M. Yasin, C. J. C. Derek, and J. K. Lim, "Microalgae as a sustainable energy source for biodiesel production: A review," Renewable and Sustainable Energy Reviews, vol. 15, pp. 584-593, 2011.
    [4] G. Kafuku and M. Mbarawa, "Biodiesel production from Croton megalocarpus oil and its process optimization," Fuel, vol. 89, pp. 2556-2560, 2010.
    [5] Y. C. Sharma and B. Singh, "Development of biodiesel: Current scenario," Renewable and Sustainable Energy Reviews, vol. 13, pp. 1646-1651, 2009.
    [6] A. S. Silitonga, A. E. Atabani, T. M. I. Mahlia, H. H. Masjuki, I. A. Badruddin, and S. Mekhilef, "A review on prospect of Jatropha curcas for biodiesel in Indonesia," Renewable and Sustainable Energy Reviews, vol. 15, pp. 3733-3756, 2011.
    [7] J. Hwang, D. Qi, Y. Jung, and C. Bae, "Effect of injection parameters on the combustion and emission characteristics in a common-rail direct injection diesel engine fueled with waste cooking oil biodiesel," Renewable Energy, vol. 63, pp. 9-17, 2014.
    [8] K. Muralidharan and D. Vasudevan, "Performance, emission and combustion characteristics of a variable compression ratio engine using methyl esters of waste cooking oil and diesel blends," Applied Energy, vol. 88, pp. 3959-3968, 2011.
    [9] R. Sathish Kumar, K. Sureshkumar, and R. Velraj, "Optimization of biodiesel production from Manilkara zapota (L.) seed oil using Taguchi method," Fuel, vol. 140, pp. 90-96, 2015.
    [10] G. Vicente, M. Martı́nez, and J. Aracil, "Integrated biodiesel production: a comparison of different homogeneous catalysts systems," Bioresource Technology, vol. 92, pp. 297-305, 2004.
    [11] V. G. Gude, P. Patil, E. Martinez-Guerra, S. Deng, and N. Nirmalakhandan, "Microwave energy potential for biodiesel production," Sustainable Chemical Processes, vol. 1, p. 5, 2013.
    [12] A. Refaat, N. Attia, H. Sibak, S. El Sheltawy, and G. El Diwani, "Production optimization and quality assessment of biodiesel from waste vegetable oil," International Journal of Environmental Science & Technology, vol. 5, pp. 75-82, 2008.
    [13] F. Chai, F. Cao, F. Zhai, Y. Chen, X. Wang, and Z. Su, "Transesterification of Vegetable Oil to Biodiesel using a Heteropolyacid Solid Catalyst," Advanced Synthesis & Catalysis, vol. 349, pp. 1057-1065, 2007.
    [14] A. Demirbas, "Biodiesel from sunflower oil in supercritical methanol with calcium oxide," Energy Conversion and Management, vol. 48, pp. 937-941, 2007.
    [15] N. Shibasaki-Kitakawa, H. Honda, H. Kuribayashi, T. Toda, T. Fukumura, and T. Yonemoto, "Biodiesel production using anionic ion-exchange resin as heterogeneous catalyst," Bioresource Technology, vol. 98, pp. 416-421, 2007.
    [16] P. Patil, V. G. Gude, S. Pinappu, and S. Deng, "Transesterification kinetics of Camelina sativa oil on metal oxide catalysts under conventional and microwave heating conditions," Chemical Engineering Journal, vol. 168, pp. 1296-1300, 2011.
    [17] S. Yan, H. Lu, and B. Liang, "Supported CaO Catalysts Used in the Transesterification of Rapeseed Oil for the Purpose of Biodiesel Production," Energy & Fuels, vol. 22, pp. 646-651, 2007.
    [18] J. Hernando, P. Leton, M. P. Matia, J. L. Novella, and J. Alvarez-Builla, "Biodiesel and FAME synthesis assisted by microwaves: Homogeneous batch and flow processes," Fuel, vol. 86, pp. 1641-1644, 2007.
    [19] A. A. Refaat, S. T. El Sheltawy, and K. U. Sadek, "Optimum reaction time, performance and exhaust emissions of biodiesel produced by microwave irradiation," International Journal of Environmental Science & Technology, vol. 5, pp. 315-322, 2008.
    [20] A. D’Cruz, M. Kulkarni, L. Meher, and A. Dalai, "Synthesis of Biodiesel from Canola Oil Using Heterogeneous Base Catalyst," Journal of the American Oil Chemists' Society, vol. 84, pp. 937-943, 2007.
    [21] E. L. Dall'Oglio, P. T. d. Sousa Jr, P. T. d. J. Oliveira, L. G. d. Vasconcelos, C. A. Parizotto, and C. A. Kuhnen, "Use of heterogeneous catalysts in methylic biodiesel production induced by microwave irradiation," Química Nova, vol. 37, pp. 411-417, 2014.
    [22] A. A. Refaat, "Biodiesel production using solid metal oxide catalysts," International Journal of Environmental Science & Technology, vol. 8, pp. 203-221, 2011.
    [23] X. Liu, H. He, Y. Wang, and S. Zhu, "Transesterification of soybean oil to biodiesel using SrO as a solid base catalyst," Catalysis Communications, vol. 8, pp. 1107-1111, 2007.
    [24] L. M. G. d. Carvalho, W. C. d. Abreu, M. d. G. d. O. e. Silva, J. R. d. O. Lima, J. E. d. Oliveira, J. M. E. d. Matos, et al., "Heterogeneous catalysis afford biodiesel of babassu, castor oil and blends," Journal of the Brazilian Chemical Society, vol. 24, pp. 550-557, 2013.
    [25] K. Faungnawakij, B. Yoosuk, S. Namuangruk, P. Krasae, N. Viriya-Empikul, and B. Puttasawat, "Sr–Mg Mixed Oxides as Biodiesel Production Catalysts," ChemCatChem, vol. 4, pp. 209-216, 2012.
    [26] M. Koberg, R. Abu-Much, and A. Gedanken, "Optimization of bio-diesel production from soybean and wastes of cooked oil: Combining dielectric microwave irradiation and a SrO catalyst," Bioresource Technology, vol. 102, pp. 1073-1078, 2011.
    [27] N. E. Leadbeater and L. M. Stencel, "Fast, Easy Preparation of Biodiesel Using Microwave Heating," Energy & Fuels, vol. 20, pp. 2281-2283, 2006.
    [28] J. Janaun and N. Ellis, "Perspectives on biodiesel as a sustainable fuel," Renewable and Sustainable Energy Reviews, vol. 14, pp. 1312-1320, 2010.
    [29] M. Pugazhvadivu and K. Jeyachandran, "Investigations on the performance and exhaust emissions of a diesel engine using preheated waste frying oil as fuel," Renewable Energy, vol. 30, pp. 2189-2202, 2005.
    [30] M. Satyanarayana and C. Muraleedharan, "Comparative Studies of Biodiesel Production from Rubber Seed Oil, Coconut Oil, and Palm Oil Including Thermogravimetric Analysis," Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, vol. 33, pp. 925-937, 2011.
    [31] G. College, "The Chemistry of Biodiesel - Differences Between Biodiesel, Diesel and Vegetable Oil," ed. Indiana, USA.
    [32] B. Freedman, E. H. Pryde, and T. L. Mounts, "Variables affecting the yields of fatty esters from transesterified vegetable oils," Journal of the American Oil Chemists' Society, vol. 61, pp. 1638-1643, 1984.
    [33] S. P. Joan Tarud, "Technoeconomic comparison of biofuels: ethanol, methanol, and gasoline from gasification of woody residues," in American Chemical Society, USA, 2011.
    [34] A. Demirbas, "Progress and recent trends in biodiesel fuels," Energy Conversion and Management, vol. 50, pp. 14-34, 2009.
    [35] M. A. Fazal, A. S. M. A. Haseeb, and H. H. Masjuki, "Biodiesel feasibility study: An evaluation of material compatibility; performance; emission and engine durability," Renewable and Sustainable Energy Reviews, vol. 15, pp. 1314-1324, 2011.
    [36] D. Y. C. Leung, X. Wu, and M. K. H. Leung, "A review on biodiesel production using catalyzed transesterification," Applied Energy, vol. 87, pp. 1083-1095, 2010.
    [37] C. Adams, J. F. Peters, M. C. Rand, B. J. Schroer, and M. C. Ziemke, "Investigation of soybean oil as a diesel fuel extender: Endurance tests," Journal of the American Oil Chemists’ Society, vol. 60, pp. 1574-1579, 1983.
    [38] A. Schwab, M. Bagby, and B. Freedman, "Preparation and properties of diesel fuels from vegetable oils," Fuel, vol. 66, pp. 1372-1378, 1987.
    [39] C.-C. Chang and S.-W. Wan, "China's Motor Fuels from Tung Oil," Industrial & Engineering Chemistry, vol. 39, pp. 1543-1548, 1947.
    [40] F. Ma and M. A. Hanna, "Biodiesel production: a review," Bioresource Technology, vol. 70, pp. 1-15, 1999.
    [41] T. Issariyakul, M. G. Kulkarni, L. C. Meher, A. K. Dalai, and N. N. Bakhshi, "Biodiesel production from mixtures of canola oil and used cooking oil," Chemical Engineering Journal, vol. 140, pp. 77-85, 2008.
    [42] J. Kansedo, K. T. Lee, and S. Bhatia, "Cerbera odollam (sea mango) oil as a promising non-edible feedstock for biodiesel production," Fuel, vol. 88, pp. 1148-1150, 2009.
    [43] C. Kaya, C. Hamamci, A. Baysal, O. Akba, S. Erdogan, and A. Saydut, "Methyl ester of peanut (Arachis hypogea L.) seed oil as a potential feedstock for biodiesel production," Renewable Energy, vol. 34, pp. 1257-1260, 2009.
    [44] A. Kumar Tiwari, A. Kumar, and H. Raheman, "Biodiesel production from jatropha oil (Jatropha curcas) with high free fatty acids: An optimized process," Biomass and Bioenergy, vol. 31, pp. 569-575, 2007.
    [45] Y. Rao, B. Xiang, X. Zhou, Z. Wang, S. Xie, and J. Xu, "Quantitative and qualitative determination of acid value of peanut oil using near-infrared spectrometry," Journal of Food Engineering, vol. 93, pp. 249-252, 2009.
    [46] P. K. Sahoo and L. M. Das, "Process optimization for biodiesel production from Jatropha, Karanja and Polanga oils," Fuel, vol. 88, pp. 1588-1594, 2009.
    [47] J. Zubr, "Oil-seed crop: Camelina sativa," Industrial Crops and Products, vol. 6, pp. 113-119, 1997.
    [48] J. San José Alonso, J. A. López Sastre, C. Romero-Ávila, and E. López, "A note on the combustion of blends of diesel and soya, sunflower and rapeseed vegetable oils in a light boiler," Biomass and Bioenergy, vol. 32, pp. 880-886, 2008.
    [49] F. F. P. Santos, J. Q. Malveira, M. G. A. Cruz, and F. A. N. Fernandes, "Production of biodiesel by ultrasound assisted esterification of Oreochromis niloticus oil," Fuel, vol. 89, pp. 275-279, 2010.
    [50] S. Saraf and B. Thomas, "Influence of Feedstock and Process Chemistry on Biodiesel Quality," Process Safety and Environmental Protection, vol. 85, pp. 360-364, 2007.
    [51] S. P. Singh and D. Singh, "Biodiesel production through the use of different sources and characterization of oils and their esters as the substitute of diesel: A review," Renewable and Sustainable Energy Reviews, vol. 14, pp. 200-216, 2010.
    [52] A. Srivastava and R. Prasad, "Triglycerides-based diesel fuels," Renewable and Sustainable Energy Reviews, vol. 4, pp. 111-133, 2000.
    [53] P. Winayanuwattikun, C. Kaewpiboon, K. Piriyakananon, S. Tantong, W. Thakernkarnkit, W. Chulalaksananukul, et al., "Potential plant oil feedstock for lipase-catalyzed biodiesel production in Thailand," Biomass and Bioenergy, vol. 32, pp. 1279-1286, 2008.
    [54] J. W. Goodrum, D. P. Geller, and T. T. Adams, "Rheological characterization of animal fats and their mixtures with #2 fuel oil," Biomass and Bioenergy, vol. 24, pp. 249-256, 2003.
    [55] P. Schinas, G. Karavalakis, C. Davaris, G. Anastopoulos, D. Karonis, F. Zannikos, et al., "Pumpkin (Cucurbita pepo L.) seed oil as an alternative feedstock for the production of biodiesel in Greece," Biomass and Bioenergy, vol. 33, pp. 44-49, 2009.
    [56] S. L. Dmytryshyn, A. K. Dalai, S. T. Chaudhari, H. K. Mishra, and M. J. Reaney, "Synthesis and characterization of vegetable oil derived esters: evaluation for their diesel additive properties," Bioresource Technology, vol. 92, pp. 55-64, 2004.
    [57] S. A. El Sherbiny, A. A. Refaat, and S. T. El Sheltawy, "Production of biodiesel using the microwave technique," Journal of Advanced Research, vol. 1, pp. 309-314, 2010.
    [58] H. Fukuda, A. Kondo, and H. Noda, "Biodiesel fuel production by transesterification of oils," Journal of Bioscience and Bioengineering, vol. 92, pp. 405-416, 2001.
    [59] U. Rashid and F. Anwar, "Production of Biodiesel through Base-Catalyzed Transesterification of Safflower Oil Using an Optimized Protocol," Energy & Fuels, vol. 22, pp. 1306-1312, 2008.
    [60] J. Sun, J. Ju, L. Ji, L. Zhang, and N. Xu, "Synthesis of Biodiesel in Capillary Microreactors," Industrial & Engineering Chemistry Research, vol. 47, pp. 1398-1403, 2008.
    [61] F.-X. Yang, Y.-Q. Su, X.-H. Li, Q. Zhang, and R.-C. Sun, "Studies on the Preparation of Biodiesel from Zanthoxylum bungeanum Maxim Seed Oil," Journal of Agricultural and Food Chemistry, vol. 56, pp. 7891-7896, 2008.
    [62] M. Di Serio, M. Cozzolino, M. Giordano, R. Tesser, P. Patrono, and E. Santacesaria, "From Homogeneous to Heterogeneous Catalysts in Biodiesel Production," Industrial & Engineering Chemistry Research, vol. 46, pp. 6379-6384, 2007.
    [63] M. M. R. Talukder, J. C. Wu, S. K. Lau, L. C. Cui, G. Shimin, and A. Lim, "Comparison of Novozym 435 and Amberlyst 15 as Heterogeneous Catalyst for Production of Biodiesel from Palm Fatty Acid Distillate," Energy & Fuels, vol. 23, pp. 1-4, 2008.
    [64] L. Bournay, D. Casanave, B. Delfort, G. Hillion, and J. A. Chodorge, "New heterogeneous process for biodiesel production: A way to improve the quality and the value of the crude glycerin produced by biodiesel plants," Catalysis Today, vol. 106, pp. 190-192, 2005.
    [65] A. Singh, B. He, J. Thompson, and J. Van Gerpen, "Process optimization of biodiesel production using alkaline catalysts," Applied Engineering in Agriculture, vol. 22, pp. 597-600, 2006.
    [66] E. Lotero, Y. Liu, D. E. Lopez, K. Suwannakarn, D. A. Bruce, and J. G. Goodwin, "Synthesis of Biodiesel via Acid Catalysis," Industrial & Engineering Chemistry Research, vol. 44, pp. 5353-5363, 2005.
    [67] A. Sivasamy, K. Y. Cheah, P. Fornasiero, F. Kemausuor, S. Zinoviev, and S. Miertus, "Catalytic Applications in the Production of Biodiesel from Vegetable Oils," ChemSusChem, vol. 2, pp. 278-300, 2009.
    [68] C. C. Akoh, S.-W. Chang, G.-C. Lee, and J.-F. Shaw, "Enzymatic Approach to Biodiesel Production," Journal of Agricultural and Food Chemistry, vol. 55, pp. 8995-9005, 2007.
    [69] J. M. Cerveró, J. Coca, and S. Luque, "Production of biodiesel from vegetable oils," Grasas y aceites, vol. 59, pp. 76-83, 2008.
    [70] L. C. Meher, D. Vidya Sagar, and S. N. Naik, "Technical aspects of biodiesel production by transesterification—a review," Renewable and Sustainable Energy Reviews, vol. 10, pp. 248-268, 2006.
    [71] C. Fang and P. Lai, "Microwave heating and separation of water-in-oil emulsions," Journal of microwave power and electromagnetic energy, vol. 30, pp. 46-57, 1995.
    [72] A. Zlotorzynski, "The Application of Microwave Radiation to Analytical and Environmental Chemistry," Critical Reviews in Analytical Chemistry, vol. 25, pp. 43-76, 1995.
    [73] C. O. Kappe, "Controlled Microwave Heating in Modern Organic Synthesis," Angewandte Chemie International Edition, vol. 43, pp. 6250-6284, 2004.
    [74] N. Kuhnert, "Microwave-Assisted Reactions in Organic Synthesis—Are There Any Nonthermal Microwave Effects?," Angewandte Chemie International Edition, vol. 41, pp. 1863-1866, 2002.
    [75] F. Chemat and E. Esveld, "Microwave Super-Heated Boiling of Organic Liquids: Origin, Effect and Application," Chemical Engineering & Technology, vol. 24, pp. 735-744, 2001.
    [76] C. Shibata, T. Kashima, and K. Ohuchi, "Nonthermal influence of microwave power on chemical reactions," Japanese journal of applied physics, vol. 35, p. 316, 1996.
    [77] D. Dallinger and C. O. Kappe, "Microwave-assisted synthesis in water as solvent," Chemical reviews, vol. 107, pp. 2563-2591, 2007.
    [78] A. Demirbaş, "Biodiesel from vegetable oils via transesterification in supercritical methanol," Energy Conversion and Management, vol. 43, pp. 2349-2356, 2002.
    [79] F. Wiesbrock, R. Hoogenboom, and U. S. Schubert, "Microwave-Assisted Polymer Synthesis: State-of-the-Art and Future Perspectives," Macromolecular Rapid Communications, vol. 25, pp. 1739-1764, 2004.
    [80] Y. Groisman and A. Gedanken, "Continuous Flow, Circulating Microwave System and Its Application in Nanoparticle Fabrication and Biodiesel Synthesis," The Journal of Physical Chemistry C, vol. 112, pp. 8802-8808, 2008.
    [81] L. Perreux and A. Loupy, "A tentative rationalization of microwave effects in organic synthesis according to the reaction medium, and mechanistic considerations," Tetrahedron, vol. 57, pp. 9199-9223, 2001.
    [82] C. Oliver Kappe, "Microwave dielectric heating in synthetic organic chemistry," Chemical Society Reviews, vol. 37, pp. 1127-1139, 2008.
    [83] A. Demirbas, "Biodiesel production from vegetable oils via catalytic and non-catalytic supercritical methanol transesterification methods," Progress in Energy and Combustion Science, vol. 31, pp. 466-487, 2005.
    [84] P. Lidström, J. Tierney, B. Wathey, and J. Westman, "Microwave assisted organic synthesis—a review," Tetrahedron, vol. 57, pp. 9225-9283, 2001.
    [85] J. M. N. van Kasteren and A. P. Nisworo, "A process model to estimate the cost of industrial scale biodiesel production from waste cooking oil by supercritical transesterification," Resources, Conservation and Recycling, vol. 50, pp. 442-458, 2007.

    無法下載圖示 校內:2020-07-16公開
    校外:不公開
    電子論文尚未授權公開,紙本請查館藏目錄
    QR CODE