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研究生: 黃漢昇
Huang, Han-son
論文名稱: 添加金屬鹽類與抗氧化酵素對於拜香燃燒 所排放污染物之影響
Addition of metallic salts and an anti- oxidant and it’s effect on incense emissions
指導教授: 林達昌
Lin, Ta-Chang
學位類別: 碩士
Master
系所名稱: 工學院 - 環境工程學系
Department of Environmental Engineering
論文出版年: 2006
畢業學年度: 94
語文別: 中文
論文頁數: 139
中文關鍵詞: 拜香懸浮微粒PAHs金屬鹽類抗氧化酵素
外文關鍵詞: anti-oxidant enzyme, metallic salts, PAHs, ash, Incense, particulates
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  • 燒香祭拜祖先與敬奉神明一直是國人重要習俗之一,但目前已知拜香燃煙中含有多環芳香化合物PAHs,相關研究指出國人鼻咽癌之得患率較高,燒香可能為致病因子之一。故本研究擬主動改善拜香成分,選取國人常用之四種拜香,於實驗箱內燃燒之方式,選用金屬鹽類與抗氧化酵素添加於拜香香支中,分別比較在燃燒情況下所產生的空氣污染物之特性。以GC/MS分析燃燒拜香所排放的PAHs,以ICP-AES分析拜香添加藥劑後之重金屬含量。
    結果顯示添加金屬鹽類使拜香燃燒速率增快、懸浮微粒排放係數減少、香灰排放係數增加,燃燒所產生的S-PAHs高於原始拜香,其特徵主要都是5環以上的PAHs為主;其中又以BaP、IND、BghiP為主要(62.8~71.4 %)。此外添加抗氧化酵素之拜香與原始拜香之燃燒速率,懸浮微粒、灰排放係數無顯著影響,但所產生的S-PAHs低於原始拜香,其特徵亦主要以5環以上的PAHs為主;其中又以BaP、IND、BghiP為主要(68.4~71.3 %)。
    本研究顯示添加的金屬含量確實對於燃燒拜香所排放的懸浮微粒有相當程度的改善;添加抗氧化酵素可以降低S-PAHs之排放量。可是添加此兩種添加劑在毒性潛在因子的評估皆高於原始拜香,對於此結果值得後續深入探討。

    Worshiping ancestors and gods by burning incense sticks is one of the important traditions for the Chinese. It has been reported that PAHs and other toxic pollutants are found in incense smoke. This research studied the effect of additives on incense emissions.
    Four types of incense sticks representing different ingredients were chosen for this study. Metallic salts and an anti-oxidant enzyme were added to several types of incense, which were burned in a custom-designed combustion chambers. Combustion products from incenses were collected and subsequently analyzed by a GC/MS for PAHs, and by an ICP-AES for metals in the emission.
    The results showed that adding the metallic salts increased the burning rate and the emission factor of ash of the incense. At the same time, the emission factor of particulate was decreased. The emission factor of S-PAHs was higher than the original unmodified incenses. The distribution profiles for PAHs were all similar among incences. Five- or higher rings were major PAHs. Especially, BaP, IND, BghiP were the most abundant (62.8~71.4 %).
    Addition of the anti-oxidant enzyme had no obvious influence on the burning rate, emission factor of ash and emission factor of particulate. The emission factor of S-PAHs was lower than unmodified incense. The distribution profiles for PAHs were all similar among incences. Again, the 5- or higher rings PAHs were major compounds. Especially, BaP, IND, BghiP had the highest contributions (68.4~71.3 %).
    This research shows that, while adding the metal content supresses the emission factor of particulate, and the anti-oxidant enzyme reduces the emission factor of S-PAHs, the emitted products become potentially more toxic. Further investigation in this aspect is therefore recommended.

    中文摘要.....................................................................................................II 英文摘要…………………………………………………………………III 誌謝………………………………………………………………………..V 表目錄……………………………………………………………………..XI 圖目錄……………………………………………………………………..XIV 第一章 前言 1 1-1研究動機 1 1-2研究目的 2 第二章 文獻回顧 3 2-1 拜香燃燒之相關研究 3 2-1.1 拜香之組成及原料特性 3 2-1.2 拜香燃燒排放污染物特性 6 2-1.3 拜香燃燒生成物對人體之危害 10 2-2 多環芳香烴化合物(PAHs)的重要性 12 2-2.1 PAHs 之形成機制 12 2-2.2 PAHs 之物理及化學性質 14 2-2.3 PAHs 之生物毒性及機制 17 2-3 影響拜香燃燒之添加劑 26 2-3.1 金屬鹽類 26 2-3.2 抗氧化酵素 27 第三章 實驗方法與步驟 29 3-1 實驗設計與規劃 29 3-2 採樣設計與規劃 31 3-2.1 採樣設備--氣固相污染物採樣模組 31 3-3 採樣前之準備 33 3-3.1 添加藥劑之配製 33 3-3.2 樣品之製備與調理 36 3-3.3 濾紙的前處理 37 3-3.4 流量校正 37 3-4 樣品定性定量分析 39 3-4.1 萃取 39 3-4.2 濃縮 39 3-4.3 淨化 40 3-4.4 再濃縮 40 3-4.5 氣相層析質譜儀(GC/MS)分析 41 3-5 樣品添加之重金屬分析 41 3-5.1 樣品備製 41 3-5.2 微波消化 42 3-5.3 感應耦合電漿原子發射光譜儀(ICP-AES)分析 45 第四章 數據分析之品質保證及品質控制 46 4-1 PAHs空白試驗 46 4-1.1溶劑空白試驗 46 4-1.2程序空白試驗 46 4-2 PAHs標準品回收率測試 48 4-3 PAHs標準品檢量線之建立 48 4-4 PAHs重複分析 49 4-5 重金屬空白試驗 53 4-5.1溶劑空白試驗 53 4-5.2程序空白試驗 53 4-6 重金屬標準品回收率測試 54 4-7 重金屬標準品檢量線之建立 55 4-8重金屬重複分析 56 4.9拜香添加水溶性藥劑之空白試驗 56 第五章 結果與討論 61 5-1 探討添加不同藥劑對拜香金屬含量之變化 61 5-1.1 硝酸鉀 61 5-1.2 氯化鈉 62 5-1.3 抗氧化酵素 62 5-2 探討添加不同藥劑對拜香之燃燒結果 63 5-2.1拜香之燃燒情況 63 5-2.2拜香之燃燒時間 63 5-2.3拜香之燃燒速率 65 5-2.4拜香燃燒之懸浮微粒排放係數 68 5-2.6單位時間拜香之懸浮微粒排放係數 74 5-2.7單位時間拜香之拜香灰排放係數 75 5-2.8 排放之固相PAHs濃度及分佈 76 5-3 探討添加藥劑對拜香排放之懸浮微粒與拜香灰之關係 84 5-4 探討添加藥劑對拜香排放之懸浮微粒與S-PAHs之關係 85 5-5 添加藥劑拜香燃燒所產生之BaPeq 86 5-6 拜香中金屬含量與拜香燃燒特性之探討 89 5-6.1 金屬含量與燃燒速率 89 5-6.2 金屬含量與懸浮微粒排放係數 90 5-6.3 金屬含量與拜香灰排放係數 91 5-6.4 金屬含量與S-PAHs排放係數 92 5-6.5 金屬含量與BaPeq 93 5-7 小結 94 第六章 結論與建議 95 6-1 結論 95 6-2 建議 97 參考文獻 98 附錄A 環保署研擬中之室內空氣品質標準草案 111 附錄B 16種PAHs之檢量線(GC/MS) 115 附錄C 3種重金屬之檢量線(ICP-AES) 131 附錄D 3種重金屬之方法偵測極限 133 附錄E 十六種PAHs之離子選擇 138

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