由於人口的快速增長和城市化的快速發展，淡水需求正在顯著增加。因海水約佔總水資源的97％，可利用的淡水不到總水量的3％。為了解決嚴重的淡水短缺問題，利用海水生產淡水會是有吸引力的方法。常見的海水淡化包括熱處理和薄膜處理法，這些方法會有些缺點包括高能耗、腐蝕及結垢。電容去離子技術被用於去除廢水或海水中離子以獲取淡水之新興方法。
目前台灣電鍍廢水處理程序複雜且成本相當昂貴，其產生之重金屬汙泥恐危及環境安全。本研究發展新穎性流體式電容去離子法(FdCDI)將針對五種電鍍廢水(pH值介於1-13之間)進行研究。此外，本研究亦開發高值化石墨烯之方法。石墨烯由純碳組成，碳原子在同一平面內共價鍵合在一起，單層石墨烯片藉由鍵合力較弱的凡德瓦爾力連接。石墨烯之剝離可以藉由化學、物理及電化學剝離方法進行。近來，電化學剝離引起了越來越多的關注，這主要優點具操作時間短、環境友好及大量化生產。低值石墨烯使用進行2個小時硫酸鹽電化學剝離法之產率為10-50％。在FdCDI鹽水(NaCl)試驗中，在施加1.2 V與流速為4.8 mL/min條件下，可得SAC為6.25 mg/g。酸性與中性廢水中高濃度銅與鈉之去除效率可達50-70%，而鹼性廢水中鋅之去除率高達90%以上。
最後本研究利用SEM、Raman及synchrotron X-ray absorption spectroscopy (XANES)分析來探討FdCDI電極之腐蝕問題。有塗佈活性碳之不鏽鋼電極對於鹼性與中性電鍍廢水減少腐蝕的影響。利用XANES可得知在酸性溶液下不銹鋼電極腐蝕後，鐵經由水解與氧化生成氫氧化鐵與四氧化三鐵。本研究發展新穎性FdCDI用於電鍍廢水具可行性，將不鏽鋼電極塗佈活性碳可提升去除效率與耐腐蝕性。在未來，本FdCDI程序可被工程放大以實際應用於電鍍廠之廢水處理。

Fresh water demand is increasing dramatically due to the rapid population growth and fast urbanization. Accessible fresh water is less than 3% of the total water, as seawater accounts for about 97% of water resources. To solve the severe shortage of fresh water, the production of fresh water from seawater is becoming an attractive method. Conventional desalination technologies include thermal- and membrane-based methods which have suffered from the drawbacks of high energy cost, corrosion, scaling, and fouling. Capacitive deionization (CDI) is thus an emerging method for the separation of ions from waste or sea waters to fresh water.
Electroplating wastewater treatments are relatively complicated with a high cost. The heavy metal sludge from the treatments of electroplating wastewater is frequently hazardous, which may also cause severe health and environmental problems. A new fluidized capacitive deionization (FdCDI) method was thus under development in the present work for a better treatments of electroplating wastewaters to achieve a green manner for recycling of water and valuable metals therein. In addition, as graphene that is made up of pure carbon whereby each carbon atom is covalently bonded together in the same planar and the monolayer graphene sheets are linked by weak-bonded van der Waals forces is becoming the next-generation novel materials for widely applications, a feasibility study for purification of low-grade graphene (L20) was also studied. The yield of the electrochemical exfoliation with sulfate salt from L20 was in the range of 10-50% at 298 K for 2 h. Corrosion of the stainless steel (SS) electrode during CDI was also studied by SEM, Raman, EIS, and synchrotron X-ray absorption spectroscopy (XANES). The activated carbon (AC) coated SS has been evaluated using electrochemical analysis, suggesting a drastic improvement in anti-corrosive properties. By XANES, the SS current collector is corrosive in the acidic solution, indicating the iron was hydrated and oxidized to FeOOH and Fe3O4. For the development of the new FdCDI method for the green-treatments of electroplating wastewaters. The AC coated SS electrodes can improve the removal efficiency and corrosion resistance. A high SAC (6.25 mg/g) of NaCl solution was obtained during FdCDI at the flow rate of 4.8 mL/min and +1.2 V. The removal efficiency of copper and sodium in the acidic and neutral wastewaters can reach 50-70%, while for the removal efficiency of zinc in alkaline wastewater is as high as 90%. The FdCDI process will be scaled up in the near future for the practical treatments of electroplating as wellas other inorganic wastewaters for recycling of fresh water and valuable methals.

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