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研究生: 邵文政
Shao, Wen-Cheng
論文名稱: 建材揮發性有機化合物管制策略之研究
A Study on the Management Strategy of the Volatile Organic Compounds Emitted from Building Materials
指導教授: 江哲銘
Chiang, Che-Ming
學位類別: 博士
Doctor
系所名稱: 規劃與設計學院 - 建築學系
Department of Architecture
論文出版年: 2006
畢業學年度: 94
語文別: 中文
論文頁數: 172
中文關鍵詞: 揮發性有機化合物建材逸散預測模式管制策略健康綠建材建材逸散模擬試驗艙
外文關鍵詞: Healthy green building materials, VOCs, Restriction strategies, Prediction model, Small scale chamber
相關次數: 點閱:187下載:7
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  •   本研究主要基於室內環境中使用人員的健康效應,探討建材逸散揮發性有機化合物對室內空氣品質(IAQ)所造成的影響,及對於室內人員的健康危害度。透過小尺寸建材逸散模擬試驗艙的研究方法,解析各種環境因子對建材中揮發性有機化合物的影響及各類建材的逸散特性,並據以推估各類建材在空間中所造成之致病風險值。最後根據建材檢測分析結果,比對各國對建材揮發性有機化合物的管制制度,建立適用於我國之建材揮發性有機化合物管制策略及管制流程。本研究主要可歸納以下結論:
    1.本研究主要探討建築材料中的揮發性有機化合物對於室內空氣品質的影響,透過綜合比較各種實驗分析系統後,建立建材逸散模擬試驗艙作為主要的研究工具,該系統的特性不僅能夠針對建材於實際空間中的逸散行為進行探討,並可滿足各類建材的檢測需求。因此本研究參考內政部建築研究所、ASTM及NRC之檢測標準試驗方法,進一步訂定標準實驗分析流程供未來相關研究及建材管制參考。
    2.根據“小尺寸建材逸散模擬試驗艙”控制環境變因(溫度、濕度、換氣率及負荷率等),並對各類建材進行檢測分析結果發現,溫、濕度的上昇亦同時造成建材逸散量的增加,而換氣率的增加對合板、清漆及及複層建材所造成的影響並未呈現相同的態勢,僅造成清漆的逸散量增加。
    3.根據建材揮發性有機化合物試驗結果所進行之健康風險評估,合板中甲醛的致癌風險值最高可達8.50 E-03(1.5ACH),遠大於可接受基準值(百萬分之一)之數千倍,長期暴露於此污染狀態,容易造成居住人員的健康危害;另外在清漆及複層建材的危害指標方面,各指標污染物質之HI值皆超過基準值,意味高度的健康危害風險同樣存在於裝修清漆及複層建材的空間中,因此建議室內空間應提高換氣次數或加設必要的通風換氣設備,施工人員並應配戴有效的防毒面具,將曝露危害降至最低。
    4.乾式建材(合板)的逸散衰減極為緩慢,即使經過長時間的放置而未經特殊處理,其逸散因子的衰減程度仍是非常微小,因此可將其初期逸散因子平均值視為該建材的逸散因子。另外經由觀測值與預測值的比對分析,本研究建立清漆及複層建材之揮發性有機化合物濃度預測模式,作為未來空間所需換氣量的設定參考。
    5.本研究建立「建材揮發性有機化合物逸散管制策略」,分別制訂管制架構及流程,以健全國內建材管制體系,在建材健康性能基準方面,透過一系列的調查研究與分析結果,並比較各先進國家的管制基準後,提出適用於台灣地區的管制基準,以確保施工人員及使用人員的安全與健康。

     This research was focus on the impacts on people’s health from the building materials in indoor environment and discussed what damages and influences would the building materials which emit volatile organic compounds (VOCs), do to indoor air quality (IAQ) and the health of people. The small scale environmental test chamber was used for analyzing the influences of the environmental factors on the characteristics of VOCs emissions from building materials, and estimating the pathogenic risk related to all kinds of building materials via the data from the experiments. Finally, according to comparing the results and analysis of the experiments with the regulations in various developed countries, the proper regulations of VOC emission from the building materials for Taiwan was set up. The following are the conclusions of this research:
    1. This research mainly discussed the impacts of VOCs from the building materials on indoor air quality. With experiments and analysis, as a major research tool, the small scale chamber for simulating the VOCs emission from building materials under indoor environmental conditions was set up. This system would not only discuss the VOC emission of building materials under the real condition but also satisfy the requirements for most kinds of building material tests. Therefore, this research referred to the related test standards and methods of the Architecture and Research Institute of Ministry of Interior, American Society for Testing and Materials (ASTM) and NRC, to set up the test analysis procedures as a consideration for future researches and restrictions on building materials.
    2. Basing on the environmental factors controlled by the test chamber (temperature, relative humidity and air exchange rate) , it was discovered that when the temperature and relative humidity increases, the amount of emission increases as well after conducting experiments on several kinds of building materials. However, the increases of air exchange rate did not do the same influences on plywood, varnish and multi-layered building materials; it only increased the amount of emission from varnish.
    3. Testing result of VOCs from building materials conduct the estimation on health hazard risk. The amount of carcinogens - formaldehyde - from the plywood would reach as high as 8.50 E-03(under 1.5ACH), which is over thousand times of the safety threshold standard (10 E-6). It would damage people’s health to be exposed under this condition over a long period of time. Furthermore, in order to lower the hazards of exposure, it is suggested that increasing the indoor air exchange rate and adding required ventilation equipments would be necessary, as for construction workers, wearing effective mask or similar means is also recommend.
    4. The decay of emission from dry building materials (plywood) is very slow. Even being placed for a long period of time without special processing, the decline of emission was still very slight. Therefore, the average value of initial emission could be its emission factor. Over and above, after comparing of estimated value and observed values, this research established the prediction model of the VOCs emission from the varnish and multi-layered building materials; this might be used as a reference to suggesting proper air exchange rate in the future.
    5. This research established “a restriction strategy to restrain VOCs from building materials”, which sets up the restraining frame and procedures to ensure the soundness of national control over the building materials. In order to proposing a performance standards of healthy building materials in Taiwan to ensure the safety and healthy of construction worker and users, a series of survey, researches and analysis was conducted, while the compare with the managing standards in developed nations was also carried out.

    目錄 中文摘要 i 英文摘要 ii 謝誌 v 目錄 vii 圖目錄 x 表目錄 xii 第一章 緒論 1-1 研究動機 1 1-2 研究目的 2 1-3 文獻回顧 3 1-3-1揮發性有機化合物 4 1-3-2室內建材與室內空氣品質 8 1-3-3揮發性有機化合物逸散模式 15 1-4 研究架構 28 1-4-1研究範圍 28 1-4-2研究流程 29 1-5 研究內容概要 30 第二章 建材揮發性有機化合物檢測分析系統之建立 2-1 台灣地區室內環境調查 33 2-1-1室內空間實測 33 2-1-2量測結果分析 36 2-2 國際間相關建材檢測方法 37 2-3 建材揮發性有機化合物逸散檢測實驗系統之建置 39 2-3-1 理論依據 40 2-3-2實驗系統構成 42 2-3-3 測試原理 43 2-4 系統儀器設備及藥品 44 2-4-1 實驗儀器設備 44 2-4-2 實驗藥品 45 2-5 定性及定量分析 46 2-5-1 定性分析 46 2-5-2 定量分析 46 2-6 實驗作業標準分析流程 46 2-6-1 標準氣體配置 46 2-6-2 樣品前處理 47 2-6-3 建材樣本測試分析 48 2-6-4 儀器分析條件 50 2-6-5 品質管制 51 2-6-6 精密度與準確度 53 2-6-7 標準分析流程 54 2-7 小結 55 第三章 建材揮發性有機化合物逸散檢測與分析 3-1 實驗設計與說明 57 3-1-1室內裝修建材試驗對象選定 57 3-1-2室內物理環境設定 57 3-2 實驗數據分析方法 60 3-3 建材揮發性有機化合物之檢測結果 63 3-3-1 室內常用建材揮發性有機化合物定性分析結果 63 3-3-2 指標污染物之選定 66 3-4 建材中甲醛及揮發性有機化合物逸散檢測結果 66 3-4-1 建材揮發性有機化合物之逸散特性 67 3-4-2 清漆在不同換氣率下之逸散特性 76 3-4-3 合板在不同換氣率下之逸散特性 80 3-5 複層建材揮發性有機化合物之檢測結果 86 3-5-1 複層建材揮發性有機化合物定性分析 86 3-5-2 複層建材揮發性有機化合物定量分析 88 3-6 複層建材揮發性有機化合物逸散特性探討 93 3-6-1 複層建材揮發性有機化合物之逸散特性 93 3-6-2 複層建材在不同換氣率下之逸散特性 99 3-6-3 小結 103 第四章 建材逸散預測模式及健康風險評估 4-1 建材逸散預測模式 105 4-1-1 衰減模式檢定方法 106 4-1-2 清漆及複層建材VOCs逸散模式之探討 108 4-2 建材逸散預測模式之應用 119 4-3 建材逸散揮發性有機化合物之危害度評估 116 4-4 小結 122 第五章 建材揮發性有機化合物管制策略研擬 5-1 國外健康綠建材標章發展與制度 125 5-2 國內健康綠建材管制基準之建立程序 137 5-2-1 健康綠建材 137 5-2-2 健康綠建材評估的意義與目的 138 5-2-3 健康綠建材評估範圍 138 5-2-4 健康綠建材評估要項與基準 139 5-3 小結 152 第六章 結論及後續研究建議 6-1 研究結論 155 6-2 後續研究建議 162

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