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研究生: 鍾金宏
Chung, Ching-hong
論文名稱: 錳離子摻雜和電極效應對CaCu3Ti4O12的介電性質及顯微結構的影響
Effects of Mn doping and electrode on the dielectric properties and microstructure of CaCu3Ti4O12 ceramics
指導教授: 方滄澤
Fang, Tsang-Tse
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年: 2007
畢業學年度: 95
語文別: 中文
論文頁數: 113
中文關鍵詞: 鈣鈦礦結構介電常數CaCu3Ti4O12
外文關鍵詞: CaCu3Ti4O12, perovskite, dielectric constant
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  • CaCu3Ti4O12(簡稱CCTO)是一種特別的介電陶瓷材料,其結構為鈣鈦礦立方晶結構。此材料特殊之處在於擁有極高的介電常數,如在室溫下可高達104~105,此外在廣泛的溫度範圍100K到600K間,其介電常數幾乎維持一定。但當溫度降至100K以下時,介電常數立即落降至約100。
    本研究為探討添加MnO2和試片表面不同電極對CCTO介電和顯微結構的影響。可以發現錳的摻雜會降低CCTO的介電常數,另外由添加矽的CCTO其等效電路中,有包含晶域、晶域邊界、晶界、電極的存在。

    An unusual dielectric ceramic material CaCu3Ti4O12 (CCTO) is a cubic perovskite structure. It possesses an extraordinarily high dielectric constant at room temperature of about 104~105. Besides, the dielectric constant is nearly constant over a wide temperature range ~100-600K. However the dielectric constant drops rapidly to 100 below about 100K.
    In this study, we would discuss the influence of MnO2 addition and electrode difference on the dielectric behavior and microstructure of CCTO. We can find that manganese doping would decrease the dielectric constant of CCTO. In addition, an equivalent circuit of CaSiO3-CCTO including domain, domain boundary, grain boundary, and electrode contact is proposed.

    目 錄 摘要……………………………………………………………………Ⅰ Abstract………………………………………………………………Ⅱ 致謝……………………………………………………………………Ⅲ 目錄……………………………………………………………………Ⅳ 表目錄…………………………………………………………………Ⅶ 圖目錄…………………………………………………………………Ⅷ 第一章 序論……………………………………………………………1 1-1 前言…………………………………………………………………1 1-2 研究目的……………………………………………………………2 第二章 理論基礎與前人研究…………………………………………3 2-1 介電陶瓷概述………………………………………………………3 2-2 基本介電原理………………………………………………………4 2-3 極化機構……………………………………………………………5 2-4 障壁層電容器……………………………………………………13 2-5 Maxwell-Wagner model…………………………………………16 2-6 阻抗分析法………………………………………………………20 2-7 電模數分析法……………………………………………………30 2-8 介電材料CaCu3Ti4O12介紹………………………………………34 2-8-1 CaCu3Ti4O12結構……………………………………………34 2-8-2 CaCu3Ti4O12介電性質概述…………………………………37 第三章 實驗步驟及方法………………………………………………45 3-1 實驗藥品…………………………………………………………45 3-2 實驗流程…………………………………………………………45 3-2-1 粉末的配製……………………………………………………45 3-2-2 試片的製備……………………………………………………46 3-3 材料分析設備及量測方法………………………………………47 3-3-1 X-ray 繞射分析………………………………………………47 3-3-2 密度量測………………………………………………………47 3-3-3 電阻率量測……………………………………………………48 3-3-4 介電性質和阻抗分析量測……………………………………49 3-3-5 SEM顯微結構觀察………………………………………………50 3-3-6 TEM顯微結構觀察………………………………………………51 第四章 實驗結果與討論………………………………………………54 4-1 粉末之合成………………………………………………………54 4-2 SEM顯微結構觀察…………………………………………………56 4-3 TEM顯微結構觀察…………………………………………………61 4-4 電性分析…………………………………………………………65 4-4-1 電阻率…………………………………………………………65 4-4-2 介電性質………………………………………………………67 4-4-3 阻抗分析………………………………………………………74 4-5 介電性質比較……………………………………………………86 4-6 阻抗分析比較……………………………………………………100 第五章 結論…………………………………………………………110 參考文獻………………………………………………………………111

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