本研究主要採用兩種新穎技術高效率處理環境荷爾蒙Bisphenol A (BPA)，以及研究生成自由基和其中間產物在BPA降解程序中的主導行為模式。
首先，吾人利用一種高硫酸複合鹽(peroxymonosulfate, PMS)所生成之高氧化電位的自由基(•OH和SO4–•)對BPA進行降解(化學計量比: [PMS]0/[BPA]0 = 2)。並鑑定於不同條件下所生成自由基之種類及主導物種。研究發現該自由基氧化程序能部分礦化BPA (Co2+/PMS程序在1小時礦化率約達40%)。與相關文獻比較，本實驗所採用之活化劑和氧化劑為最小用量。
其次，基因於改善Fenton’s family (Fenton, 電–Fenton 和 光–Fenton程序)技術的通病，在中性pHi處理條件下提出UV–Na2S2O8/H2O2–Fe(II,III)兩階段氧化程序，應用於降解或礦化BPA。第一階段吾人利用另一種高硫酸鹽(persulfate，S2O82–)以生成高氧化電位的硫酸根自由基將BPA氧化降解成較小分子(化學計量比: [S2O82–]0/[BPA]0 = 1)。接著再以光–Fenton程序將此較小分子進行礦化，總礦化率由40%提升至91%。據吾人所知，此乃首次採用此複合技術達完全降解雙酚A。再者，此亦為首次藉由實驗直接證實自由基主導行為模式在此兩種不同氧化劑系統中確實有差異。
另外，吾人亦針對此兩種氧化程序進行其降解動力模式探討；發現該兩種提出之氧化程序皆遵循〝擬一階動力模式〞，如同相關文獻結果，但不同的是，吾人發現在此UV/persulfate程序中所需之活化能相較於一般單獨利用熱催化氧化高硫酸鹽程序所需的活化能(ΔE)要來得小，僅約26 kJ mol–1。在該兩階段氧化程序中，搭配不同研究條件亦可達到25–91%不等之礦化成效。另外，在25–45 °C下Co2+/PMS氧化程序之研究，結果發現BPA之降解受活化劑Co2+劑量之影響相較於受氧化劑PMS劑量來得顯著。而藉由自由基和其中間產物鑑定分析結果吾人亦提出可能之氧化降解反應機制。
相信，此一研究果在後續相關研究可提供有用的參考；再者，此一低化學藥劑量氧化技術於實際廢水處理之應用，亦能單獨或搭配其他氧化方法做為進入生物處理程序前之〝前置處理技術〞。

This study mainly proposed two novel technologies for efficient Bisphenol A (BPA) decontaminantion, and investigated the behavior of dominant radicals and intermediates involved in these BPA degradation processes.
Firstly, we took advantage of the high oxidation–reduction potential of hydroxyl and sulfite radicals transformed from peroxymonosulfate (PMS) (stoichiometric ratio: [PMS]0/[BPA]0 = 2) as the oxidants to oxidize BPA to less complex intermediates. The expected radicals were used to mineralize those compounds very efficient (TOC removal ~40% at 1 h). Further, qualitative identification of both hydroxyl and (bi)sulfate radicals was performed to evaluate their dominance under different conditions.
Secondly, a two–stage oxidation (UV–Na2S2O8/H2O2–Fe(II,III)) process was applied to mineralize BPA at pHi (initial pH) = 7 based on the concept for improving the common drawbacks of Fenton’s family (i.e. Fenton, Fered–Fenton and Photo–Fenton processes). We take advantage of the high oxidation potential of sulfate radicals and use persulfate (stoichiometric ratio: [S2O82–]0/[BPA]0 = 1) as the 1st–stage oxidant to oxidize BPA to less complex intermediates. Afterwards, photo–Fenton process was used to mineralize those intermediates to CO2 (TOC removal was increased 40% to 91%). To the best of our knowledge, this is the first attempt to utilize the two processes in conjunction for the complete degradation of BPA. This is also the first attempt to evidence that the dominant behavior of radicals in a (bi)sulfite process is very different from that in a persulfate process. Additionally, the utilization of extremely small amounts of activator and oxidant for the complete degradation of BPA was achieved.
Moreover, both the BPA degradation in these two proposed oxidation processes formulated a pseudo–first–order kinetic model well as suggested as literature review. Differently, the much lower activation energy (ΔE = 26 kJ mol–1) was further calculated in the UV–Na2S2O8/H2O2–Fe(II,III) process to clarify that the thermal–effect of an illuminated system differs from single heat–assisted systems described. Final TOC removal levels of BPA by the use of such two–stage oxidation processes were 25–34%, 25%, and 87–91% for additional Fe(II,III) activation, H2O2 promotion, and Fe(II,III)/H2O2 promotions, respectively. For the Co2+/PMS oxidative process, the BPA degradation is not obviously dependent on the PMS concentration, but is related to Co2+ dosage over a practicable range of 25–45 °C. Possible BPA side–chain oxidative metabolic pathways are suggested based on experimental results incorporating the evidence from EPR (electron paramagnetic resonance) and analysis from GC–MS (gas chromatography–mass spectrometry).
Hence, the experimental results are believed to be useful for further study. Furthermore, the proposed procedures with low chemical dosages have great potential for lowering operational costs, and thus can be practically implemented with other AOPs as a pretreatment of industrial biological processes.

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