本論文利用傅式轉換紅外光譜儀(FT-IR) 研究異丙醇頻哪醇硼酸酯(2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane，ITDB)在二氧化鈦粉末表面上的吸附與反應。ITDB在35 oC時會以分子型態吸附於二氧化鈦表面上。在真空環境下，ITDB分子會熱分解為環氧硼分子以及異丙醇基分子，隨著溫度的上升進一步分解為硼氧化物吸附於表面。在有氧環境下，異丙醇基分子會氧化產生甲酸根、乙酸根以及CO2，而同位素實驗則可證實O2確實參與了反應，而非異丙醇基分子和二氧化鈦表面之氧原子進行反應。ITDB/TiO2在真空加熱反應後顏色出現了變化，將粉末刮下後進行的性質檢測也證實可進行可見光降解；ITDB/TiO2 進行有氧照光反應後，整體結構並無明顯變化，僅CO2、C=O及CO32-生成。而ITDB/SiO2，並不會產生反應。

Fourier-transform infrared spectroscopy has been employed to investigate the adsorption and reactions of 2-isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (ITDB) on powdered TiO2. ITDB is adsorbed molecularly on TiO2 surface at 35 oC, but it is subjected to thermal decomposition, producing adsorbed C3H7O and surface-bonded borate ester which decomposes into boron oxide at high temperatures under vacuum. In the presence of O2, HCOO-、CH3COO-、CO2 are generated thermally by the oxidation of isopropoxy. O2 participates in the formation of these products, which is confirmed by using 18O2. A significant color change of the TiO2, from white to brown was found after heating ITDB/TiO2 to 400 oC in vacuum. X-ray photoelectron spectroscopy shows that the B and C are left on TiO2, which exhibit visible-light sensitive photocatalytic activity of methylene blue degradation. In the ITDB/TiO2 photoreaction in the presence of O2, CO2、C=O and CO32- are formed. However, there is no reaction for ITDB/SiO2 under UV-light irradiation.

1. Gregg, S. J.; Sing, K. S. W. Adsorption, Surface Area and Porosity, Academic Press, New York, 1967.
2. Somorjai, G. A. Introduction to Surface Chemistry and Catalysis, Wiley & Sons, New York, 1994.
3. Vickerman, J. C. Surface Analysis, Wiley & Sons, New York, 1997.
4. Atkins, P. W. Physical Chemistry, Oxford University, 1994.
5. 卓靜哲, 何瑞文, 黃守仁, 施良垣, 蘇士剛 物理化學, 三民書局, 台南市, 1994年.
6. Fujishima, A.; Honda, K. Nature, 1972, 37, 238.
7. Bard, A. J. Science, 1980, 207, 139.
8. O’Regan, B.; Grätzel, M. Nature, 1991, 353, 737.
9. Tennakone, K.; Kumara, G. R. R. A.; Kumarasinghe, A. R.; Wijayantha, K. G. U.; Sirimanne, P. M. Semicond. Sci. Technol. 1995, 10, 1689.
10. Fujishima, A.; Zhang X.; Tryk, D. A. Surf. Sci. Rep. 2008, 63, 515.
11. Linsebigler,A. L.; Lu, G.; Yates, J. T., Jr. Chem. Rev. 1995, 95, 735.
12. Hoffmann, M. R.; Martin, S. T.; Choi, W.; Bahnemannt, D. W. Chem. Rev. 1995, 95, 69.
13. Arora, M. K.; Sinha, A. S. K.; Upadhyay, S. N. Ind. Eng. Chem. Res., 1998, 37, 3950.
14. Franks, S. N.; Bard, A. J. J. Phys. Chem., 1977, 81, 1484.
15. Leland, J. K.; Bard, A. J. J. Phys. Chem., 1987, 91, 5076.
16. Wu, W.; Herrman, J. M.; Pichat, P. J. Catal., 1989, 3, 73.
17. Lin, J.-L. J. Chin. Chem. Soc. 2002, 60, 457.
18. Burdett, J. K.; Hughbands, T.; Gordon, J. M.; Richardson, J. W., Jr.; Smith, J. V. J. Am. Chem. Soc. 1987, 109, 3639.
19. Augustynski, J. Electrochim. Acta 1993, 38, 43.
20. Cao, L.; Spiess, F.-J.; Huang, A.; Suib, S. L. J. Phys. Chem. B 1999, 103, 2912.
21. Low, K.-C. G.; McEvoy, S. R.; Matthews, R. W. Environ. Sci. Technol. 1991, 25, 460.
22. Ollis, D. F.; Pelizzetti, E.; Serpone, N. Environ. Sci. Technol. 1991, 25, 1522.
23. Legrini, O.; Oliveros, E.; Braun, A. M. Chem. Rev. 1993, 93, 671.
24. Wold, A. Chem. Mater. 1993, 5, 280.
25. Adams, J. H. Borate.; New Generation EP Gear Lubricant. Lubr.
Eng. 1977, 33, 241.

26. Kreuz, K. L.; Fein, R. S.; Dundy, M. EP Films from Borate Lubricants. ASLE Trans. 1967, 10, 67.
27. Philippon, D.; De Barros-Bouchet, M. -I.; Lerasle, O.; Le Mogne, Th.; Martin, J. -M. Experimental Simulation of Tribochemical Reactions Between Borates Esters and Steel Surface. Tribol. Letts. 2011, 41, 73.
28. Kimura, Y.; Wakabayashi, T.; Okada, K.; Wada, T.; Nishikawa, H. Boron Nitride as a Lubricant Additive. Wear 1999, 232, 199.
29. Goto, M.; Kasahara, A.; Tosa, M.; Yoshihara, K. Control of Frictional Force on Coating Films of Boron Nitride-Copper Complex in Ultra High Vacuum. Thin Solid Films 2002, 405, 300.
30. Erdemir, A.; Bindal, C.; Fenske, G. R. Formation of Ultralow Friction Surface Films on Boron Carbide. Appl. Phys. Lett. 1996, 68,1637.
31. Hu, Z. S.; Yie, Y.; Wang, L. G.; Chen, G. X.; Dong, J. X. Synthesis and Tribological Properties of Ferrous Octoxyborate as Antiwear and Friction-Reducing Additive of Lubricating Oil. Tribol. Lett. 2000, 8, 45.
32. E. F. Medvedev1.; A. Sh. Komarevskaya. Glass and Ceramics. 2007, 2, 8.
33. 黃信彰, 二甲基亞石風在二氧化鈦粉末表面上的吸附與反應, 國立成功大學化學研究所, 2012, p15.
34. Fan, J.; Yates, J. T. Jr. Phys. Chem. 1994, 98, 10621.
35. D. Peak.; G.W. Luther.; D.L. Sparks. Geochim. Cosmochim. Acta. 2003, 67,2551.
36. W. C. Wu.; C. C. Chuang.; J. L. Lin, J. Phys. Chem. B. 2000, 104, 8719
37. G. Busca, J. amotte, J.-C. Lavalley and V. Lorenezelli. J. Am. Chem. Soc. 1987, 109, 5197
38. C.-C. Chuang, W.-C. Huang, I.-C. Huang and J.-L. in. J. Catal. 1999, 185, 423
39. Miyata, H., Wakamiya, M., and Kubokawa, Y. J. Catal . 1974, 34, 117.
40. M. Dahlqvist, M. Hotokka, and M. Ra¨sa¨nen. Chem. Phys. 1998, 229, 137.
41. Toda, F.; Tanaka, K. Chem. ReV. 2000, 100, 1025
42. C.F. Lien.; C.H. Ho.; C.Y. Shieh.; C.L. Tseng.; J. L. Lin. J. Phys. Chem. C. 2008, 112, 8365.
43. G. A. Crowder. 3,3-Dimethyl-2-butanone: Infrared and Raman Spectra, Normal Coordinate Calculations, and Calculated Structure, Spectroscopy Letters: An International Journal for Rapid Communication. 2006, 307, 1353.
44. C.-C. Chuang., W.-C. Wu., M.-C. Huang., I.-C. Huang., J.-L. Lin.
J. Catal. 1999,185, 423.
45. Miller, B.P., Fulong, J.O., Tysoe, W.T. Langmuir. 2012, 28, 6322.