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研究生: 黃松輝
Huang, Sung-Hui
論文名稱: 氧化鋅膜做為有機高分子發光元件之陽極電極製作與分析
Investigation of ZnO thin films on the application of the anode electrode of PLED
指導教授: 李玉華
Lee, Yu-Hua
學位類別: 碩士
Master
系所名稱: 理學院 - 光電科學與工程研究所
Institute of Electro-Optical Science and Engineering
論文出版年: 2006
畢業學年度: 94
語文別: 中文
論文頁數: 150
中文關鍵詞: 氧化鋅有機高分子發光元件陽極
外文關鍵詞: zinc oxide, PLED, anode
相關次數: 點閱:81下載:1
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  •   本實驗使用高純度的氧化鋅靶材(99.99%)在室溫下利用離子束濺鍍系統在玻璃基板上沉積氧化鋅薄膜,透過改變離子束電壓(Vb),離子束電流(Ib)以及在沉積時通入不同流量的氧氣,來觀察對樣品的微觀結構、組成成分,電性及光學特性上的影響。
      接著,將氧化鋅薄膜應用在PLED 元件上當做陽極,PLED 元件結構組成分別是Ca/Al 作為陰極,PF 作為發光層,PEDOT:PSS 作為電洞傳輸層,氧化鋅(2000 )作為陽極,並研究其元件的光電表現特性,並與使用銦
    錫氧化物(ITO)為陽極時的PLED 元件作一比較。
      在本實驗中的最佳樣品為Vb=400 V,Ib=10 mA,在沒有通入氧氣當做反應氣體的條件下所成長出來的氧化鋅薄膜,厚度約為2000 ,電阻率為2×10-3 Ω-cm,載子濃度為2×1020 #/cm3,載子遷移率為15.1 cm2/V-s,可見光平均穿透率(Tav)為90%,而其在PLED元件的表現上,在偏壓為15V時可以得到最大亮度約為8000 cd/m2,而此時的發光效率為4 cd/A。

      In our study,zinc oxide (ZnO) films were deposited on the glass substrates by ion beam sputtering system using high-purity of ZnO
    (99.99%) target at room temperature.We investigated the influenceon the structure,composition,electrical and optical properties of ZnO films by changing the ion beam voltage (Vb) ,ion beam current (Ib) and feeding different oxygeng as flow rates.
      Then,ZnO films were used as anodes for polymer light emitting devices(PLED).We fabricated the PLED structure consisted of
    Ca/Al as a cathode,PF as a luminously layer,PEDOT-PSS as a hole transporting layer and ZnO (2000) as an anode.The electroluminescence
    performance of the devices were studied and compared to a control device with an indium tin oxide (ITO) anode.
      The Best ZnO film with resistivity as low as 2×10-3 Ω-cm,carrier concentration of 2×1020 #/cm3,Mobility of 15.1 cm2/V-s and optical
    transmittance 90% in the visible range was prepared at Vb=400 V and Ib=10 mA without feedind oxygen gas.The performance of PLED have
    the brightness of 8000 cd/m2 and luminance efficiency of 4 cd/A at 15 V.

    第一章 序論 第一節 透明導電膜簡介………………………… 1 第二節 有機發光元件簡介……………………… 8 第三節 研究動機與目……………………………11 第二章 理論原理 第一節 有機發光二極體介紹……………………12 第二節 氧化鋅薄膜特性…………………………27 第三節 氧化鋅薄膜製備相關論文回顧…………31 第四節 濺鍍原理及系統介紹……………………33 第三章 實驗儀器介紹與樣品製作流程 第一節 實驗儀器介紹 ………………………… 45 (一)離子束濺鍍系統…………………………… 45 (二)α-step 膜厚量測……………………………54 (三)歐傑電子能譜儀…………………………… 56 (四)X-ray 繞射分析儀 …………………………57 (五)AFM 量測系統 …………………………… 58 (六)霍爾效應量測系統 ……………………… 62 (七)可見光譜儀量測系統 …………………… 70 第二節 氧化鋅透明導電膜製作流程 ………… 74 第四章 PLED 元件製作與量測 第一節 PLED 元件製作過程 ………………… 79 第二節 PLED 光電特性量測 ………………… 85 第五章 實驗結果與討論 第一節 氧氣流量為零的實驗結果與討論 ……86 第二節 氧氣流量不為零的實驗結果與討論 …107 第三節 PLED 元件光電特性 ………………… 124 第六章 結論 ………………………………… 140 參考文獻 ……………………………………… 142 自述………………………………………………150

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