本論文是以導電性高分子聚二苯胺研究主體，探討導入磺酸根導入高分子中，對高分子性質之改變。
研究的內容主要分為兩部分，第一部分是利用電化學針對二苯胺(DPA)與2,5-二氨基苯磺酸(DABSA)在硫酸水溶液下進行電化學共聚合，探討DABSA添加量對聚合速率的影響，及利用循環伏安掃描(cyclic voltammetry)來檢視膜的電化學行為，以及紫外光/可見光光譜電化學來推論聚合起始時可能之機制及利用化學分析譜(XPS)來探討化學成分。由實驗結果發現2,5-二氨基苯磺酸單元確實有導入高分子結構中，且其共聚合之速率與 DPA 和 DABSA 的濃度有密切關係。當共聚物中含有DABSA 之結構，會產生自我摻雜效應，導致共聚物亞胺結構的增加。
第二部分直接利用化學方法，以發煙硫酸對不同氧化狀態之聚二苯胺進行磺酸化，探討其對磺酸化程度(S/N)之影響，利用XPS來探討氧化狀態及紫外光/可見光光譜學來探討自我摻雜之效應，以及熱重分析法(TGA)來探討其熱穩定性。由實驗結果發現以還原態之聚二苯胺進行磺酸化所得產物具有較高之S/N值，及較佳之熱穩定性。

Sulfonated polydiphenylamine using electrochemical/chemical synthesis is studied in this dissertation. Emphasis is placed on the effect of the introduction of sulfonic acid group on the polydiphenylamine chains, properties of the resulting polymer .
Electrochemical copolymerization of diphenylamine (DPA) with 2,5-diaminobenzenesulfonic acid (DABSA) was carried out in aqueous 4 M H2SO4 by employing cyclic voltammetry. Copolymer films were grown for different molar concentration ratios of DPA or DABSA. Electrochemical homopolymerization of DPA alone was also carried out under similar conditions. UV-Visible spectroelectrochemical studies were performed to add evidence for copolymer formation when electropolymerization was performed with DPA and DABSA. A growth equation for the deposition of copolymer film was deduced as QG = k [DPA]1.02 [DABSA]-0.69 Cn1.2 where Cn is the number of cycles in cyclic voltammetry by utilizing the charge associated for film deposition. X-ray photoelectron spectroscopy (XPS) was used to find the elemental composition of copolymer and changes in redox characteristics of the copolymer in comparison with PDPA.
Chemical synthesis of sulfonated polydiphenylamine prepared via sulfonation of emeraldine (EB) and leucomeraldine base (LEB) oxidation state of polydiphenylamine. Sulfonation level (S/N ratio) has been studied using X-ray photoelectron spectroscopy (XPS). LEB-SPDPA has a higher S/N ratio of 140% than EB-SPDPA, S/N~16.4%. UV-vis and TGA results for LEB-SPDPA and EB-SPDPA are shown to be a consequence of the much higher S/N ratio in LEB-SPDPA.

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