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研究生: 李怡潔
LI, Yi-Chieh
論文名稱: 表面電漿共振增強 MoSe2 之自發輻射
Surface Plasmon Resonance Enhanced Spontaneous Emission of MoSe2
指導教授: 周昱薰
Chou, Yu-Hsun
學位類別: 碩士
Master
系所名稱: 理學院 - 光電科學與工程學系
Department of Photonics
論文出版年: 2023
畢業學年度: 111
語文別: 中文
論文頁數: 65
中文關鍵詞: 侷域化表面電漿MoSe2二維材料
外文關鍵詞: surface plasmon resonance effect, mechanical exfoliation, mono layer of MoSe2, amplified spontaneous emission (ASE)
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  • 表面電漿共振效應(surface plasmon resonance)是一個新穎的突破,這 個效應讓金屬表面、奈米金屬粒子表面,能夠突破繞射的極限,而本論文 是研究:侷域化表面電漿共振的結構,進一步去分析。
    本論文的侷域化表面電漿共振的結構,分別為單層的二維材料 MoSe2 , 用來當作雷射的增益介質,並以激子為作為耦合出表面電漿子的媒介,並 以數層 hBN 用來彌補單層 MoSe2 的缺陷,並再用奈米銀柱,使光與奈米銀 柱的表面電漿耦合激發出光。
    使用機械剝離法撕出單層 MoSe2 與數層 h-BN,利用轉移系統,並將單 層 MoSe2 、數層 h-BN,相互疊在一起,接著找出適當的奈米銀柱,也是用 相同的轉移方法,也相互疊在一起,就完成了本實驗的樣品,製作出三層 二維材料的異質結構。
    接下來將此二維材料的異質結構,去進行光激發螢光系統量測分析, 探討此異質結構的轉移性,另外並分析 MoSe2 的製程方式,並分析出了表 面電漿共振增強 MoSe2 之自發輻射的特性。

    The Surface Plasmon Resonance (SPR) effect is a breakthrough that enables metal surfaces and nano-metal particles to surpass the optical diffraction limit. This thesis focuses on the analysis of the SPR cavity structure. The localized SPR structure discussed in this thesis is a monolayer two-dimensional material, MoSe2, which serves as the gain medium for the laser. Excitons are used to couple out the surface plasmons, and several layers of hBN are added to compensate for the defects of the monolayer MoSe2 because hBN is an excellent insulator. Finally, a nano-silver wire is used to couple light with the surface plasmon of the nano-silver wire to excite light.
    The preparation of the monolayer MoSe2 and several layers of hBN was achieved through mechanical exfoliation. The transfer method was used to stack the monolayer MoSe2, several layers of hBN, and the nano-silver wire together to create a three-layer, two-dimensional material heterogeneous structure.
    This heterogeneous structure of the two-dimensional material will be studied and analyzed using photoluminescence to examine the spectral properties. The outcome of the SPR cavity structure analysis shows amplified spontaneous emission (ASE) characteristics but does not exhibit lasing characteristics.

    摘要 i Extended Abstract ii 誌謝 v 目錄 vi 圖目錄 vii 表目錄 x 第一章 緒論 1 第一節 前言 1 第二節 研究動機與目的 2 第三節 論文大綱 3 第二章 實驗簡介與原理 4 第一節 實驗簡介 4 第二節 雷射原理 4 第三節 雷射條件 9 第四節 史密斯–珀塞爾效應 12 第五節 表面電漿奈米雷射 14 第六節 單層二維材料MoSe2 28 第七節 奈米銀柱 31 三實驗步驟 32 第一節 實驗流程圖 32 第二節 實驗流程轉移基板製作(裂片) 33 第三節 單層MoSe2製造 34 第四節 在顯微鏡下尋找單層二維材料MoSe2 36 第五節 PET轉移工具製作 38 第六節 單層MoSe2轉移與數層hBN轉移 39 第七節 奈米銀柱的製備和轉移 42 第八節 光激發螢光量測的原理和架設與測量流程 44 第四章 實驗結果與討論 46 第一節 光譜分析 46 第二節 單層二維材料MoSe2製程方法分析 55 第三節 樣品的可轉移性 58 第五章 結論與未來展望 60 參考文獻 62

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