結構型超級電容器(SSC)具有高比電容、優異的結構強度與長循環壽命等特性進而受到廣泛的關注，使SSC成為便攜式設備、電動車與航太產業最具吸引力的選擇。本研究探討一種新型的SSC，其電極採用雙向編織碳纖維，介電層採用雙向編織玻璃纖維，電解液使用PVA-KOH 的鹼性聚合物，基材則使用環氧樹脂與硬化劑。透過樹脂塗布成型(RS)、無預先抽真空之樹脂轉注成型(RTM)、預先抽真空之樹脂轉注成型(RTMV)與真空輔助樹脂轉注成型(VARTM)四種製程用以製作SSC，比較不同製程對於SSC性能變化的影響，旨在製造出孔隙率低、性質穩定、尺寸與厚度皆均勻的SSC。實驗結果表明，透過預先使用真空泵浦排出纖維中的空氣並提高灌注電解液時的氣壓，可以有效地降低SSC 之孔隙率並使其電化學性質與機械性質得到大幅的提升。同時，為了確定SSC最適當的電化學和機械性質範圍，製作了三種不同樹脂含量的SSC，當樹脂含量在15 wt%到30 wt%之間時，SSC表現出最為優秀的性質。綜上所述，本研究成功開發出了穩定成型的SSC製程，並透過製程上的優化與改善成功提升SSC之各項性質，為日後SSC的研究與應用奠定了穩固的基礎。

This study investigated the structural supercapacitor (SSC) with high specific capacitance, high structural strength, fast charging and discharging, and stable charging and discharging cycle. It uses woven carbon fiber as the electrode, woven glass fiber as an insulating layer, alkaline and epoxy resin compound as electrolyte. Four processes, resin smear molding (RS), resin transfer molding without vacuum (RTM), resin transfer molding with vacuum (RTMV), and vacuum assisted resin transfer molding (VARTM), are used to produce the SSC, and the most suitable process for SSC was selected by comparing the results. Due to the vacuum and injecting the electrolyte through high air pressure, the electrochemical and mechanical properties of SSC can be greatly improved, and the porosity in SSC can be reduced at the same time. The best electrochemical performance mechanical properties of SSCs were observed in the range of resin content from 15 wt% to 30 wt%. This study contributes to the development of SSCs through the establishment of the fabrication process with improvement of part quality.

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