本論文主要研究兩種材料：囊泡狀的孔洞氧化矽、金屬矽酸鹽複合材料，並從材料的製備以及實際應用兩方面進行討論。
第一部分：水相中製備囊泡狀孔洞氧化矽材料作為消光劑之應用
藉由有機模板法製備氧化矽孔洞材料時，受限於界面活性劑分子的大小，要合成孔洞大的材料需要額外添加擴孔劑，如1,3,5-trimethyl benzene(TMB)。製程中牽涉到有機物的添加，對人體及環境往往是一大負擔，有鑑於此，本研究嘗試發展新的合成實驗方法，在無任何有機溶劑的添加下，經由反應條件的調整，調控囊泡狀氧化矽的孔洞性質。最後將囊泡狀氧化矽應用在工業上的皮革消光劑，具有散射光線的效果。
第二部分：製備Fe-silicate複合材料
水合氧化鐵是一種優良的吸附劑，對於多種汙染物質都有吸附的效果，且低毒性，但水合氧化鐵以膠體粒子的形式懸浮在溶液中，在應用上有不易回收的缺點；再者，奈米等級的水合氧化鐵易自身聚集，而降低活性。為克服上述的缺點，本研究以氧化矽為載體(氧化矽前驅物為矽酸鈉)，使用共沉澱法合成出Fe-silicate。在應用方面，針對低濃度Ni2+、Cu2+溶液，Fe-silicate展現良好的金屬離子移除效果。
第三部分：製備Cu/Fe-silicate及Ni-silicate複合材料
對於金屬矽酸鹽(metal-silicate) 複合材料的合成具有一定的基礎後，將金屬來源改為日月光半導體封裝廠提供的銅鐵廢水，合成出Cu/Fe-silicate複合材料，比表面積約400 m2g-1；反應後的水質經由檢測，金屬殘留量在1.0 ppm以下，同時達到淨化水質的效果，也經實驗發現，Cu/Fe-silicate對於台塑氨氮廢液，有良好的氨氮移除率。
另外，改良「共沉澱法」成為「多重塗佈法」，突破一般製備metal-silicate的合成法有金屬擔載量上的限制，。將製備出高金屬單載量的材料應用在電池電極材料上，有良好的電容量，及電容保留率。

This research is to develop two kind of material. Mesocellular silica foam (MCF), consisting of silica spheres with a hollow void space in the order of nanometers, is synthesized using tri-block copolymer Pluronic® P123 as a structure-directing template and TEOS as a silica precursor. The effects of the stirring temperature and hydrothermal treatment on the porosity of the MCF are systematically examined. It is shown that the MCF has significant potential as a matting agent for synthetic leather. Fe-silicates are prepared by mixing Fe(NO3)3(s) with acidified sodium silicate and then adjusting the pH value through the addition of NaOH(aq). The effects of the pH value on the solubility of the Fe(OH)3(s) are examined. In addition, the use of a water-washing treatment to increase the specific surface area of the synthesized Fe-silicates is explored. It is shown that the Fe-silicates have considerable potential as adsorbents of Ni2+ and Cu2+ in solution at the ppm level.

參考文獻
1. J. S. Beck, J. C. Vartuli, W. J. Roth, M. E. Leonowicz, C. T. Kresge, K. D. Schmitt, C. T. W. Chu, D. H. Olson and E. W. Sheppard, J. Am. Chem. Soc., 1992, 114, 10834
2. F. Hoffmann, M. Cornelius, J. Morell and M. Froba, Angew. Chem., Int. Ed., 2006, 45,3216
3. W. Wang, S. Xie, W. Zhou and A. Sayari, Chem. Mater., 2004, 16, 1756-1762.
4. J. Fan, C. Z. Yu, T. Gao, J. Lei, B. Z. Tian, L. M. Wang, Q. Luo, B. Tu, W. Z.
Zhou and D. Y. Zhao, Angew. Chem. Int. Ed. 2003, 42, 3146-3150.
5. A. Vinu, V. Murugesan and M. Hartmann, Chem Mater, 2003, 15, 1385-1393.
6. H. P. Lin, C. L. Kuo, B. Z. Wan and C. Y. Mou, J Chin Chem Soc-Taip, 2002, 49, 899-906.
7. V. Alfredsson and M. W. Anderson, Chem Mater, 1996, 8, 1141-1146.
8. H. P. Lin and C. Y. Mou, Accounts Chem Res, 2002, 35, 927-935
9. J. M. Kim, Y. Sakamoto, Y. K. Hwang, Y. U. Kwon, O. Terasaki, S. E. Park and G. D. Stucky, J Phys Chem B, 2002, 106, 2552-2558.
10. A. Bhaumik and S. Inagaki, J Am Chem Soc, 2001, 123, 691-696.
11. Z. T. Zhang, Y. Han, L. Zhu, R. W. Wang, Y. Yu, S. L. Qiu, D. Y. Zhao and F. S. Xiao, Angew Chem Int Edit, 2001, 40, 1258.
12. A. Walcarius, M. Etienne and B. Lebeau, Chem Mater, 2003, 15, 2161-2173.
13. T. Yokoi, H. Yoshitake and T. Tatsumi, J Mater Chem, 2004, 14, 951-957.
14. J. N. Cha, T. J. Deming, D. E. Morse and G. D. Stucky, Abstr Pap Am Chem S, 2000, 219, U837-U837.
15. Z. R. R. Tian, J. Liu, J. A. Voigt, B. McKenzie and H. F. Xu, Angew. Chem. Int. Ed., 2003, 42, 414.
16. F. Noll, M. Sumper and N. Hampp, Nano Lett, 2002, 2, 91-95.
17. Z. Y. Zhong, Y. D. Yin, B. Gates and Y. N. Xia, Adv Mater, 2000, 12, 206-+.
18. P. Jiang, J. F. Bertone and V. L. Colvin, Science, 2001, 291, 453-457.
19. C. E. Fowler, D. Khushalani and S. Mann, Chem Commun, 2001, 2028-2029.
20. Q. S. Huo, J. L. Feng, F. Schuth and G. D. Stucky, Chem Mater, 1997, 9, 14-&.
21. Y. F. Lu, H. Y. Fan, A. Stump, T. L. Ward, T. Rieker and C. J. Brinker, Nature, 1999, 398, 223-226.
22. C. E. Fowler, D. Khushalani, B. Lebeau and S. Mann, Adv Mater, 2001, 13, 649-652.
23. T. F. Todros, Surfactants, Academic Press : London, 1984.
24. D. Zhao, Q. Huo, J. Feng, B. F. Chmelka, G. D. Stucky, J. Am. Chem. Soc., 1998, 120, 6024
25. R. K. Iler, The Chemistry of Silica , John Wiley, New York, 1979.
26. H. P. Lin and C. Y. Mou Acc. Chem. Rev., 2002, 35, 927.
27. M. G. Clerici, G. Bellussi and U. Romano, J Catal, 1991, 129, 159-167.
28. C. B. Dartt, C. B. Khouw, H. X. Li and M. E. Davis, Abstr Pap Am Chem S, 1993, 206, 57-Petr.
29. J. C. van der Waal, P. J. Kooyman, J. C. Jansen and H. van Bekkum, Micropor Mesopor Mat, 1998, 25, 43-57.
30. C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli and J. S. Beck, Nature, 1992, 359, 710-712.
31. A. Corma, V. Fornes, M. T. Navarro and J. Perezpariente, J Catal, 1994, 148, 569-574.
32. M. D. Alba, Z. H. Luan and J. Klinowski, J Phys Chem-Us, 1996, 100, 2178-2182.
33. R. Mokaya, W. Jones, Z. H. Luan, M. D. Alba and J. Klinowski, Catal Lett, 1996, 37, 113-120.
34. B. L. Newalkar, J. Olanrewaju and S. Komarneni, Chem Mater, 2001, 13, 552-557.
35. D. R. Rolison, Science, 2003, 299, 1698-1701.
36. F. A. C. Garcia, J. C. M. Silva, J. L. de Macedo, J. A. Dias, S. C. L. Dias and G. N. R. Filho, Micropor Mesopor Mat, 2008, 113, 562-574.
37. M. Plabst, L. B. McCusker and T. Bein, J Am Chem Soc, 2009, 131, 18112-18118.
38. M. Haruta, N. Yamada, T. Kobayashi and S. Iijima, J Catal, 1989, 115, 301-309.
39. R. Nares, J. Ramirez, A. Gutierrez-Alejandre, C. Louis and T. Klimova, J Phys Chem B, 2002, 106, 13287-13293.
40. Y. Chi, T. Y. Chou, Y. J. Wang, S. F. Huang, A. J. Carty, L. Scoles, K. A. Udachin, S. M. Peng and G. H. Lee, Organometallics, 2004, 23, 95-103.
41. James Wittke, Meteorite Book: Glossary P, 2014
42. E. P. Giannelis, R. Krishnamoorti and E. Manias, Adv Polym Sci, 1999, 138, 107-147
43. 張曉鐳、張哲，中國皮革，2007，Vol. 36，No.1
44. 徐峰，二氧化矽消光劑及應用，2001
45. J.M. Tarascon and M. Armand, Nature, 2001, 414, 359-367
46. D. Wieboldt, I. Ruff, and M. Hahn, Techniques for Raman Analysis of Lithium-Ion Batteries, 2015, 30,6
47. G. Ertl, H. Knözinger, F. Schüth, and J. Weitkamp, Handbook Of Heterogeneous Catalysis, 2nd, Wiley-VCH, Weinheim, 2008
48. 吳宇婷,林弘萍,“以金屬氫氧化物模板法製備metal-silicate孔洞性複合材料之合成與應用”, 2014
49. 郭美德,林弘萍,“金屬矽酸鹽和鋁酸鹽孔洞性複合材料之合成與應用研究”, 2016
50. Parker et al ., 1975
51. 賴佩琳,林弘萍,“利用有機模板法合成中孔洞氧化矽複合材料及其應用”, 2013
52. J. S. Lettow, Y. J. Han, P. S. Winkel, P. Yang, D. Zhao, G. D. Stucky and J. Y. Ying, Langmuir, 2000, 16, 8291-8295
53. F. Bauera, U. Deckera, K. Czihala, R. Mehnertb, C. Riedelc, M. Riemschneiderd, R. Schuberta, M. R. Buchmeisera, Progress in Organic Coatings, 2009, 64, 474–481
54. Lecture notes: Precipitation of Iron Hydroxides, Northwestern University
55. 行政院環保署，事業、污水下水道系統及建築物污水處理設施之放流水標準
56. 許建紅、高乃云、唐玉霖、梨雷，水處理技術，2011，37，22-34
57. D. Ghernaout, A. I. Al-Ghonamy, A. Boucherit, B. Ghernaout, amd M.W. Naceur, American Journal of Environmental Protection , 2015, 4, 1-15
58. Vuceta & Morgan, Limnology and Oceanography, 1977,22,742
59. S. Yang, J. Li, D. Shao, J. Hu and X.Wang, J. Haz. Mate., 2009, 166, 109–116
60. R. Darvishi Cheshmeh Soltani, M. Safari, A. Rezaee, and H. Godinid, Environmental Progress & Sustainable Energy, 2014, Vol.34
61. O. Yavuz, Y. Altunkaynak, F. Guzel, Water Research, 2003, 37, 948
62. O. Abollino, A. Giacomino, M. Malandrino, and E. Mentasti, Appl. Clay Sci., 2008, 38, 227–236
63. E. Alvarez-Ayuso, A. Garcia-Sanchez,Clays and Clay Minerals, 2003, 51, 475
64. W. Maa, P. Zonga, Z. Chenga, B. Wangb, and Q. Sunb, Journal of Hazardous Materials, 2014, 266, 19–25
65. S. Coruh, and O.N. Ergun, Environ. Prog. Sustain. Energy, 2009, 28, 162–172
66. L. Trakal, , R. Šigut, H. Šillerová, D. Faturíková, and M. Komárek, Ara. J. Chem.,2014, 7, 43–52
67. R. Davarnejad, and P. Panahi, J. Indu. Engi. Chem., 2016, 33, 270–275
68. 張士元，專論：煉油廠廢水處理與回用，2009，21-45
69. 物竞化学品数据库：产品名称：邻甲酚，CAS号：95-48-7
70. 王建文,郭炳林,“雙連續相二氧化矽/碳中空球之合成與其應用於快速充放電鋰離子電池負極”, 2015