| 研究生: |
楊朝隆 Yang, Chao-Long |
|---|---|
| 論文名稱: |
四環素類抗生素在畜牧廢水好氧處理程序中去除機制之探討 Removal of tetracycline antibiotics in aerobic swine wastewater treatment process |
| 指導教授: |
黃良銘
Whang, Liang-Ming 陳如 Chen, Wan-Ru |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 環境工程學系 Department of Environmental Engineering |
| 論文出版年: | 2014 |
| 畢業學年度: | 102 |
| 語文別: | 中文 |
| 論文頁數: | 113 |
| 中文關鍵詞: | 四環素類抗生素 、畜牧廢水 、污泥 、溶解性有機物 、吸附 |
| 外文關鍵詞: | tetracyclines antibiotics, livestock wastewater, sludge, dissolved organic matter, sorption |
| 相關次數: | 點閱:129 下載:4 |
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隨著檢測技術的進步,許多過去未發現或忽略的新興污染物持續被發現,而畜牧廢水中的抗生素便是其中之一。抗生素常被作為治療動物疾病、飼養畜禽之飼料添加劑,因此被廣泛的應用於畜牧業中。
傳統的污水處理程序在設計時並未考慮新興污染物,因此對於這些污染物去除效率相當有限,使得這些抗生素隨著廢水、污泥、液態肥料等途徑進入環境中。在許多文獻中都發現在河川、湖泊、底泥、地下水層、土壤等環境中都偵測到抗生素的殘留,特別是以畜牧廢水做為肥料澆灌的土壤。
為了減少抗生素經由畜牧廢水進入環境中,釐清抗生素在畜牧廢水處理程序中的宿命是相當重要的,因此本研究將探討四環素類抗生素(TCs)在畜牧廢水好氧處理程序中的去除機制,首先針對2座畜牧廢水處理廠進行調查,定期偵測包括四環素類抗生素在內共10種抗生素在畜牧廢水處理單元中的出現頻率與去除情形;且為了在穩定的條件下模擬實場環境,架設了兩個SBR反應槽,一個長期添加四環素類抗生素,用以馴養反應槽內的微生物,另一個則作為吸附實驗的對照組;此外,為了更加釐清畜牧廢水好氧槽中各介質的影響,以批次實驗的方式,模擬實場環境,找出四環素類抗生素在好氧處理程序中主要的去除機制。
研究發現,除了污泥會吸附抗生素外,經過實場厭氧處理的廢水中的溶解性有機物也會吸附抗生素。當廢水中有機質較高,如畜牧廢水,會使污泥的吸附效果大幅下降。推測是因為畜牧廢水中的有機物與污泥競爭抗生素,使得部分抗生素不被污泥吸收吸附。
Water scarcity issue becomes an important concern around the world. How to reduce contaminants and reuse treated wastewater has attracted great interests in many aspects. Reclamation and reuse of swine wastewater for agricultural land application is of important in the 21th century, because it not only reduces swine wastewater pollution potential to receiving water bodies, but also provides an environment friendly solution to better management of nitrogen cycle. Before this application can be practiced in Taiwan, many pollution indexes regarding treated swine wastewater effluent should be established, especially the most limited information for veterinary antibiotics used in swine industries.
The research on livestock wastewater treatment has been developed, but issues on antibiotics in livestock wastewater were still unclear. This study investigate two livestock wastewater treatment plant. Four classes of antibiotics: Tetracycline, Sulfonamide, macrolide, and lincosamide were measured, which were commonly used in swine. This studty use batch experiment to clarify what will happen when the tetracycline antibiotics (TCs) appear in the aerobic swine wastewater treatment process And, in order to simulate the real the aerobic swine wastewater treatment, this study also build two aerobic Sequencing Batch Reactor (SBR).
The result indicates that dissolved organic matter and suspended solids cause adsorptive and absorptive effects on tetracyclines in live-stock wastewater. However, when these two matter get together, the total sorption capacity will decrease. It might because of competitive adsorption.
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