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研究生： 詹竣宇
Jan, Jiun-Yun
論文名稱： 混合物實驗設計法應用於混摻高分子與小分子作為高效率高分子發光二極體的電子注入層
Blending Polymer and Small Molecule as An Electron Injection Layer in Highly Efficient Polymer Light Emitting Diodes via Mixture Design
指導教授： 溫添進
Wen, Ten-Chin
學位類別： 碩士
Master
系所名稱： 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年： 2015
畢業學年度： 103
語文別： 中文
論文頁數： 93
中文關鍵詞： 高分子發光二極體 、混合物實驗設計法 、電子注入層
外文關鍵詞： polymer light-emitting diode, electron injection, mixture design
相關次數： 點閱：100  下載：2 
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    • 本篇論文混合了三種不同電子注入材料，並使用溶液製程方式成膜出三成份電子注入層，搭配高功函數金屬鋁做為陰極，製作出高效率高分子發光二極體。
    第二章將使用一種高分子PVP加兩種小分子TOAB、2PAD混合後做為電子注入層，並利用混合物實驗設計法加以分析迴歸以利探討。由回歸出來之三角等高線圖可得到在何種混合比例下有最高的電流密度、亮度與發光效率。藉由分析三角等高線圖可推論出三種材料混合後各自扮演著什麼角色，並利用AFM與XRD等數據加以分析。
    第三章將使用兩種高分子PEIE、PVP加一種小分子TOAB混合後做為電子注入層，並利用混合物實驗設計法加以分析迴歸以利探討。由回歸出來之三角等高線圖可得到在何種混合比例下有最高的電流密度、亮度與發光效率。藉由分析三角等高線圖可推論出三種材料混合後各自扮演著什麼角色，並利用AFM等數據加以分析。

    Highly efficient polymer light-emitting diodes (PLEDs) are demonstrated by using a three-component EIL composed of poly(vinylpyrrolidone) (PVP), Tetraoctylammonium bromide (TOAB), and 2-phenylacetamide (2PAD), optimized by mixture design. Also, highly efficient polymer light-emitting diodes (PLEDs) are demonstrated by using a three-component EIL composed of Polyethylenimine, 80% ethoxylated (PEIE), Tetraoctylammonium bromide (TOAB), and poly(vinylpyrrolidone) (PVP), optimized by mixture design. Due to remarkable electron injection, the devices with PVP+TOAB+2PAD/Al cathodes show the high luminance efficiency 13.4 cd A-1, and PEIE+TOAB+PVP/Al cathodes show the high luminance efficiency 13.5 cd A-1, respectively. It paves the way for developing interfacial materials to achieve high-performance organic/polymer optoelectronics.

    中文摘要 I Extended Abstract II 誌謝 VI 目錄 VIII 表目錄 XIII 圖目錄 XIV 符號與縮寫 XVII 第一章 緒論 1 1-1 前言 1 1-2 有機發光二極體之概述 2 1-2-1 高分子發光二極體之發光原理 2 1-2-2 高分子有機發光二極體之層狀結構 4 1-3 修飾陰極的電子注入層之簡介與文獻回顧 6 1-3-1真空蒸鍍電子注入層之製程 6 1-3-1-1 金屬離子化合物 7 1-3-1-2 有機高分子與小分子材料 7 1-3-2旋轉塗佈電子注入層之製程 8 1-3-2-1 金屬離子化合物 8 1-3-2-2中性共軛界面活性劑 9 1-3-2-3共軛聚電解質 9 1-3-2-4有機高分子緩衝材料 10 1-3-2-5有機小分子鹽類 11 1-3-2-6 雙成份混合型電子注入層 11 1-4 混合物實驗設計法 12 1-4-1混合物實驗設計之原理 13 1-4-2混合物實驗設計之典型多項式 14 1-4-3混合物實驗設計之典型多項式的參數估計 15 1-4-4混合物實驗結合製作參數 17 1-4-5三成份之混合物實驗設計 18 1-4-6迴歸模式之檢定 19 1-5研究動機 21 第二章 一個高分子(聚乙烯吡咯烷酮)加兩個小分子(正四辛基溴化銨與乙醯苯胺)之三成份電子注入層應用於高分子發光二極體 31 2-1前言 31 2-2實驗流程 32 2-2-1藥品來源 32 2-2-2 元件組裝與特性量測 32 2-2-3 三角等高線圖與迴歸方程式之製作 36 2-2-4 開路電壓之量測 36 2-2-5 X-ray繞射圖譜之量測 36 2-2-6 原子力顯微鏡之量測 37 2-3 結果與討論 37 2-3-1電流密度、亮度與發光效率的迴歸方程式和三角圖之分析 37 2-3-1-1 以電流密度與發光效率圖討論PVP之角色 40 2-3-1-2 以電流密度與亮度圖討論TOAB之角色 40 2-3-1-3 以電流密度、亮度與發光效率圖討論2PAD之角色 41 2-3-1-4 藉由確認點確認三角圖之趨勢 41 2-3-1-5 開路電壓之分析 42 2-3-2 不同混合比例的三成份電子注入層對薄膜表面型態之影響 42 2-3-2-1 原子力顯微鏡之分析 43 2-3-2-2 X-ray繞射圖譜於不同TOAB比例的結晶性之分析 44 2-4結論 46 第三章 兩個高分子(乙氧基聚乙烯亞胺與聚乙烯吡咯烷酮)加一個小分子(正四辛基溴化銨)之三成份電子注入層應用於高分子發光二極體 62 3-1前言 62 3-2 實驗流程 63 3-2-1 藥品來源 63 3-2-2 元件組裝與特性量測 63 3-2-3 三角等高線圖與迴歸方程式之製作 66 3-2-4 開路電壓之量測 67 3-2-5 原子力顯微鏡之量測 67 3-3結果與討論 68 3-3-1電流密度、亮度與發光效率的迴歸方程式和三角圖之分析 68 3-3-1-1 以電流密度與亮度圖討論PEIE之角色 71 3-3-1-2 以電流密度與發光效率圖討論PVP之角色 71 3-3-1-3 以電流密度、亮度與發光效率圖討論TOAB之角色 72 3-3-1-4 藉由確認點確認三角圖之趨勢 72 3-3-1-5 開路電壓之分析 73 3-3-2 不同混合比例的三成份電子注入層對薄膜表面型態之影響 73 3-3-2-1 原子力顯微鏡之平面圖與3D圖分析 74 3-3-2-2 原子力顯微鏡之相圖分析 74 3-4 結論 75 第四章 總結與建議 87 4-1總結 87 4-2 未來發展與建議 88 參考文獻 89

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