簡易檢索 / 詳目顯示

研究生: 張家碩
Chang, Chia-Shuo
論文名稱: 水庫淤泥燒製輕質骨材的燒結行為之研究
The Research on Sintering Behavior of the Lightweight Aggregate Utilizing Reservoir Sediments
指導教授: 黃紀嚴
Huang, Chi-Yen
學位類別: 碩士
Master
系所名稱: 工學院 - 資源工程學系
Department of Resources Engineering
論文出版年: 2005
畢業學年度: 93
語文別: 中文
論文頁數: 70
中文關鍵詞: 燒結輕質骨材發泡機制
外文關鍵詞: bloating, sintering, lightweight aggregates
相關次數: 點閱:106下載:1
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  •   台灣的水庫淤泥每年所增加的淤積量約1460萬立方公尺,而挖掘淤泥的成本既高且沒有一個適當的方式可以處理淤泥,其處理方式多以堆積於置土場,造成不經濟也不環保的現象。淤泥中含有豐富的SiO2、Al2O3、Fe2O3及K2O等成份,可以提供燒製輕質骨材的所需原料,在適當的燒結溫度下以期可獲得質輕、低吸水性及高強度的輕質骨材,再加以控制燒結的持溫時間,希望可以在較低溫度即得到上述的良好性質。

      本研究針對曾文水庫淤泥進行燒結,由於曾文水庫內的淤泥已提供一個適合燒製輕質骨材的礦物相組成,控制升溫條件以便在燒結溫度時可以提供一個理想的發氣反應,並在一燒結溫度範圍內來控制其胚體產生的黏滯度,在適當的黏滯度下以滯含氣體不使外逸,促使在燒結溫度時可以造成胚體的膨脹現象,並在快速的降溫條件下形成一高緻密玻璃質表面的輕質骨材。

      將所得的燒結體以阿基米得法來量測其輕質骨材體密度及吸水率等性質,發現已可以得到較質輕且有較低吸水率的輕質骨材,進一步的以MTS來量測其輕質骨材的抗壓強度,在本研究中其溫度在高於1250℃以上即可以得到輕質骨材,其抗壓強度已達33MPa~7MPa。

      由BCA所規範量測輕質骨材的方法來評估本研究所燒製的輕質骨材,在本研究中可以得到其Strength/weight值在1.96的輕質骨材,其燒製條件為1250℃持溫2小時,顯示以曾文水庫淤泥燒製的輕質骨材其性質已足以為工程上所使用。

     With the rapidly depositing sludge in reservoirs of Taiwan, proper and economical disposal of sludge in reservoirs has become an urgent subject confronted by Taiwan. The chemical composition of sludge in the reservoir is mostly SiO2, Al2O3, Fe2O3, K2O, which could make the major composition of lightweight aggregate. This research hopes obtain light weight, porous, high strength lightweight aggregate under proper sintering conditions.

     This research investigated the sintering behavior of sludge in Tseng Wen Reservoir for lightweight aggregates, by sintering and promoting bloating the bulk made of sludge under controlled conditions of varying temperature, time. SEM, XRD, MTS, DTA, Ta-Mass techniques were used to examine the thermal treatment properties, including the bloating mechanism, microstructure, and crystalline variations.

     As for the compressive strength of lightweight aggregates which is about 33MPa~7MPa under sintering temperature 1250℃~1300℃. Follow in BCA ( British Cement Association ) procedure to estimate lightweight aggregates, the value of strength/weight is 1.96 under sintering condition 1250℃/2hours. And the lightweight aggregates that this research investigated are already enough to use for the construction.

    目錄 摘要.........................................I 致謝.........................................III 目錄.........................................IV 表目錄.......................................VI 圖目錄.......................................VII 第一章 緒論..................................1 1-1前言......................................1 1-2研究目的..................................2 第二章 理論基礎與前人研究....................4 2-1 水庫淤泥基本性質.........................4 2-1-1水庫淤泥的形成..........................4 2-1-2矽酸鹽類結晶構造........................4 2-1-3伊萊石熱分析反應........................10 2-2輕質骨材的基本性質........................11 2-3輕質骨材製造原理..........................12 2-3-1成分....................................12 2-3-2玻璃結構................................14 2-3-3成型方式................................17 2-3-4人造輕質骨材的燒結理論..................19 2-3-3-1玻化..................................19 2-3-3-2液相燒結..............................19 2-3-5燒結 ....................................21 2-4前人研究..................................22 第三章 實驗方法與步驟........................24 3-1實驗流程..................................24 3-2淤泥原樣的性質測試........................26 3-2-1淤泥樣品準備............................26 3-2-2淤泥粒徑分佈............................26 3-2-3淤泥X-Ray繞射分析(XRD..................26 3-2-4淤泥DTA、TG及TA-Mass熱分析既質譜儀分析..26 3-2-5淤泥化學成分分析........................27 3-3成型與成型後燒結試驗......................27 3-3-1單軸加壓成型............................27 3-3-2燒結體基本物理性質量測..................28 3-3-3燒結體顯微結構觀察......................29 3-3-4燒結體XRD相鑑定.........................29 3-3-5燒結體強度試驗..........................29 第四章 結果與討論............................30 4-1淤泥原樣性質..............................30 4-1-1 淤泥粒徑及粉末型態分析.................30 4-1-2淤泥X-Ray繞射分析及化學分析.............32 4-1-3淤泥熱分析暨質譜儀分析..................36 4-2燒結體性質................................41 4-2-1燒結體之體密度..........................41 4-2-2燒結體之礦物相..........................47 4-2-3燒結體顯微結構分析......................51 4-2-4燒結體之抗壓強度........................59 4-3發泡機制..................................64 第五章 結論與建議............................66 5-1 結論.....................................66 5-2建議......................................67 參考文獻.....................................68

    參考文獻
    1.Mindness, S. and Young, J. F., “Concrete,”1981, Prentice-Hall ,
    Inc.
    2.Skalny, J. P., “Materials Science of Concrete I,” The American Ceramic
    Society, Inc.(1989)
    3.Klein, C. and Hurlbut, C. S., “Manual of Mineralogy,”1993, John Wiley &
    Sons.
    4.余樹楨,「矽酸鹽類晶體結構」,晶體之結構與性質,第十三章
    5.Grim, R.E., “Clay Mineralogy,” 1953, McGRAW-HILL BOOK COMPANY, ING.
    6.Short, Kinniburgh, “Light-Weight Concrete,"1963, MAMLXIII, London.
    7.Riley, C. M., “Relation of chemical properties to the bloating of clays,"
    J. Am. Ceram. Soc., 34 121-128. (1969)
    8.柳春圃,「輕集料混凝土」,中國鐵道出版社,北京,1996
    9.Heller, L. and Miloslavski, I. and Aizenshtat, Z. and Halicz, L., “Chemical
    and mass spectrometric analysis of volatiles derived from clays,”Am.
    Mineral., 73 (1988) 376-382.
    10.吳振名,「玻璃之結構與特性」,陶瓷技術手冊,第二十六章
    11.Warren, B. E., “Kristallogy. Mineralog. Petrogr. ,"86,349 (1933)
    12.Vogel. W., “Chemistry of glass,”Am. Ceram. Soc., 38, (1985)
    13.Reed, J.S., “Principles of ceramics processing: 2nd ed., ” Wiley & Sons.
    (1995)
    14.Kingery, W. D. and Bowen, H. K. and Uhlmann, D. R., “Introduction to
    Ceramics. 2nd Ed,” (1976).
    15.Ducman, V. and Mladenovic, A. and Suput, J. S., “Lightweight aggregate
    based on waste glass and its alkali-silica ractivity,” Cement and Concrete
    Research 32 223-226 (2002)
    16.de’ Gennaro, R. and Cappelletti, P. and Cerri, G. and de’Gennaro, M. and
    Dondi, M. and Langella, A.., “Zeolitic tuffs as raw materials for
    lightweight aggregates,”Applied Clay Science 25 71-81 (2004)
    17.Cheeseman, C. R.and Makinde, A. and Bethanis, S., “Properties of
    lightweight aggregate produced by rapid sintering of incinerator bottom
    ash,” Resources, Conservation and Recycling 43 147-162 (2005)
    18.Fragoulis, D. and Stamatakis, M. G. and Chaniotakis, E. and Columbus, G.,
    “Charaterization of lightweight aggregates produced with clayey diatomite
    rocks originating from Greece,” Materials Characterization 53 307-316
    (2004)
    19.郭玉順,王征及丁建彤,「粉煤灰燒脹陶粒的化學成分、膨脹氣體與性能關係的研
    究」,清華大學土木水利學院建築材料研究所 北京100084
    20.楊志政及王鯤生,「下水污泥焚化灰細度變化與矽氧晶相對燒成骨材輕質化之影響」,
    國立中央大學環境工程研究所,碩士論文(2001.5)
    21.Clarke, J. L., “Structural lightweight aggregate concrete,” Blackie
    Academic & Professional (1993)
    22.Wen, C. E. and Yamada, Y. and Shimojima, K. and Chino, Y. and Hosokawa, H.
    and Mabuchi, M., “Compressibility of porous magnesium foam: dependency on
    porosity and pore size, ”Materials Letters 58 357– 360 (2004)
    23.Kilic, A. and Atis, C. D. and Yasar, E. and Ozcan, F., “High-strength
    lightweight concrete made with scoria aggregate containing mineral
    admixtures, ”Cement and Concrete Research 33 1595-1599 (2003)
    24.Pioro, L. S. and Pioro, I. L., “Production of expanded-clay aggregate for
    lightweight concrete from non-selfbloating clays,” Cement & Concrete
    Composites 26 639–643 (2004)
    25.Wasserman, R. and Bentur, A., ”Effect of Lightweight Fly Ash Aggregate
    Microstructure on the Strength of Concrete,” Cement and Concrete Research,
    Vol.27, No.4, 525-537 (1997)
    26.Lingling, X. and Wei, G. and Tao, W. and Nanru, Y., “Study on fired bricks
    with replacing clay by fly ash in high volume ratio,” Construction and
    Building Materials 19 243-247 (2005)

    下載圖示 校內:2006-08-22公開
    校外:2006-08-22公開
    QR CODE