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研究生: 陳健群
Chen, Chien-Chun
論文名稱: 具微米柱結構之氮化鋁鎵系列蕭特基 紫外光偵測器之研究
AlGaN-based Schottky Barrier Ultraviolet Photodetector with Micropillar Structures
指導教授: 賴韋志
Lai, Wei-Chi
學位類別: 碩士
Master
系所名稱: 理學院 - 光電科學與工程研究所
Institute of Electro-Optical Science and Engineering
論文出版年: 2010
畢業學年度: 98
語文別: 中文
論文頁數: 66
中文關鍵詞: 蕭特基光偵測器氮化鋁鎵微米柱結構硫化處理
外文關鍵詞: Schottky Barrier, Photodetector, AlGaN, Micropillar Structures, (NH4)2Sx treatment
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  • 本論文針對具微米柱結構氮化鋁鎵系列蕭特基二極體光偵測器之研究,由於成長氮化鋁鎵層的過程中,在微米柱的平台和邊緣側壁上的應力以及成長速率等等的差異影響,會存在相異鋁含量分佈在微米柱的平台和邊緣側壁的氮化鋁鎵層。從CL量測結果,波長340nm和320nm的CL影像圖可以證明,成長氮化鋁鎵層於具有微米柱結構的氮化鎵基板上,在微米柱的邊緣側壁和平台的氮化鋁鎵層有不同的鋁含量。同時光響應量測分析結果有三個階段吸收,截止波長分別落在326nm、346nm、356nm,該波長位置的響應度為1.1×10-2、5.9×10-3、和 4.04×10-3 A/W。
    然而在氮化鋁鎵層表面所形成的缺陷而提供的漏電路徑,是因為晶格常數的不匹配加上成長氮化鋁鎵層時的熱擴散效應,導致缺陷的產生,為了抑制漏電流,我們使用硫化銨溶液處理試片表面,發現經過硫化處理後,降低了氧化銦錫的載子濃度和光學能隙,並在表面形成硫保護層,抑制漏電流路徑。

    In this study, we demomstrated a single AlGaN layer with two different Al contents on the GaN μ-pillars template. It was found by the selective wavelength spatial cathodoluminescence images that the emission wavelength of the AlGaN layer were at 340 and 320nm on the side of the cone and on the top and valley surface of pillars, respectively. The Schottky-type photodector were also demonstrated on double Al contents of deposited AlGaN on GaN micropillar template. The three steps of response occurred at about 326, 346, and 356nm with responsivities of 1.1×10-2, 5.9×10-3, and 4.04×10-3 A/W, respectively.
    However, the pits formation might arise from the lattice mismatch and the higher strain of AlGaN layer on sidewall of GaN pillar, resulting in the larger leakage current. In order to restrain the leakage current and improve the performances, we treated out the surface on sample with (NH4) 2Sx .We found that after (NH4) 2Sx treatment might result in a decrease in the carrier concentration and optical bandgap of ITO film. The effects of an (NH4) 2Sx treatment could change the properties of ITO films and form sulfide passivation for the enhancement of the schottky barrier height.

    摘要 I ABSTRACT II 誌謝 III 目錄 IV 表目錄 VII 圖目錄 VIII 第一章 緒論 1 參考文獻 4 第二章 實驗原理與裝置 6 2-1 前言 6 2-1-1 X-ray繞射原理 6 2-1-2 陰極發光原理(Cathodoluminescence,簡稱CL) 8 2-1-3 霍爾量測原理 8 2-1-4 柏斯坦-摩斯(Burstein-Moss)效應 10 2-2 蕭特基二極體實驗原理與裝置 10 2-2-1 蕭特基接觸原理 10 2-2-2 電流-電壓量測原理 13 2-2-3 光響應度量測原理 15 參考文獻 23 第三章 蕭特基光偵測器元件製程與特性 24 3-1 製作樣品結構 24 3-2 製程步驟 24 3-2-1 以ITO作為蕭特基接觸的氮化鋁鎵蕭特基二極體偵測器之製作 24 3-2-2 以ITO作為蕭特基接觸的氮化鋁鎵蕭特基二極體偵測器之製作並使用硫化銨溶液處理 26 3-3 蕭特基光偵測器量測設備 28 3-3-1 I-V量測設備 28 3-3-2 光響應度(Responsivity)之量測設備 29 3-4 光偵測原理 29 3-5 影響光偵測器特性的不理想因素 30 3-5-1 漏電流機制 30 3-5-2 費米能階釘札機制(Fermi Level Pinning) 33 3-5-3 蕭特基效應 36 參考文獻 43 第四章 蕭特基接觸光偵測器元件特性分析 45 4-1 XRD量測 45 4-2 CL量測 45 4-3 氧化銦錫於具微米柱結構氮化鋁鎵基底之蕭特基光偵測器電性分析 47 4-4 氧化銦錫於具微米柱結構氮化鋁鎵基底之蕭特基光偵測器經過硫化銨溶液處理之電性分析 49 4-5 氧化銦錫於具微米柱結構氮化鋁鎵基底蕭特基光偵測器之光響應分析 51 4-6 氧化銦錫於具微米柱結構氮化鋁鎵基底蕭特基光偵測器並使用硫化銨溶液處理之光響應分析 52 參考文獻 65 第五章 結論與未來方向 66

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